公开(公告)号：US20100289174A1

公开(公告)日：2010-11-18

申请号：US12808095

申请日：2008-12-12

Applicant: Kotaro Kimishima ,  Sadakatsu Suzuki

Inventor： Kotaro Kimishima ,  Sadakatsu Suzuki

IPC: B29C47/08 ,  C08J3/00

CPC classification number: C08J9/28 ,  B01D67/0016 ,  B01D67/0095 ,  B01D2323/08 ,  C08J11/02 ,  C08J2201/03 ,  C08J2201/0543 ,  C08J2201/0546 ,  H01M2/145 ,  H01M2/1653 ,  H01M10/052 ,  H01M10/0565

Abstract: The invention relates to a method for removing a process solvent (P-sol) from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with chlorinated hydrocarbon (CHC) and hydrofluoroether (HFE) in a first stage; contacting the extrudate from the first stage with HFE in a second stage; combining the first and second waste streams and then separating the P-sol from the combined streams to make an HFE-CHC stream; cooling the HFE-CHC stream to make an HFE-rich phase and a CHC-rich phase; and conducting the CHC-rich phase and/or the HFE-rich phase to step (A).

Abstract translation: 本发明涉及一种从聚合物挤出物中除去工艺溶剂（P-sol）的方法，特别是与微孔膜的制造方法有关。 该方法包括在第一阶段使挤出物与氯化烃（CHC）和氢氟醚（HFE）接触; 在第二阶段将来自第一阶段的挤出物与HFE接触; 组合第一和第二废物流，然后将P-sol与合并的流分离以制备HFE-CHC流; 冷却HFE-CHC流以形成富含HFE的相和富CHC相; 并且将富CHCl相和/或富HFE相进行到步骤（A）。

公开(公告)号：US20080261011A1

公开(公告)日：2008-10-23

申请号：US11855723

申请日：2007-09-14

Applicant: Paul L. Benenati ,  James L. Boyer ,  Charles R. Coleman ,  Luciano M. Parrinello ,  Narayan K. Raman

Inventor： Paul L. Benenati ,  James L. Boyer ,  Charles R. Coleman ,  Luciano M. Parrinello ,  Narayan K. Raman

IPC: C08J9/00 ,  B32B27/32

CPC classification number: C08J9/28 ,  C06B23/008 ,  C08J5/18 ,  C08J2201/03 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/02 ,  C08J2323/06

Abstract: Provided is a microporous material, e.g., a microporous sheet material, having a matrix of polyolefin, finely-divided, substantially water insoluble particulate filler, a network of interconnecting pores communicating throughout the microporous material, and at least one retrospectively identifiable taggant material embedded within the matrix, wherein the polyolefin is present in the microporous material in an amount of 20 to 60 weight percent, based on the weight of the microporous material. The taggant material provides a marker, signature or code that is capable of retrospective identification by machine, instrument or by the naked eye. Articles including the microporous material and processes for preparing the microporous material also are provided.

Abstract translation: 提供了一种微孔材料，例如微孔片材，其具有聚烯烃基质，细分的，基本上不溶于水的颗粒填料，连通整个微孔材料的互连孔网络，以及至少一个可回收识别的标记物材料 基质，其中基于微孔材料的重量，聚烯烃以20至60重量％的量存在于微孔材料中。 标签材料提供能够通过机器，仪器或肉眼追溯鉴定的标记，签名或代码。 还提供了包括微孔材料的制品和用于制备微孔材料的方法。

公开(公告)号：US20080260793A1

公开(公告)日：2008-10-23

申请号：US12134941

申请日：2008-06-06

Applicant: Kjell Nilsson

Inventor： Kjell Nilsson

IPC: A61K9/00 ,  A61K47/42 ,  A61K9/14 ,  A61P17/00 ,  A61K35/00

CPC classification number: C08J9/30 ,  A61L27/222 ,  A61L27/24 ,  A61L27/56 ,  A61L27/60 ,  C08J9/28 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2389/00

Abstract: The present invention relates to a porous gelatin material in the form of spherical particles with a continuous pore structure and cast, three-dimensional, porous gelatin structures. The invention also comprises methods for preparation of the porous gelatin materials and structures. The method for preparing the porous gelatin material in the form of spheres with a continuous pore structure comprises the steps of preparing a homogenous water-based gelatin solution, adding an emulsifier with an HLB value >9, adding a first composition comprising an organic solvent and an emulsifier with an HLB value >9, adding a second composition comprising an organic solvent and an emulsifier with an HLB value

