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公开(公告)号:US11220519B2
公开(公告)日:2022-01-11
申请号:US17267601
申请日:2019-07-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Simona Guidotti , Dario Liguori , Giampiero Morini , Gianni Vitale
IPC: C07F7/28 , C07F3/02 , C07F9/94 , C08F210/06
Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, halogen and an electron donor obtained from a process including the steps:
(a) dissolving a Mg(OR)2 compound wherein R groups, equal to or different from each other, are C1-C15 hydrocarbon groups optionally containing a heteroatom selected from O, N and halogen, in an organic liquid medium, thereby forming a first liquid mixture;
(b) contacting the first liquid mixture (a) with TiCl4, thereby forming a second liquid mixture absent a solid phase, and
(c) subjecting the second liquid mixture (b) to conditions, whereby solid catalyst particles are formed,
wherein (i) a Bi compound and (ii) a bidentate electron donor compound are present in one or more of steps (a) to (c) and/or contacted with the solid catalyst particles obtained from (c).-
公开(公告)号:US11186664B2
公开(公告)日:2021-11-30
申请号:US16647672
申请日:2018-08-30
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Claudio Cavalieri , Davide Tartari , Tiziana Caputo , Isabella Maria Vittoria Camurati
IPC: C08F210/16 , C08F210/06 , C08F2/34 , C08L23/14
Abstract: A propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %; and vii) C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol % and C13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.
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公开(公告)号:US20210309892A1
公开(公告)日:2021-10-07
申请号:US17261100
申请日:2019-07-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTA MARCHINI , SILVIA GUERRA , STEFANO PASQUALI , ANKUR RASTOGI , STEFANO SPATARO
IPC: C09J123/20
Abstract: A polyolefin-based hot melt adhesive composition made from or containing
(A) 25-75 wt. % of a copolymer of butene-1 with a Melt Flow Rate, measured according to ISO 1133 (190° C., 2.16 kg), higher than 1500; and (B) 75-25 wt. % of at least one additional component selected from the group consisting of waxes, resins, plasticizers, additional polymers and mixtures thereof, wherein the amounts of A) and B) are referred to the total weight of A)+B).-
公开(公告)号:US11041033B2
公开(公告)日:2021-06-22
申请号:US16633185
申请日:2018-08-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Roberta Marchini , Stefano Spataro , Roberta Pica
IPC: C08F10/08 , C08L23/20 , C08F210/08 , C09J123/20 , C08F210/16
Abstract: A butene-1 polymer having: a) a Melt Flow Rate value of from 20 to less than 100 g/10 min., measured according to ISO 1133 at 190° C. with a load of 2.16 kg; b) an intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135° C. equal to lower than 0.95 dl/g; c) a Mw/Mn value equal to or lower than 3.5 and a lower limit of 1.5; d) a Mz value of 180,000 g/mol or higher; and e) optionally, a comonomer content of up to 10% by weight.
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公开(公告)号:US11021555B2
公开(公告)日:2021-06-01
申请号:US16317676
申请日:2017-07-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Tiziano Dall'Occo , Simona Guidotti , Dario Liguori , Giampiero Morini
IPC: C08F210/16
Abstract: A catalyst component for the polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from the group consisting of aliphatic cyclic ethers and alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from the group consisting of Zn and Cu, wherein the catalyst component is devoid of Zn—C or Cu—C bonds and the Mg/Ti molar ratio ranges from 4.0 to 50.0.
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公开(公告)号:US20210130509A1
公开(公告)日:2021-05-06
申请号:US16633259
申请日:2018-08-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTA MARCHINI , STEFANO SPATARO , ROBERTA PICA
IPC: C08F10/08 , C08F210/08 , C08F2/00 , C08F4/659 , C08F4/6592 , C08L23/20 , B01J19/00 , C09J123/20 , C08F210/16
Abstract: A butene-1 polymer composition having MFR values of from 20 to less than 100 g/10 min., measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing: A) a butene-1 homopolymer or a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; and B) a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 20% by mole; wherein the composition having a total copolymerized comonomer content from 4% to 15% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 75% by weight or less, determined on the total weight of A) and B).
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公开(公告)号:US20210087307A1
公开(公告)日:2021-03-25
申请号:US16613655
申请日:2018-05-09
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: DIEGO BRITA , SIMONA GUIDOTTI
Abstract: A catalyst mixture made from or containing (a) particles of a solid catalyst component comprising Ti, Mg, Cl, and (b) from 0.5 to 5.0% by weight, based upon the total weight of the mixture, of particles of a solid compound having particle size ranging from 0.1 μm to 1 mm containing more than 50% by weight of SiO2 units.
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公开(公告)号:US20200376458A1
公开(公告)日:2020-12-03
申请号:US16636774
申请日:2018-07-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GIAN LUCA BONACCORSI , GIUSEPPE PENZO , ENRICO BALESTRA , MAURIZIO DORINI , RICCARDO RINALDI
Abstract: A manhole for a polymerization unit having a through-hole formed with a shoulder matching a corresponding shoulder of a plug of a closure member operatively inserted in the through-hole. The through-hole can be closed with a minimum clearance, such that polymer particles do not deposit in the gap between the wall of the unit and the plug of the closure member.
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公开(公告)号:US10792637B2
公开(公告)日:2020-10-06
申请号:US16477283
申请日:2017-12-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Enrico Balestra , Tiziana Caputo , Massimo Covezzi , Maurizio Dorini , Antonio Mazzucco , Gabriele Mei , Ricardo Rinaldi
Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing the fluid into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D>0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.
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公开(公告)号:US20200308381A1
公开(公告)日:2020-10-01
申请号:US16617403
申请日:2018-05-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GIANNI VITALE , FABRIZIO PIEMONTESI , BENEDETTA GADDI , GIANNI COLLINA , GIAMPIERO MORINI , CAROLINE CATHELIN , MARCO CIARAFONI , GIANPIERO FERRARO , CLAUDIO CAVALIERI , PAOLA MASSARI , MICHELE GRAZZI
IPC: C08L23/12 , C08F210/02 , C08F210/06 , C08F2/00 , C08F4/646 , C08F4/649 , C08F4/657
Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %, based upon the total weight of the polypropylene composition, of a propylene homopolymer; and B) from 10 wt % to 50 wt %, based upon the total weight of the polypropylene composition, of a copolymer of propylene and ethylene having from 30.0 wt % to 70.0 wt %, based upon the total weight of the copolymer, of ethylene derived units; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 and 4.0 dl/g; ii) a MFR L from 0.5 to 100 g/10 min; and iii) a xylene soluble fraction ranging from 10 wt % to 50 wt %, based upon the total weight of the polypropylene composition.
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