Abstract:
A new class of nanostructured RE-doped SiO2-base materials that display superior fluorescence properties is provided. In particular, high gain combined with a broad and flat spectral band width is observed in material composed of a high fraction of a nano-dispersed metastable silicate phase in a glassy SiO2 matrix, produced by partial devitrification (crystallization) of several glassy Al2O3/Er2O3- and Y2O3/Er2O3-doped SiO2 compositions. Also, a highly deconvoluted spectral emission, with several prominent peaks, is observed in completely devitrified material, consisting of a uniform nano-dispersion of an equilibrium silicate phase in a crystobalite SiO2 matrix. Such enhanced fluorescence properties were observed in heat treated nanopowders prepared by vapor-phase, solgel, rapid solidification, and spray-pyrolysis methods.
Abstract translation:提供了一类新型的具有优异荧光性能的纳米结构的RE掺杂SiO 2基体材料。 特别地,在通过部分失透反应产生的玻璃状SiO 2基体中的高分数纳米分散的亚稳态硅酸盐相组成的材料中观察到具有宽的和平坦的光谱带宽的高增益( 几个玻璃状的Al 2 O 3 / O 2 O 3 - 和Y 2的结晶, O 3组成的二氧化硅组合物。 此外,在完全失透的材料中观察到具有几个突出的峰的高度去卷积的光谱发射,由平底硅酸盐相在均匀的SiO 2基体中的均匀的纳米分散体组成。 在通过气相,溶胶凝胶,快速凝固和喷雾热解方法制备的热处理纳米粉末中观察到这种增强的荧光性质。
Abstract:
A quartz glass lamp vessel 1 or 21 is used in many types of lamps. Sometimes it is expedient to absorb a certain portion of the emission spectrum. In accordance with the prior art this is possible by including rare earth metal oxides in the quartz glass.The solubility of rare earth metal oxides in quartz glass is, however, limited.According to the invention, quartz glass is used which contains an alkali metal oxide and optionally, an alkaline earth metal oxide, in addition to a rare earth metal oxide. The alkali metal oxide increases the solubility of the rare earth metal oxide, so that rare earth metal oxides can be used in larger concentrations. This results in glasses which have a higher degree of absorption, from which lamp vessels can be produced.