Abstract translation: 本发明涉及具有连续孔结构的球形颗粒形式的多孔明胶材料和铸造的三维多孔明胶结构。 本发明还包括制备多孔明胶材料和结构的方法。 制备具有连续孔结构的球形多孔明胶材料的方法包括以下步骤：制备均匀的水基明胶溶液，加入HLB值> 9的乳化剂，加入包含有机溶剂的第一组合物和 HLB值> 9的乳化剂，加入包含HLB值<8的有机溶剂和乳化剂的第二组合物，并使明胶材料固化。 还包括根据本发明的材料的用途。

公开(公告)号：US20080161442A1

公开(公告)日：2008-07-03

申请号：US11883503

申请日：2006-02-02

Applicant: Kimio Nakayama ,  Tatsuya Shoji ,  Yukihiko Asano ,  Shigeru Yao

Inventor： Kimio Nakayama ,  Tatsuya Shoji ,  Yukihiko Asano ,  Shigeru Yao

IPC: C08G69/00

CPC classification number: C08J9/28 ,  C08J3/14 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2377/00 ,  C08J2377/02

Abstract: Porous spherical particles of polyamide 11 or polyamide 12 can be produced by an industrially advantageous process which comprises the steps of mixing a polyamide solution of polyamide 11 or polyamide 12 dissolved in a phenol compound and a low molecular weight aliphatic alcohol which is a poor solvent for the polyamides but is well compatible with the phenol compound in the presence of a high molecular weight alkylene glycol to prepare a mixture solution having an initial viscosity of 10 mPa·s or more, and allowing the mixture solution to stand, to precipitate polyamide particles.

Abstract translation: 聚酰胺11或聚酰胺12的多孔球形颗粒可以通过工业上有利的方法制备，其包括将溶解在酚化合物中的聚酰胺11或聚酰胺12的聚酰胺溶液与作为不良溶剂的低分子量脂肪醇混合的步骤 聚酰胺，但是在高分子量亚烷基二醇的存在下与酚化合物良好相容，以制备初始粘度为10mPa.s或更高的混合溶液，并使混合溶液静置以沉淀聚酰胺颗粒。

公开(公告)号：US20070144972A1

公开(公告)日：2007-06-28

申请号：US11419461

申请日：2006-05-19

Applicant: Gunther Bonn ,  Said Lubban ,  Lukas Trojer

Inventor： Gunther Bonn ,  Said Lubban ,  Lukas Trojer

IPC: B01D15/08

CPC classification number: C08J9/28 ,  B01D15/325 ,  B01J20/261 ,  B01J20/264 ,  B01J20/285 ,  B01J20/3064 ,  B01J2220/82 ,  C08F212/08 ,  C08F212/12 ,  C08F212/34 ,  C08J9/142 ,  C08J9/149 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2325/06 ,  C08J2325/16 ,  C08F212/36

Abstract: Monolithic organic copolymer prepared by copolymerisation of an alkylstyrene and a divinylbenzene or a derivative thereof in the presence of a porogen, wherein said porogen comprises decanol and at least one of the group consisting of tetrahydrofuran and toluene.

Abstract translation: 通过烷基苯乙烯和二乙烯基苯或其衍生物在造孔剂存在下共聚制备的单片有机共聚物，其中所述致孔剂包括癸醇和由四氢呋喃和甲苯组成的组中的至少一种。

公开(公告)号：US06177181B1

公开(公告)日：2001-01-23

申请号：US09117275

申请日：1998-07-23

Applicant: Toyozo Hamada ,  Shuji Nakatsuka ,  Kiyoharu Mizumoto

Inventor： Toyozo Hamada ,  Shuji Nakatsuka ,  Kiyoharu Mizumoto

IPC: B32B326

CPC classification number: B32B27/06 ,  B01D67/0011 ,  B01D69/02 ,  B01D69/12 ,  B01D2323/30 ,  B01D2325/04 ,  B32B3/266 ,  B32B5/18 ,  B32B23/20 ,  B32B27/286 ,  B32B27/30 ,  B32B27/302 ,  B32B27/36 ,  B32B2367/00 ,  B41M5/506 ,  B41M5/5254 ,  C08J9/28 ,  C08J2201/0502 ,  C08J2201/054 ,  C08J2201/0543 ,  C08J2201/0546 ,  Y10T428/249953 ,  Y10T428/31634 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31982 ,  Y10T428/31996

