Abstract:
PURPOSE: A positive active material is provided to obtain a capacity of 220mAhg^-1 or more and to improve the charging and discharging properties and high voltage performance of a lithium secondary battery. CONSTITUTION: A thickness of a positive active material has a plate with a thickness of 1-30nm and is represented by chemical formula 1, Ni_xCo_yMn_(1-x-y-z)M_z(OH). The positive active material is manufactured using the precursor. The size of a primary particle is 1-500nm and is represented by chemical formula 2, Li_wNi_xCo_yMn_(1-x-y-z)M_zO_2. In the chemical formulas, 1.2
Abstract:
PURPOSE: A negative electrode material for lithium secondary batteries is provided to have extremely high charging voltage when used in the negative electrode by having extremely low discharging voltage, thereby providing energy density of a battery. CONSTITUTION: A negative electrode material for lithium secondary batteries is represented by chemical formula: Li_aV_bO_c and is a lithium-vanadium complex oxide that lithium ions can be inserted into/separated from the lithium-vanadium complex oxide. In chemical formula, a/b≥3.0 and c= Ua+5b ^/2. A manufacturing method of the negative electrode material comprises: a step of manufacturing a uniform mixture by mixing a lithium supply source which contains oxygen atoms, and a vanadium supply source which contains oxygen atoms; and a step of heat-treating the lithium-vanadium complex oxide by heat-treating the uniform mixture under an oxidation atmosphere.