公开(公告)号：DE69033814T2

公开(公告)日：2002-05-29

申请号：DE69033814

申请日：1990-01-30

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： AOKI ISAO ,  TABUCHI TAKANORI ,  MINAMIDA ISAO

IPC: A01N33/18 ,  A01N35/08 ,  A01N37/52 ,  A01N43/40 ,  A01N43/42 ,  A01N43/60 ,  A01N43/78 ,  C07C201/06 ,  C07C201/14 ,  C07C205/08 ,  C07C205/09 ,  C07C209/08 ,  C07C211/27 ,  C07C211/29 ,  C07D213/38 ,  C07D213/61 ,  C07D213/64 ,  C07D213/70 ,  C07D213/74 ,  C07D215/08 ,  C07D215/12 ,  C07D239/26 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D277/42 ,  C07D213/36 ,  C07D241/12

Abstract: Methods for the production of 1,1,1,-trihalogeno-2-nitroethanes from 1,1-dihalogenoethylene by using nitric acid or its salt and hydrogen chloride or hydrogen bromide or its salt, and for the production of alpha-unsaturated amines from the 1,1,1-trihalogeno-2-nitroethanes which are useful as insecticides.

公开(公告)号：DE68929307T2

公开(公告)日：2002-03-14

申请号：DE68929307

申请日：1989-12-27

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： UNEME HIDEKE ,  IWANAGA KOICHI ,  HIGUCHI NORIKO ,  MINAMIDA ISAO ,  OKAUCHI TETSUO

IPC: A01N43/40 ,  A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

Abstract: An insecticidal composition containing a guanidine derivative of the formula: wherein R is an optionally substituted homocyclic or heterocyclic group, n is 0 or 1, R is a hydrogen atom or an optionally substituted hydrocarbon group, R is a primary, secondary or tertiary amino group, X is an electron attractive group such as nitro or trifluoroacetyl group, provided that when n is 0, R is an optionally substituted heterocyclic group or a salt thereof.

公开(公告)号：DE68929307D1

公开(公告)日：2001-07-26

申请号：DE68929307

申请日：1989-12-27

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： UNEME HIDEKE ,  IWANAGA KOICHI ,  HIGUCHI NORIKO ,  MINAMIDA ISAO ,  OKAUCHI TETSUO

IPC: A01N43/40 ,  A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

Abstract: An insecticidal composition containing a guanidine derivative of the formula: wherein R is an optionally substituted homocyclic or heterocyclic group, n is 0 or 1, R is a hydrogen atom or an optionally substituted hydrocarbon group, R is a primary, secondary or tertiary amino group, X is an electron attractive group such as nitro or trifluoroacetyl group, provided that when n is 0, R is an optionally substituted heterocyclic group or a salt thereof.

公开(公告)号：CA1340991C

公开(公告)日：2000-05-16

申请号：CA573430

申请日：1988-07-29

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： IWANAGA KOICHI ,  MINAMIDA ISAO ,  OKAUCHI TETSUO

IPC: C07D213/61 ,  A01N33/18 ,  A01N35/08 ,  A01N43/40 ,  A01N43/42 ,  A01N43/60 ,  A01N43/78 ,  A01N47/24 ,  A01N55/00 ,  C07C211/22 ,  C07C211/29 ,  C07C229/34 ,  C07C243/10 ,  C07C311/50 ,  C07D20060101 ,  C07D213/24 ,  C07D213/38 ,  C07D213/40 ,  C07D213/42 ,  C07D213/64 ,  C07D213/70 ,  C07D213/74 ,  C07D213/77 ,  C07D215/12 ,  C07D215/38 ,  C07D239/26 ,  C07D241/12 ,  C07D277/20 ,  C07D277/22 ,  C07D277/28 ,  C07D277/32 ,  C07D277/38 ,  C07D277/42 ,  C07D295/13 ,  C07D295/30 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07F7/08 ,  C07D213/60 ,  C07D241/14

Abstract: .alpha.-Unsaturated amines of the formula: (see formula I) wherein X1 and X2 are such that one is an electron-attracting group with the other being a hydrogen atom or an electron-attracting group; R1 is a group attached through a nitrogen atom; R2 is a hydrogen atom or a group attached through a carbon, nitrogen or oxygen atom; n is an integer equal to 0, 1 or 2; A is a heterocyclic group or a cyclic hydrocarbon group, and salts thereof and their agrochemical use as insecticidal and/or miticidal agents are described.