Abstract: Porous membranes having a micro phase separation structure and showing a light transmittance at the wavelength of 400 nm of not less than 30% are obtained by the dry phase conversion method comprising drying a coating layer of a dope containing a polymer, a good solvent for the polymer and a poor solvent for the polymer which solvent has a higher boiling point than the good solvent. The polymer includes cellulose derivatives, vinyl-series polymers such as acrylonitrile-series polymers and (meth)acrylic acid ester-series polymers, polysulfone-series polymers, and the like. The porous polymer membranes have a porosity of 10 to 60%, a mean pore size of about 0.002 to 0.35 &mgr;m and a maximum pore size of not greater than 0.4 &mgr;m. These porous membranes shows not only excellent transparency but also high productivity.

Abstract translation: 具有微相分离结构并且在400nm波长下显示光透射率不小于30％的多孔膜通过干相转化方法获得，该方法包括干燥含有聚合物的涂料的涂层，用于 聚合物和溶剂的不良溶剂，该溶剂的沸点高于良溶剂。 聚合物包括纤维素衍生物，乙烯基系聚合物如丙烯腈系聚合物和（甲基）丙烯酸酯系聚合物，聚砜系聚合物等。 多孔聚合物膜具有10至60％的孔隙率，约0.002至0.35μm的平均孔径和不大于0.4μm的最大孔径。 这些多孔膜不仅具有优异的透明性，而且显示出高生产率。

公开(公告)号：US6063484A

公开(公告)日：2000-05-16

申请号：US996681

申请日：1997-12-23

Applicant: Bert J. Exsted ,  Steven L. Kangas

Inventor： Bert J. Exsted ,  Steven L. Kangas

IPC: B01D15/08 ,  B01D67/00 ,  B01D71/44 ,  B01D71/78 ,  C08J9/00 ,  C08J9/28 ,  B32B3/10

CPC classification number: C08J9/28 ,  B01D67/0027 ,  B01D67/003 ,  B01D71/44 ,  B01D71/78 ,  B01D2323/08 ,  B01D2323/24 ,  B01D71/26 ,  B01D71/62 ,  C08J2201/0543 ,  C08J2201/0546 ,  Y10T428/249978 ,  Y10T428/249979

Abstract: The present invention provides a microporous material or a membrane in which the membrane includes an azlactone moiety which is blended with or grafted to a thermoplastic polymer to provide a porous material having an internal structure characterized by a multiplicity of spaced, randomly disposed, non-uniform shaped, equiaxed particles of the polyazlactone polymer/thermoplastic polymer blends or the azlactone-graft copolymer. Each of the adjacent particles throughout the material are separated from one another to provide said material with a network of interconnected micropores and each of the particles are connected to each other by a plurality of fibrils. In addition to unmodified azlactone membranes, membranes which have been modified by subsequent reaction of the azlactone moiety with a suitable nucleophile are also included within the scope of the present invention. Preferred nucleophiles capable of reacting with an azlactone membrane of this invention include biologically significant nucleophiles such as amines, thiols and alcohols as well as amino acids, nucleic acids and proteins.

Abstract translation: 本发明提供了一种微孔材料或膜，其中膜包括偕根酮部分，其与热塑性聚合物共混或接枝到热塑性聚合物上，以提供具有内部结构的多孔材料，其特征在于多个间隔开的，随机排列的，不均匀的 聚硅烷内酯聚合物/热塑性聚合物共混物或吖内酯接枝共聚物的等轴晶粒。 整个材料中的每个相邻颗粒彼此分离，以使所述材料具有互连微孔的网络，并且每个颗粒通过多个原纤维彼此连接。 除了未改性的吖内酯膜之外，已经通过吖内酯部分与合适的亲核试剂的后续反应进行了修饰的膜也包括在本发明的范围内。 能够与本发明的吖内酯膜反应的优选的亲核试剂包括生物显着的亲核试剂例如胺，硫醇和醇以及氨基酸，核酸和蛋白质。

公开(公告)号：US5322935A

公开(公告)日：1994-06-21

申请号：US103508

申请日：1993-08-06

Applicant: Tammy Smith

Inventor： Tammy Smith

IPC: C08B37/08 ,  C08J9/28 ,  C12N11/10

CPC classification number: C08J9/28 ,  C08B37/003 ,  C12N11/10 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2305/08

Abstract: This invention relates to highly porous, crosslinked bodies derived from nitrogen-containing polymers, and a process of producing the porous bodies which comprises dissolving a nitrogen-containing polymer to form a gel, ionically crosslinking the gel, and covalently further crosslinking the ionically crosslinked gel body.

