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公开(公告)号：KR800000427B1
公开(公告)日：1980-05-26
申请号：KR730001523
申请日：1973-09-13
Applicant: STANDARD OIL CO
Inventor： HUGHES R , STEIGELMANN E
Abstract: A gaseous hydrocarbon mixt. was passed through a liq. barrier consisting of complex-forming metal ions in aq. soln., supported in a semipermeable membrane. to give highly selective sepn. of aliph. unsaturated hydrocarbons. Thus, a mixt. contg. ethylene 41.0, methane 22.3, and C2H6 36.7% had C2H4 content 99.948 % ater permeation at 0.471 ml/cm2 min through a cellulose acetate filter, saturated in 1 mole aq. silver nitrate solution and sandwiched between 2 silicone polycarbonate films.
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2.发明授权Method of separating aliphatically unsaturated hydrocarbons by contacting said hydrocarbons with a solid water-insoluble, semi-permeable film membrane 失效通过用固体水不溶性，半透膜形成的膜连接固体碳氢化合物分离偶联的不饱和烃的方法
公开(公告)号：US3770842A
公开(公告)日：1973-11-06
申请号：US3770842D
申请日：1972-06-29
Applicant: STANDARD OIL CO
Inventor： STEIGELMANN E , HUGHES R
Abstract: THERE IS DESCRIBED THE SEPARATION OF ALIPHATICALLY-UNSATURATED HYDROCARBONS FROM GASEOUS MIXTURES BY THE COMBINED USE OF FLOODED-CELL, LIQUID BARRIER PERMEATION AND METAL COMPLEXING TECHNIQUES. THE LIQUID BARRIER IS DISPOSED AS A CONTINUOUS, DISTINCT LIQUID PHASE IN CONTACT WITH A FILM MEMBRANE, AND THE BARRIER CONTAINS COMPLEXFORMING METAL IONS IN AQUEOUS SOLUTION. THE HYDROCARBON FEED GAS IS CONTACTED WITH THE LIQUID BARRIER CONTAINING A SURFACE-ACTIVE AGENT IN SOLUTION IN THE LIQUID BARRIER. THE SURFACE AGENT SERVES TO IMPROVE THE SELECTIVITY OF THE SEPARATION. THE METAL IONS IN THE LIQUID BARRIER MAY BE, FOR EXAMPLE, NOBLE METAL, NICKEL, MERCURIC, CUPROUS OR OTHER METAL IONS, AND MIXTURES OF THE METAL IONS, WITH OR WITHOUT OTHER CATIONS, MAY BE USED. THE SEPARATION OF ETHYLENE FROM ETHANE AND METHANE IS OF PARTICULAR INTEREST.
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公开(公告)号：US3823529A
公开(公告)日：1974-07-16
申请号：US33500073
申请日：1973-02-23
Applicant: STANDARD OIL CO
Inventor： HUGHES R , STEIGELMANN E
CPC classification number: B01D53/228 , B01D53/22 , C07C7/156 , C07C9/06
Abstract: There is described the separation of carbon monoxide from gaseous mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is in contact with a semi-permeable film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The metal ions may be, for example, cuprous or other metal ions, and mixtures of these metal ions, with or without other cations, may be used. The separation of carbon monoxide from lower alkanes, e.g., ethane and methane, or hydrogen is of particular interest.
Abstract translation: 描述了通过液体屏障渗透和金属络合技术的组合使用从气态混合物中分离一氧化碳。 液体屏障与半透膜膜接触，屏障在水溶液中含有络合物形成金属离子。 金属离子可以是例如亚铜或其它金属离子，并且可以使用具有或不具有其它阳离子的这些金属离子的混合物。 一氧化碳与低级烷烃（例如乙烷和甲烷）或氢气的分离是特别有意义的。
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公开(公告)号：US3758605A
公开(公告)日：1973-09-11
申请号：US3758605D
申请日：1972-09-13
Applicant: STANDARD OIL CO
Inventor： HUGHES R , STEIGELMANN E
Abstract: There is described the separation of aliphatically-unsaturated hydrocarbons from mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is within a hydrophilic film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The metal ions may be, for example, noble metal, nickel, mercurous, cuprous or other metal ions, and mixtures of these metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
Abstract translation: 描述了通过组合使用液体屏障渗透和金属络合技术从混合物中分离脂族不饱和烃。 液体屏障在亲水膜膜内，屏障在水溶液中含有复合物形成金属离子。 金属离子可以是例如贵金属，镍，汞，亚铜或其它金属离子，并且可以使用这些金属离子与或不与其它阳离子的混合物。 乙烯与乙烷和甲烷的分离是特别有意义的。
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公开(公告)号：US3844735A
公开(公告)日：1974-10-29
申请号：US28878272
申请日：1972-09-13
Applicant: STANDARD OIL CO
Inventor： STEIGELMANN E , HUGHES R
IPC: C07C7/144 , B01D53/22 , B01D61/38 , B01D65/10 , C07C1/00 , C07C7/152 , C07C11/00 , C07C11/02 , C07C13/02 , C07C67/00
CPC classification number: B01D61/38 , B01D53/228 , C07C7/152 , Y02P20/51 , C07C11/04
Abstract: There is described the separation of aliphatically unsaturated hydrocarbons from gaseous mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is present essentially in a solid matrix that is a film membrane or is in contact with a film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The liquid barrier is in contact with a relatively non-volatile, hygroscopic agent that may be in solution in the liquid barrier or composited with the solid matrix, This agent may serve to reduce the loss of water from the liquid barrier which loss may otherwise be excessive. The hygroscopic agent when composited within a hydrophilic film membrane, may serve to increase the permeability of the film and maintain the strength of the film when it is swollen with the aqueous liquid barrier. The metal ions in the liquid barrier may be, for example, noble metal, nickel, mercurous, cuprous or other metal ions, and mixtures of the metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
