公开(公告)号：KR1020100011542A

公开(公告)日：2010-02-03

申请号：KR1020080072800

申请日：2008-07-25

Applicant: 한국화학연구원

Inventor： 정순용 ,  김철웅 ,  정광은 ,  채호정 ,  서곤 ,  박지원 ,  김선중

IPC: C07C2/86 ,  C07C11/02

Abstract: PURPOSE: A method for preparing light olefins is provided to obtain propylene and butane selectively at yield more than 60 weight%, especially to obtain butane at 30 weight% yield. CONSTITUTION: A method for preparing light olefins using a mordenite catalyst comprises a step of preparing C2~C4 olefins by reacting an oxygen-containing compound in the presence of the mordenite catalyst with an Si/Al molar ratio of 80~150. The sum of butene and propylene is 60 weight% or more and the yield of butane is 20 weight% or more. The BET specific surface area of the mordenite catalyst is 400~500 m^2/g.

Abstract translation: 目的：提供一种制备轻质烯烃的方法，以产率大于60重量％选择性地获得丙烯和丁烷，特别是以30重量％的产率获得丁烷。 构成：使用丝光沸石催化剂制备轻质烯烃的方法包括在丝光沸石催化剂存在下使含氧化合物与Si / Al摩尔比为80〜150的反应制备C 2 -C 4烯烃的步骤。 丁烯和丙烯的总和为60重量％以上，丁烷的收率为20重量％以上。 丝光沸石催化剂的BET比表面积为400〜500m 2 / g。

公开(公告)号：KR100915025B1

公开(公告)日：2009-09-02

申请号：KR1020070139303

申请日：2007-12-27

Applicant: 한국화학연구원 ,  에스케이이노베이션 주식회사

Inventor： 정순용 ,  정광은 ,  김철웅 ,  채호정 ,  김규태 ,  윤영식 ,  안형웅 ,  박삼룡 ,  오승훈 ,  김경록 ,  유재욱

IPC: B01J21/08 ,  B01J23/00 ,  B01J37/02

Abstract: 본 발명은 선택산화탈황용 촉매와 이의 제조방법에 관한 것으로, 더욱 상세하게는 특정의 기공 크기, 벽두께, 입자 크기, 및 비표면적을 갖는 중기공성 실리카 분자체에, 전이금속을 일정 함량 비율로 담지시킨 선택산화탈황용 촉매와 추가적으로 상기 실리카 분자체의 표면이 실릴화된 선택산화탈황용 촉매를 제공함으로써, 높은 황화합물 함량을 갖는 석유계 탄화수소에 대한 선택적 산화탈황성능을 최대로 하고, 선택산화탈황 반응의 부산물인 술폰화합물이 촉매의 담체로 침적되는 것을 방지하여 촉매의 수명을 최대로 연장시킨 선택산화탈황용 촉매 및 이의 제조방법에 관한 것이다.

公开(公告)号：KR100908495B1

公开(公告)日：2009-07-24

申请号：KR1020070058543

申请日：2007-06-14

Applicant: 한국화학연구원 ,  주식회사 신영에프엔씨

Inventor： 김철웅 ,  정순용 ,  정광은 ,  김영남

IPC: A23L1/237

Abstract: The iodine-free salt suitable for thyroid patients, and a method for preparing the iodine-free salt are provided to make the iodine-free salt having a flower shape, to reduce the solid part insoluble in water and to improve the taste and preference. The iodine-free salt is prepared by adding 1-10 parts by weight of the saturated refined salt aqueous solution containing 2-5 ppb of iodine to 1 part by weight of the bay salt containing 50-300 ppm of iodine, and filtering and washing it to make the bay salt containing 1-10 ppm of iodine; and mixing 1-5 parts by weight of the washed bay salt and 5-9 parts by weight of the refined salt containing 2-5 ppb of iodine in water and crystallizing it by evaporation at 70-100 deg.C.

Abstract translation: 提供适用于甲状腺患者的无碘盐，以及制备无碘盐的方法，以制成具有花形状的无碘盐，以减少不溶于水的固体部分并改善味道和偏好。 不含碘盐是通过将1-10重量份含有2-5ppb碘的饱和精制盐水溶液添加到1重量份含有50-300ppm碘的海湾盐中，过滤并洗涤 它使海湾盐含有1-10ppm的碘; 将1-5重量份洗涤后的海湾盐和5-9重量份含有2-5ppb碘的精制盐在水中混合，并在70-100℃下蒸发结晶。

公开(公告)号：KR1020090071097A

公开(公告)日：2009-07-01

申请号：KR1020070139303

申请日：2007-12-27

Applicant: 한국화학연구원 ,  에스케이이노베이션 주식회사

Inventor： 정순용 ,  정광은 ,  김철웅 ,  채호정 ,  김규태 ,  윤영식 ,  안형웅 ,  박삼룡 ,  오승훈 ,  김경록 ,  유재욱

IPC: B01J21/08 ,  B01J23/00 ,  B01J37/02

CPC classification number: B01J21/08 ,  B01J23/00 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/02

Abstract: A catalyst for selective oxidative desulfurization and a manufacturing method thereof are provided to extend a lifetime of the catalyst and to maximize selective oxidation desulphurization capacity about the petroleum hydrocarbon having high sulfide content. A catalyst for selective oxidative desulfurization includes 0.5 ~ 10 weight part of a transition metal dipped in a mesopore silica molecule having 2 ~ 10 nm of pore size, 14 ~ 20 Å of wall thickness, 0.1 ~ 1.0 mum of particle size, and 500 ~ 1400 m^2/g of specific surfacearea. The surface of the catalyst for selective oxidative desulfurization is sylilated by a silylating agent of 0.05 ~ 1.0 molar ratio based on a molar ratio of a silica molecule. The silylating agent is a silane compound selected among C1-20 alkyl silane, C1-20 alkylsilazane, and C1-20 alkoxy silane. The transition metal is a single transition metal or the transition metals more than 2 kinds selected from 4B, 5B, 6B, 7B and 8B family.