公开(公告)号：CA1340990C

公开(公告)日：2000-05-09

申请号：CA616738

申请日：1988-07-29

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： IWANAGA KOICHI ,  OKAUCHI TETSUO ,  MINAMIDA ISAO

IPC: C07D213/61 ,  A01N33/18 ,  A01N35/08 ,  A01N43/40 ,  A01N43/42 ,  A01N43/60 ,  A01N43/78 ,  A01N47/24 ,  A01N55/00 ,  C07C211/22 ,  C07C211/29 ,  C07C229/34 ,  C07C243/10 ,  C07C311/50 ,  C07D20060101 ,  C07D213/24 ,  C07D213/38 ,  C07D213/40 ,  C07D213/42 ,  C07D213/64 ,  C07D213/70 ,  C07D213/74 ,  C07D213/77 ,  C07D215/12 ,  C07D215/38 ,  C07D239/26 ,  C07D241/12 ,  C07D277/20 ,  C07D277/22 ,  C07D277/28 ,  C07D277/32 ,  C07D277/38 ,  C07D277/42 ,  C07D295/13 ,  C07D295/30 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07F7/08 ,  C07D413/06

Abstract: Disclosed are compounds of the formula: (see formula I) (wherein: A' is pyridyl, pyrazinyl or thiazolyl, each of which may optionally be substituted with halogen, C1-4alkyl, halo-C1-4alkyl, C1-4alkoxy, halo-C1-4alkoxy, C1-4alkylthio or halo-C1-4alkylthio; n is 0, 1 or 2; and R2 is hydrogen, C1-2alkoxy, di-C1-2alkylamino, C1-4alkyl, halo-C1-4alkyl, C1-2acyl, 2,2-dimethoxyethyl or 2-methoxyethyl). The compounds of the formula ¢III'! are useful for producing .alpha.-unsaturated amines of the formula: (see formula II) (wherein X1 and X2 are such that one is an electron-attracting group with the other being a hydrogen atom or an electron-attracting group R1 is a group attached through a nitrogen atom; R2 is a hydrogen atom or a group attached through a carbon, nitrogen or oxygen atom; n is an integer equal to 0, 1 or 2; A is a heterocyclic group or a cyclic hydrocarbon group) and salts thereof which are useful in the agrochemical field as insecticidal and/or miticidal agents.

公开(公告)号：DE3856183T2

公开(公告)日：1998-11-05

申请号：DE3856183

申请日：1988-07-28

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： MINAMIDA ISAO ,  IWANAGA KOICHI ,  OKAUCHI TETSUO

IPC: C07D213/61 ,  A01N33/18 ,  A01N35/08 ,  A01N43/40 ,  A01N43/42 ,  A01N43/60 ,  A01N43/78 ,  A01N47/24 ,  A01N55/00 ,  C07C211/22 ,  C07C211/29 ,  C07C229/34 ,  C07C243/10 ,  C07C311/50 ,  C07D20060101 ,  C07D213/24 ,  C07D213/38 ,  C07D213/40 ,  C07D213/42 ,  C07D213/64 ,  C07D213/70 ,  C07D213/74 ,  C07D213/77 ,  C07D215/12 ,  C07D215/38 ,  C07D239/26 ,  C07D241/12 ,  C07D277/20 ,  C07D277/22 ,  C07D277/28 ,  C07D277/32 ,  C07D277/38 ,  C07D277/42 ,  C07D295/13 ,  C07D295/30 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07F7/08 ,  C07D405/12

Abstract: α-Unsaturated amines of the formula:wherein X¹ and X² are such that one is an electron-attracting group with the other being a hydrogen atom or an electron-attracting group; R¹ is a group attached through a nitrogen atom; R² is a hydrogen atom or a group attached through a carbon, nitrogen or oxygen atom; n is an integer equal to 0, 1 or 2; A is a heterocyclic group or a cyclic hydrocarbon group, and salts thereof and their agrochemical use as insecticidal and/or miticidal agents are described.

