Polymers containing Sulphhydryl Groups

    公开(公告)号:GB1158576A

    公开(公告)日:1969-07-16

    申请号:GB3503866

    申请日:1966-08-04

    Applicant: OREAL

    Abstract: 1,158,576. Hair preparation. L'OREAL. 4 Aug., 1966 ![5 Aug., 1965], No. 35038/66. Heading A5B. [Also in Divisions C3, C4 and D1] A hair-dressing composition comprises a polymer consisting of recurring units of formula in which Q is derived from an anhydride radical of formula or the corresponding acid radical and -NH-M represents a mercaptoamine radical, and optionally also of recurring units of the formula in which X represents OH; or -NH(CH 2 CH 2 CH 2 R 4 wherein R 4 is hydrogen, alkyl of 1 to 4 carbon atoms or-N 1 , which may be the same or different, represents alkyl or I to 4 carbon atoms or r and r 1 , together with the nitrogen atom to which they are attached, form a saturated mononuclear heterocyclic ring and m is 0, 1, 2, 3 or 4 and a compatible diluent.

    Coloured Copolymers suitable for use in Hair Lacquers and Wave Setting Lotions

    公开(公告)号:GB1153061A

    公开(公告)日:1969-05-21

    申请号:GB2139366

    申请日:1966-05-13

    Applicant: OREAL

    Abstract: 1,153,061. Hair lacquers &c. L'OREAL. 13 May, 1966 [13 May, 1965; 20 April, 1966], No. 21393/66. Heading ASB. [Also in Divisions C3 and C4] Hair lacquers and wave-setting lotions comprise an alcoholic or aqueous alcoholic solution of at least one coloured addition copolymer of (a) at least one monomer free from epoxy groups and (b) at least monomer having an epoxy group, said copolymer having bonded thereto at least one dyestuff containing an extra nuclear primary or secondary amine group, and said amine group being condensed with said epoxy group. Monomer component (a) may be selected from vinyl acetate, N- vinyl-pyrrolidone, alkyl acrylates and methacrylates, and acrylamide, methacrylamide and their substituted derivatives. Component (b) is preferably selected from glycidyl acrylate, glycidyl metnacrylate and allyl glycidyl ether. The compositions may additionally include a colourless polymer such as polyvinyl pyrrolidone or a vinyl pyrrolidone/vinyl acetate copolymer. Other optional components include plasticisers, perfumes, surface-active or wetting agents, penetrating agents, and aerosol propellants.

    New copolymers and cosmetics applications thereof

    公开(公告)号:GB1103284A

    公开(公告)日:1968-02-14

    申请号:GB867866

    申请日:1966-02-28

    Applicant: OREAL

    Abstract: The invention comprises copolymers of (a) vinyl acetate, (b) crotonic acid and (c) at least one acrylic or methacrylic ester of the formula where R represents hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of formula where R11 is ethyl, isopropyl, butyl, isobutyl or chloroethyl, and salts of these copolymers. The copolymers preferably contain 75 to 85% by weight of vinyl acetate, 5 to 15% by weight of crotonic acid and 5 to 15% by weight of component (c). Suitable salts include those with ammonia, monoethanolamine, monoethylamine, dimethylamine, diethylamine, aminoethylamine, ethanolamine, monoisopropanolamine, 2 - amino - 2 - methyl - propanol - 1, or 2 - amino - 2 - methyl - propanediol - 1,3. Solutions of the salts, preferably in the form of aerosol lacquers, may be used as cosmetics. The aerosol lacquer may contain alcohol and a propellant gas preferably a halogenated hydrocarbon.ALSO:Aerosol compositions comprise solutions of salts of copolymers of (a) vinyl acetate; (b) crotonic acid; and (c) at least one acrylic or methacrylic ester of the formula where R is hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of the formula CH2 = CH-O-R11, where R11 is ethyl, isopropyl butyl, isobutyl or chloroethyl. The aerosol lacquers are used as cosmetic products and also contain alcohols and propellant gas. Preferred alcohols are anhydrous ethanol or isopropanol and preferred propellant gases are halogenated hydrocarbons. In examples fluorinated hydrocarbons, butyl phthalate, ethyl alcohol, isopropyl palmitate, triethylene glycol, water and isopropyl myristate are used.ALSO:Hair lacquers and lotions comprise solutions of salts of copolymers of (a) vinyl acetate, (b) crotonic acid and (c) at least one acrylic or methacrylic ester of the formula where R is hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of the formula CH2=CH-O-R11 where R11 is ethyl, isopropyl, butyl, isobutyl or chloroethyl. The products are preferably in the form of aerosol lacquers which preferably include alcohols and propellant gases. Preferred alcohols are anhydrous ethanol or isopropanol and preferred propellant gases are halogenated hydrocarbons. In Examples fluorinated hydrocarbons, butyl pthalate, ethyl alcohol, isopropyl palmitate, triethylene glycol, water and isopropyl myristate are used. Conventional cosmetics additives, e.g. plastisizers, perfumes and dyestuffs may also be incorporated.

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