Abstract translation: 描述了通过液体屏障渗透和金属络合技术的组合使用从气态混合物中分离脂族不饱和烃。 液体屏障基本上存在于作为膜膜或与膜膜接触的固体基质中，并且阻挡层在水溶液中含有复合物形成金属离子。 液体屏障与可能在液体屏障溶液中或与固体基质复合的相对不挥发的吸湿剂接触。该试剂可用于减少液体屏障中的水分损失，否则这种损失可能是 过多。 当在亲水膜膜内复合时，吸湿剂可用于增加膜的渗透性并且当其与水性液体屏障一起溶胀时保持膜的强度。 液体屏障中的金属离子可以是例如贵金属，镍，汞，亚铜或其它金属离子，并且可以使用具有或不具有其它阳离子的金属离子的混合物。 乙烯与乙烷和甲烷的分离是特别有意义的。
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Patent Agency Ranking
公开(公告)号：US3812651A
公开(公告)日：1974-05-28
申请号：US27321572
申请日：1972-07-19
Applicant: STANDARD OIL CO
Inventor： STEIGELMANN E
Abstract: There is described the separation of aliphatically-unsaturated hydrocarbons of two to four carbon atoms from gaseous mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is in contact with a film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The film membrane is contacted with a swelling agent to increase the selectivity of the separation and, preferably, increase permeation by the aliphatically unsaturated hydrocarbon to be separated. The metal ions in the liquid barrier may be, for example, noble metal, nickel, mercurous, cuprous or other metal ions, and mixtures of the metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
Abstract translation: 描述了通过组合使用液体屏障渗透和金属络合技术从气态混合物中分离出二至四个碳原子的脂族不饱和烃。 液体屏障与膜膜接触，屏障在水溶液中含有复合物形成金属离子。 膜膨胀剂与溶胀剂接触以提高分离的选择性，优选增加被分离的脂肪族不饱和烃的渗透。 液体屏障中的金属离子可以是例如贵金属，镍，汞，亚铜或其它金属离子，并且可以使用具有或不具有其它阳离子的金属离子的混合物。 乙烯与乙烷和甲烷的分离是特别有意义的。
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公开(公告)号：US3800506A
公开(公告)日：1974-04-02
申请号：US3800506D
申请日：1972-08-23
Applicant: STANDARD OIL CO
Inventor： HUGHES R , STEIGELMANN E
CPC classification number: B01D67/0088 , B01D61/38 , B01D69/12 , C07C7/152 , C07C11/04
Abstract: There is described the separation of aliphatically-unsaturated hydrocarbons from gaseous mixtures by the combined use of flooded-cell, liquid barrier permeation and metal complexing techniques. The liquid barrier is disposed as a continuous, distinct or separate liquid phase in contact with a film membrane composite, and the barrier contains complex-forming metal ions in aqueous solution. The film is composed of a hydrophobic membrane having a hydrophilic surface on its feed inlet side. The hydrocarbon feed gas is contacted with the liquid barrier and the presence of the hydrophilic surface on the feed inlet side of the hydrophobic film membrane serves to improve the selectivity of the separation. The metal ions in the liquid barrier may be, for example, noble metal, nickel, mercurous, cuprous or other metal ions, and mixtures of metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
Abstract translation: 描述了通过组合使用淹水池，液体屏障渗透和金属络合技术从气态混合物中分离脂族不饱和烃。 液体屏障被设置为与薄膜复合材料接触的连续，不同或分离的液相，并且阻挡层在水溶液中含有络合物形成金属离子。 膜由在其进料口侧具有亲水性表面的疏水性膜构成。 烃进料气体与液体阻挡层接触，并且疏水膜膜的进料入口侧的亲水表面的存在用于提高分离的选择性。 液体阻挡层中的金属离子可以是例如贵金属，镍，汞，亚铜或其它金属离子，并且可以使用具有或不具有其它阳离子的金属离子的混合物。 乙烯与乙烷和甲烷的分离是特别有意义的。
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公开(公告)号：US3758603A
公开(公告)日：1973-09-11
申请号：US3758603D
申请日：1972-05-12
Applicant: STANDARD OIL CO
Inventor： STEIGELMANN E , HUGHES R
CPC classification number: C07C7/152 , B01D61/38 , B01D71/56 , C07C7/156 , C07C11/24 , C07C11/02 , C07C11/04
Abstract: There is described the separation of aliphatically unsaturated hydrocarbons from mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is in contact with a film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The metal ions may be, for example, noble metal, mercuric, cuprous or other metal ions, and mixtures of these metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
Abstract translation: 描述了通过组合使用液体屏障渗透和金属络合技术从混合物中分离脂族不饱和烃。 液体屏障与膜膜接触，屏障在水溶液中含有复合物形成金属离子。 金属离子可以是例如贵金属，汞，亚铜或其它金属离子，并且可以使用这些金属离子与有或没有其它阳离子的混合物。 乙烯与乙烷和甲烷的分离是特别有意义的。
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公开(公告)号：BR7306902D0
公开(公告)日：1974-07-18
申请号：BR690273
申请日：1973-09-05
Applicant: STANDARD OIL CO
Inventor： HUGHES R , STEIGELMANN E
Abstract: There is described the separation of aliphatically-unsaturated hydrocarbons from mixtures by the combined use of liquid barrier permeation and metal complexing techniques. The liquid barrier is within a hydrophilic film membrane, and the barrier contains complex-forming metal ions in aqueous solution. The metal ions may be, for example, noble metal, nickel, mercurous, cuprous or other metal ions, and mixtures of these metal ions, with or without other cations, may be used. The separation of ethylene from ethane and methane is of particular interest.
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