公开(公告)号：DE3856183D1

公开(公告)日：1998-06-18

申请号：DE3856183

申请日：1988-07-28

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： MINAMIDA ISAO ,  IWANAGA KOICHI ,  OKAUCHI TETSUO

IPC: C07D213/61 ,  A01N33/18 ,  A01N35/08 ,  A01N43/40 ,  A01N43/42 ,  A01N43/60 ,  A01N43/78 ,  A01N47/24 ,  A01N55/00 ,  C07C211/22 ,  C07C211/29 ,  C07C229/34 ,  C07C243/10 ,  C07C311/50 ,  C07D20060101 ,  C07D213/24 ,  C07D213/38 ,  C07D213/40 ,  C07D213/42 ,  C07D213/64 ,  C07D213/70 ,  C07D213/74 ,  C07D213/77 ,  C07D215/12 ,  C07D215/38 ,  C07D239/26 ,  C07D241/12 ,  C07D277/20 ,  C07D277/22 ,  C07D277/28 ,  C07D277/32 ,  C07D277/38 ,  C07D277/42 ,  C07D295/13 ,  C07D295/30 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07F7/08 ,  C07D405/12

Abstract: α-Unsaturated amines of the formula:wherein X¹ and X² are such that one is an electron-attracting group with the other being a hydrogen atom or an electron-attracting group; R¹ is a group attached through a nitrogen atom; R² is a hydrogen atom or a group attached through a carbon, nitrogen or oxygen atom; n is an integer equal to 0, 1 or 2; A is a heterocyclic group or a cyclic hydrocarbon group, and salts thereof and their agrochemical use as insecticidal and/or miticidal agents are described.

公开(公告)号：DE69126350D1

公开(公告)日：1997-07-10

申请号：DE69126350

申请日：1991-03-14

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： UNEME HIDEKI ,  HIGUCHI NORIKO ,  MINAMIDA ISAO

IPC: A01N47/46 ,  A01N51/00 ,  C07D277/20 ,  C07D277/32

Abstract: Novel processes for preparing 2-chlorothiazoles, useful as an intermediate for insecticides, from allyl isothiocyanate derivatives having the formula [ II ]: wherein X represents a leaving group, are simple and convenient reaction procedures under mild conditions without need of a large excess of a chlorinating agent. Further, processes for preparing 5-(aminomethyl)-2-chlorothiazole or salts thereof from the compound [ II ] achieve higher yields by simple, convenient and inexpensive procedures.

公开(公告)号：DK0446913T3

公开(公告)日：1997-07-07

申请号：DK91103927

申请日：1991-03-14

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： MINAMIDA ISAO ,  UNEME HIDEKI ,  HIGUCHI NORIKO

IPC: A01N47/46 ,  A01N51/00 ,  C07D277/20 ,  C07D277/32

Abstract: Novel processes for preparing 2-chlorothiazoles, useful as an intermediate for insecticides, from allyl isothiocyanate derivatives having the formula [ II ]: wherein X represents a leaving group, are simple and convenient reaction procedures under mild conditions without need of a large excess of a chlorinating agent. Further, processes for preparing 5-(aminomethyl)-2-chlorothiazole or salts thereof from the compound [ II ] achieve higher yields by simple, convenient and inexpensive procedures.

公开(公告)号：AT154016T

公开(公告)日：1997-06-15

申请号：AT91103927

申请日：1991-03-14

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD

Inventor： UNEME HIDEKI ,  HIGUCHI NORIKO ,  MINAMIDA ISAO

IPC: A01N47/46 ,  A01N51/00 ,  C07D277/20 ,  C07D277/32

Abstract: Novel processes for preparing 2-chlorothiazoles, useful as an intermediate for insecticides, from allyl isothiocyanate derivatives having the formula [ II ]: wherein X represents a leaving group, are simple and convenient reaction procedures under mild conditions without need of a large excess of a chlorinating agent. Further, processes for preparing 5-(aminomethyl)-2-chlorothiazole or salts thereof from the compound [ II ] achieve higher yields by simple, convenient and inexpensive procedures.