Abstract translation: 提供了一种用于选择性氧化脱硫的催化剂及其制备方法，以延长催化剂的使用寿命，并使围绕具有高硫化物含量的石油烃的选择性氧化脱硫能力最大化。 用于选择性氧化脱硫的催化剂包括浸渍在细孔二氧化硅分子中的过渡金属0.5〜10重量份，壁厚为2〜10nm，壁厚为14〜20μm，粒径为0.1〜1.0μm， 1400 m ^ 2 / g比表面积。 用于选择性氧化脱硫的催化剂的表面基于二氧化硅分子的摩尔比，通过0.05〜1.0摩尔比的甲硅烷基化剂进行甲基化。 甲硅烷基化剂是选自C 1-20烷基硅烷，C 1-20烷基硅氮烷和C 1-20烷氧基硅烷的硅烷化合物。 过渡金属是选自4B，5B，6B，7B和8B族的单一过渡金属或多于2种的过渡金属。

公开(公告)号：KR1020090028018A

公开(公告)日：2009-03-18

申请号：KR1020070093270

申请日：2007-09-13

Applicant: 한국화학연구원 ,  현대엔지니어링 주식회사

Inventor： 정순용 ,  김철웅 ,  정광은 ,  채호정

IPC: B01J29/85

CPC classification number: B01J29/85 ,  B01J35/1023 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  C07C1/20

Abstract: A method for manufacturing a silicoaluminophosphate molecular sieve with high performance and stability to manufacture of light olefins and a method for manufacturing the light olefins using the same are provided to increase MTO reactivity efficiency, catalyst life, and a catalyst synthesis yield by optimizing size of a crystal. A method for manufacturing a silicoaluminophosphate catalyst to manufacture of light olefins comprises the following steps of: manufacturing aluminum phosphate gel by mixing water, an alumina precursor, a phosphoric acid; adding an organic template is added in the aluminum phosphate gel; manufacturing synthesized gel by agitating the aluminum phosphate gel and the organic template; dissolving silica after mixing and agitating a DEA organic template and a silica precursor; mixing a silica-dissolved mixture with the synthetic gel; manufacturing SAPO-34 containing the organic template; and the manufacturing the SAPO-34 removed the organic template.

Abstract translation: 提供了一种制造轻质烯烃制造的高性能和稳定性的硅铝磷酸盐分子筛的方法，以及使用其制备轻质烯烃的方法，以通过优化尺寸来增加MTO反应性效率，催化剂寿命和催化剂合成产率 水晶。 制造轻质烯烃的硅铝磷酸盐催化剂的方法包括以下步骤：通过混合水，氧化铝前体，磷酸制备磷酸铝凝胶; 在磷酸铝凝胶中加入添加有机模板; 通过搅拌磷酸铝凝胶和有机模板制备合成凝胶; 在混合和搅拌DEA有机模板和二氧化硅前体之后溶解二氧化硅; 将二氧化硅溶解的混合物与合成凝胶混合; 制造含有有机模板的SAPO-34; 并且制造SAPO-34移除了有机模板。

公开(公告)号：KR1020090012557A

公开(公告)日：2009-02-04

申请号：KR1020070076482

申请日：2007-07-30

Applicant: 한국화학연구원 ,  에스케이이노베이션 주식회사

Inventor： 정순용 ,  김철웅 ,  정광은 ,  채호정 ,  안화승 ,  김규태 ,  윤영식 ,  안형웅 ,  박삼룡 ,  오승훈 ,  김경록 ,  유재욱

IPC: C07C49/213

Abstract: A method for producing tetralone is provided to improve the conversion ratio and selectivity of tetralone by using a heterogeneous catalyst containing transition metals and to maintain the durability and activity of catalyst although the catalyst is reused by a cleaning process. In a method for producing tetralone by performing the oxidation of the liquid portion of tetralin in the presence of a catalyst system and oxidant, the catalytic system is a heterogeneous catalyst containing molecular sieve 99.5~95 mole % and transition metal 0.5~5.0 mole % and the reaction is performed at 20~150 °C for 2~12 hours with a stirring speed of 50~1000 rpm.

Abstract translation: 提供了制备四氢萘酮的方法，以通过使用含有过渡金属的多相催化剂来提高四氢萘酮的转化率和选择性，并且保持催化剂的耐久性和活性，尽管催化剂通过清洗方法再利用。 在催化剂体系和氧化剂的存在下，通过进行四氢化萘的液体部分的氧化生产四氢萘酮的方法，催化体系是含有分子筛99.5〜95摩尔％，过渡金属0.5〜5.0摩尔％的多相催化剂， 反应在20〜150℃下进行2〜12小时，搅拌速度为50〜1000rpm。