公开(公告)号：JPH1046194A

公开(公告)日：1998-02-17

申请号：JP11715297

申请日：1997-05-07

Applicant: HOECHST AG

Inventor： LOEFFLER MATTHIAS DR ,  MEES BERNHARD DR ,  REINHARDT GERD DR

IPC: C07D213/84 ,  C07D213/85 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395

Abstract: PROBLEM TO BE SOLVED: To provide a bleaching activator which has improved solubility and compatibility with fibers and exhibits a better bleaching action than that of a conventional bleaching activator by selecting a specific compd. as or incorporating it into a bleaching activator. SOLUTION: This bleaching activator is or contains a compd. represented by the formula (wherein R1 is H, a 1-24C alkyl, a 2-24C alkenyl, an aryl, cyanomethyl, or a 1-4C alkoxy-(1-4C) alkyl; R2 to R4 are each H, a 1-24C alkyl, a 2-24C alkenyl, an aryl, a 1-4C alkoxy-(1-24C) alkyl, or cyano; when Z is cyano, then Y is the same as R2 to R4 , and when Y is cyano, then Z is the same as R2 to R4 ; and X is an anion). The synthetic route is as follows: for example, isonicotinonitrile is obtd, by a known method, i.e., by the direct oxidation or ammonoxidation of 4-methylpyridine; and, for example, a corresponding N- alkyl-4-cyanopyridinium salt is obtd. by the alkylation of isonicotinonitrile with a methylation agent (e.g. methyl chloride or dimethyl sulfate).

公开(公告)号：JPH1059934A

公开(公告)日：1998-03-03

申请号：JP16769797

申请日：1997-06-24

Applicant: HOECHST AG

Inventor： LOEFFLER MATTHIAS DR ,  REINHARDT GERD DR

IPC: C07D233/60 ,  C07D207/26 ,  C07D207/263 ,  C07D207/27 ,  C11D3/28 ,  C11D3/39 ,  C11D3/395 ,  C11D7/32 ,  C11D9/30

Abstract: PROBLEM TO BE SOLVED: To produce a new compound useful as a bleach activator for a detergent composition. SOLUTION: This new compound is represented by formula I R1 to R3 are each a 1-24C alkyl or an aryl; R2 and R3 together with N to which both are bonded form a 4-6C ring, etc.; L is a group represented by formula II [(n) is 3-5], etc.; X is an anion}, e.g. (N,N,N-trimethylammonium)acetylpyrrolidone chloride. The compound represented by formula I is obtained by reacting a lactam with chloroacetyl chloride in the presence of an auxiliary base, providing an N-(chloroacetyl)amide, then reacting the resultant compound with a secondary amine, preparing a 2-(N,N-dialkylamine)acetyllactam and subsequently alkylating the resultant compound.

公开(公告)号：EP0806473A3

公开(公告)日：1998-12-23

申请号：EP97107051

申请日：1997-04-29

Applicant: HOECHST AG

Inventor： LOEFFLER MATTHIAS DR ,  MEES BERNHARD DR ,  REINHARDT GERD DR

IPC: C07D213/84 ,  C07D213/85 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/28

CPC classification number: C11D3/392

Abstract: Die Verwendung von Verbindungen der allgemeinen Formel wird beansprucht, worin die Reste R
1 bis R
4 sowie Y und Z organische Substituenten und X ein geeignetes Anion bedeuten. Die erfindungsgemäßen Verbindungen werden als Bleichaktivatoren in bleichenden Wasch- und Reinigungsmittel eingesetzt.

公开(公告)号：EP0761809A3

公开(公告)日：1998-09-02

申请号：EP96113058

申请日：1996-08-14

Applicant: HOECHST AG

Inventor： REINHARDT GERD DR ,  FRIDERICHS VERA ,  SCHARBERT BERND DR ,  SCHULZ ROLF PETER DR ,  KREBS BERNT PROF DR ,  BOEHNER RAINER DL ,  THUELIG CHRISTIAN DL

IPC: A61K8/00 ,  A61K8/22 ,  A61K8/33 ,  A61K8/37 ,  A61K8/38 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/60 ,  A61Q11/02 ,  C11D3/39 ,  C11D3/395

CPC classification number: C11D3/3932

Abstract: Bleichmittelzusammensetzung enthaltend ein oder mehrere Bleichmittel und einen oder mehrere Polyoxometallate der Formel
(Q)
q (A
a X
x M
m O
y Z
z (H
2 O)
b ·cH
2 O
als Bleichkatalysator, wobei die Symbole Q, A, X, M, Z, q, a, x, m, y, z, b und c die in der Beschreibung genannten Bedeutung haben.

公开(公告)号：EP0710716A3

公开(公告)日：1998-07-08

申请号：EP95116730

申请日：1995-10-24

Applicant: HOECHST AG

Inventor： BERENBOLD HELMUT DR ,  BORCHERS GEORG ,  CRAMER JUERGEN DR ,  NOELTNER GERHARD ,  REINHARDT GERD DR ,  SCHULER WILFRIED ,  HEININGER WOLFGANG DR

IPC: C11D3/395 ,  C11D3/12 ,  C11D3/39 ,  C11D11/00 ,  C11D17/00

CPC classification number: C11D3/3935 ,  C11D3/126 ,  C11D11/00 ,  C11D17/0039

Abstract: Gegenstand der vorliegenden Erfindung ist ein Verfahren zur Herstellung eines lagerstabilen Granulates bestehend im wesentlichen aus einem Bleichaktivator und einem anorganischen Bindematerial, gekennzeichnet durch die Verfahrensschritte:

a) Vermischen eines trockenen Bleichaktivators mit einem trockenen anorganischen Bindematerial,
b) Verpressen dieser Mischung zu größeren Agglomeraten und
c) Zerkleinern dieser Agglomerate auf die gewünschte Korngröße.

