Process for the preparation of tertiary amines from primary amines and nitriles
    93.
    发明公开
    Process for the preparation of tertiary amines from primary amines and nitriles 审中-公开
    Verfahren zur HerstellungtertiärerAmine ausprimärenAminen und Nitrilen

    公开(公告)号:EP2264006A1

    公开(公告)日:2010-12-22

    申请号:EP10179198.6

    申请日:2002-11-05

    Abstract: Disclosed is a method for preparing tertiary amine compounds from primary amines and nitriles in the presence of hydrogen gas and metal catalyst, or metal-containing catalyst composition, at a temperature from about 50°C to about 200°C and at a pressure from about 100 psig to 1500 psig. The primary amines and the nitriles used in the process may be diamines and/or dinitriles, or may be combinations of primary amines and/or nitriles. Also disclosed and novel tertiary amine compounds made by the described method.

    Abstract translation: 公开了一种在氢气和金属催化剂或含金属的催化剂组合物存在下,在约50℃至约200℃的温度和约约压力下从伯胺和腈制备叔胺化合物的方法 100 psig至1500 psig。 在该方法中使用的伯胺和腈可以是二胺和/或二腈,或者可以是伯胺和/或腈的组合。 还公开了通过所述方法制备的新型叔胺化合物。

    A selective synthesis of organophosphites
    95.
    发明公开
    A selective synthesis of organophosphites 有权
    选择性合成有机亚磷酸酯

    公开(公告)号:EP2239248A2

    公开(公告)日:2010-10-13

    申请号:EP10170520.0

    申请日:2003-12-02

    CPC classification number: C07F9/146 C07F9/142 C07F9/145

    Abstract: Disclosed herein is a process for the selective synthesis of triorganophosphite intermediates, including mono- and di-phosphites, from phosphorus trihalides, alcohols and triorganoamines where the alcohol and the triorganoamine are added either (a) separately but concurrently and continuously, (b) separately, concurrently but discontinuously, or (c) separately, discontinuously and in alternating portions of triorganoamine and alcohol.

    Abstract translation: 本文所公开的是用于磷酸三有机酯的中间体,包括单 - 和二 - 亚磷酸酯,由三卤化磷,醇和triorganoamines其中加入醇和triorganoamine的选择性合成的方法或者(a)分别但同时地和连续地,(B)分别 ,同时但不连续地,或(c)分开地,不连续地并且交替地部分三有机胺和醇。

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