公开(公告)号：EG11167A

公开(公告)日：1977-01-31

申请号：EG18474

申请日：1974-05-21

Applicant: STANDARD OIL CO

Inventor： WAMPFLER G ,  CROFT L ,  CROFT G ,  PARK O

IPC: C07C63/14 ,  B01J27/00 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/265 ,  C07C63/15 ,  C07C63/307 ,  C07C67/00 ,  B01J21/06

Abstract: 1467886 Oxidation of di- or tri-methylbenzenes STANDARD OIL CO 15 May 1974 [21 May 1973] 21569/74 Heading C2C A method of oxidizing di- or tri-methylbenzene with molecular oxygen to benzene di- or tri-carboxylic acid or infra-molecular anhydride thereof under liquid phase conditions at temperatures in the range of 130‹ to 275‹ C. comprises conducting said oxidation in the presence of the catalyst system comprising either a source of bromine with manganese and zirconium or a source of bromine with cobalt, manganese and zirconium and wherein said catalyst system provides a total of from 1 to 5 milligram atoms of manganese and cobalt and from 1 to 10 milligram atoms of bromine for each mole of said di- or tri-methylbenzene and from 0À1 to 3À0 milligram atom of zirconium for each milligram atom of manganese and cobalt.

公开(公告)号：BR7404000D0

公开(公告)日：1974-12-03

申请号：BR400074

申请日：1974-05-17

Applicant: STANDARD OIL CO

Inventor： WAMPFLER G ,  CROFT G

IPC: C07C63/14 ,  B01J27/00 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/265 ,  C07C63/15 ,  C07C63/307 ,  C07C67/00 ,  C07C63/02 ,  C07C63/32

Abstract: 1467886 Oxidation of di- or tri-methylbenzenes STANDARD OIL CO 15 May 1974 [21 May 1973] 21569/74 Heading C2C A method of oxidizing di- or tri-methylbenzene with molecular oxygen to benzene di- or tri-carboxylic acid or infra-molecular anhydride thereof under liquid phase conditions at temperatures in the range of 130‹ to 275‹ C. comprises conducting said oxidation in the presence of the catalyst system comprising either a source of bromine with manganese and zirconium or a source of bromine with cobalt, manganese and zirconium and wherein said catalyst system provides a total of from 1 to 5 milligram atoms of manganese and cobalt and from 1 to 10 milligram atoms of bromine for each mole of said di- or tri-methylbenzene and from 0À1 to 3À0 milligram atom of zirconium for each milligram atom of manganese and cobalt.