Weiterer Gegenstand der Erfindung ist die Verwendung, der nach diesen Verfahren hergestellten Granulate in Wasch-, Reinigungs-, Blech- und Desinfektionsmitteln.

公开(公告)号：AT136580T

公开(公告)日：1996-04-15

申请号：AT89122759

申请日：1989-12-09

Applicant: HOECHST AG

Inventor： ENDO HAJIME DR ,  GETHOEFFER HANSPETER DR ,  GRABLEY FRITZ-FEO DR ,  REINHARDT GERD DR

IPC: C11D3/395 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02

Abstract: Triacylated ethanolamines of the formula… (RCO)(R1CO)N-(CH2)2-OCOR2… in which R, R1 and R2 are identical or different and are alkyl, alkenyl or aryl groups, and the total of all C atoms in the molecule is 8 to 14, are liquid and readily miscible with water. By reason of these properties they are very suitable as peroxide activators in liquid detergents and cleaners.

公开(公告)号：DE59106184D1

公开(公告)日：1995-09-14

申请号：DE59106184

申请日：1991-05-23

Applicant: HOECHST AG

Inventor： GETHOEFFER HANSPETER DR ,  REINHARDT GERD DR ,  NAUMANN PETER

IPC: A01N47/28 ,  C07C407/00 ,  C07C409/40 ,  C11D3/39 ,  C11D7/54

Abstract: Compounds of the formula (* CHEMICAL STRUCTURE *) where y is 1 or 2, A is hydrogen, C1-C2-alkyl, aryl or a group of the formula (* CHEMICAL STRUCTURE *) if y is 1, or C2-C20-alkylene or arylene if y is 2, R1 and R2 can be identical or different and each is hydrogen, C1-C20-alkyl, aryl, haloaryl, alkoxyaryl or alkylaryl, or else R1 and R2 together are a C2-C4-alkylene radical, x is 0 or 1, B is a group of the formula (* CHEMICAL STRUCTURE *) (* CHEMICAL STRUCTURE *) n is from 1 to 20, m is 0, 1 or 2, R3 is C1-C20-alkyl and R4 is in each case hydrogen or C1-C20-alkyl. These compounds are suitable for use as bleaching, oxidizing or disinfecting agents.

公开(公告)号：ES2067450T3

公开(公告)日：1995-04-01

申请号：ES88102260

申请日：1988-02-17

Applicant: HOECHST AG

Inventor： REINHARDT GERD DR

IPC: C07C67/00 ,  C09K23/06 ,  C07C261/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C07C309/03 ,  C07C309/08 ,  C07C309/12 ,  C11D1/28

Abstract: Acyloxyalkanesulphonates of the formula in which R represents C7-C21-alkyl or C7-C21-alkenyl, A represents C2-C4-alkylene and M represents an alkali metal atom or alkaline earth metal atom, are prepared by esterifying carboxylic acids with salts of hydroxyalkanesulphonic acids under mild reaction conditions, carboxylic acids of the general formula R-CO2H being esterified with a salt of the formula HO-A-SO3M in the presence of aqueous hydrochloric acid.

公开(公告)号：DE3852408D1

公开(公告)日：1995-01-26

申请号：DE3852408

申请日：1988-02-17

Applicant: HOECHST AG

Inventor： REINHARDT GERD DR

IPC: C09K23/06 ,  C07C67/00 ,  C07C261/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C07C309/03 ,  C07C309/08 ,  C07C309/12 ,  C11D1/28

Abstract: Acyloxyalkanesulphonates of the formula in which R represents C7-C21-alkyl or C7-C21-alkenyl, A represents C2-C4-alkylene and M represents an alkali metal atom or alkaline earth metal atom, are prepared by esterifying carboxylic acids with salts of hydroxyalkanesulphonic acids under mild reaction conditions, carboxylic acids of the general formula R-CO2H being esterified with a salt of the formula HO-A-SO3M in the presence of aqueous hydrochloric acid.

公开(公告)号：MX9200450A

公开(公告)日：1992-08-01

申请号：MX9200450

申请日：1992-01-31

Applicant: HOECHST AG

Inventor： REINHARDT GERD DR ,  FRIDERICHS VERA ,  RUDOLF ULRIKE

IPC: C11D1/72 ,  C11D1/825 ,  C11D3/39 ,  C11D3/395 ,  C11D17/08 ,  D06L3/00 ,  D06L3/02 ,  C07C409/34

Abstract: Storage-stable aqueous suspensions of organic peracids containing 1 to 50 % by weight of a surfactant mixture consisting of 1 to 4 parts by weight of a C8-C22-fatty alcohol, oxyethylated with 1 to 5 units of ethylene oxide, and 4 to 1 parts by weight of a C8-C22-fatty alcohol, oxyethylated with 6 to 25 units of ethylene oxide, and optionally in addition other conventional components. It is possible owing to the use of two different surfactants to adjust very different viscosity levels in these suspensions, from low viscosity to pasty formulations.