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公开(公告)号：DE69621503D1
公开(公告)日：2002-07-11
申请号：DE69621503
申请日：1996-03-22
Applicant: PHILLIPS PETROLEUM CO
Inventor： BROWN RONALD E , HARPER TIMOTHY P , REED LARRY E , SCHARRE MARK D , GREENWOOD GIL J
Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.
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公开(公告)号：DE69523105T2
公开(公告)日：2002-06-06
申请号：DE69523105
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.
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公开(公告)号：ES2136777T3
公开(公告)日：1999-12-01
申请号：ES95113299
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P
Abstract: A novel method for treating the radiant tubes of a fired pyrolysis heater with an antifoulant composition for inhibiting the formation and deposition of coke thereon. Such novel method includes introducing the antifoulant into the crossover conduit between the convection tubes and radiant tubes of the fired pyrolysis heater.
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公开(公告)号：SG55118A1
公开(公告)日：1998-12-21
申请号：SG1996006632
申请日：1996-03-14
Applicant: PHILLIPS PETROLEUM CO
Inventor： BROWN RONALD E , REED LARRY E , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.
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公开(公告)号：ES2122411T3
公开(公告)日：1998-12-16
申请号：ES95113301
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P
Abstract: The incremental yield of hydrocarbons having five or more carbon atoms in a cracked product from a thermal cracking process is increased by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
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Patent Agency Ranking
公开(公告)号：DE69505215D1
公开(公告)日：1998-11-12
申请号：DE69505215
申请日：1995-08-24
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: The incremental yield of hydrocarbons having five or more carbon atoms in a cracked product from a thermal cracking process is increased by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
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7.发明专利
公开(公告)号：AU672943B2
公开(公告)日：1996-10-17
申请号：AU2851295
申请日：1995-08-11
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , MURTHA TIMOTHY P , BROWN RONALD E , DEGRAFFENRIED JAMES P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: Spalling of coke produced during the thermal cracking of hydrocarbon is promoted by contacting or treating the tubes of a thermal cracking furnace with a composition having an absence of silicon and comprising tin.
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公开(公告)号：AU670527B2
公开(公告)日：1996-07-18
申请号：AU2856995
申请日：1995-08-17
Applicant: PHILLIPS PETROLEUM CO
Inventor： REED LARRY E , BROWN RONALD E , DEGRAFFENRIED JAMES P , MURTHA TIMOTHY P , GREENWOOD GIL J , HARPER TIMOTHY P , SCHARRE MARK D
Abstract: The energy required to achieve a given conversion in the thermal cracking of hydrocarbons is reduced by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
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公开(公告)号：CA1263622A
公开(公告)日：1989-12-05
申请号：CA527321
申请日：1987-01-14
Applicant: PHILLIPS PETROLEUM CO
Inventor： PORTER RANDALL A , REED LARRY E
Abstract: The formation of carbon on metals exposed to hydrocarbons in a thermal cracking process is reduced by contacting such metals with an antifoulant selected from the group consisting of a combination of tin and silicon, a combination of antimony and silicon and a combination of tin, antimony and silicon.
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公开(公告)号：CA1252282A
公开(公告)日：1989-04-11
申请号：CA494321
申请日：1985-10-31
Applicant: PHILLIPS PETROLEUM CO
Inventor： PORTER RANDALL A , REED LARRY E
Abstract: The formation of carbon on metals exposed to hydrocarbons in a thermal cracking process is reduced by contacting such metals with an antifoulant selected from the group consisting of a combination of tin and copper, a combination of antimony and copper and a combination of tin, antimony and copper.
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