公开(公告)号：US4744906A

公开(公告)日：1988-05-17

申请号：US785324

申请日：1985-10-04

Applicant: Klaus Gerlach ,  Erich Kessler

Inventor： Klaus Gerlach ,  Erich Kessler

IPC: B01D67/00 ,  B01D69/02 ,  B01D69/08 ,  B29C67/20 ,  C08J9/28 ,  D01D5/24 ,  D01D5/247 ,  B01D13/00

CPC classification number: B01D71/26 ,  B01D67/003 ,  B01D69/02 ,  B01D69/08 ,  B01D69/087 ,  B29C67/205 ,  C08J9/28 ,  D01D5/24 ,  D01D5/247 ,  C08J2201/0543 ,  C08J2201/0546

Abstract: The invention concerns porous fibers and membranes, methods for their preparation and for their use. The fibers are characterized by a smooth porous surface and an apparent density of between about 10 to 90% of the true density of the polymeric starting material employed. The process involves the formation of a homogeneous mixture of at least two components, one of which is a meltable polymer and another liquid inert with respect to the polymer. The mixture formed must be of a binary type, in which there is a temperature range of complete miscibility and a range in which there is a miscibility gap. The mixture is extruded at a temperature above the separation temperature into a bath containing at least some of the inert liquid which is at a temperature below the separation temperature. Upon introduction of the mixture into the bath, the fiber structure of the product is fixed.

Abstract translation: 本发明涉及多孔纤维和膜，其制备方法和用途。 纤维的特征在于光滑的多孔表面和表观密度为所用聚合物原料的真实密度的约10至90％。 该方法包括形成至少两种组分的均匀混合物，其中一种是可熔融聚合物，另一种是相对于聚合物惰性的液体。 形成的混合物必须是二元型，其中存在完全混溶性的温度范围和存在混合间隙的范围。 将混合物在高于分离温度的温度下挤出至含有至少一些惰性液体的浴中，该惰性液体的温度低于分离温度。 当将混合物引入浴中时，产品的纤维结构是固定的。

公开(公告)号：US4734196A

公开(公告)日：1988-03-29

申请号：US832916

申请日：1986-02-24

Applicant: Koichi Kono ,  Shoichi Mori ,  Kenji Miyasaka ,  Jyoichi Tabuchi

Inventor： Koichi Kono ,  Shoichi Mori ,  Kenji Miyasaka ,  Jyoichi Tabuchi

IPC: B01D67/00 ,  B01D71/26 ,  C08J5/18 ,  C08J9/28 ,  B29C43/00 ,  B29C55/12

CPC classification number: C08J9/28 ,  B01D67/0009 ,  B01D71/26 ,  C08J5/18 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/34 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/02

Abstract: A micro-porous membrane of ultra-high-molecular-weight alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, the micro-porous membrane having through holes 0.01 to 1 micrometer in average pore size, with a void ratio from 30 to 90% and being oriented such that the linear draw ratio in one axis is greater than two and the areal draw ratio is greater than ten. The micro-porous membrane is obtained by forming a gel-like object from a solution of an alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, removing at least 10 wt % of the solvent contained in the gel-like object so that the gel-like object contains 10 to 90 wt % of alpa-olefin polymer, orientating the gel-like object at a temperature lower than that which is 10.degree. C. above the melting point of the alpa-olefin polymer, and removing the residual solvent from the orientated product. A film is produced from the orientated product by pressing the orientated product at a temperature lower than that of the melting point of the alpha-olefin polymer.

Abstract translation: 超高分子量α-烯烃聚合物的微孔膜的重均分子量大于5×10 5，微孔膜具有平均孔径为0.01-1微米的通孔，孔隙率为 30〜90％，一方向的线性拉伸比大于2，面积比大于10。 微孔膜通过从重均分子量大于5×10 5的α-烯烃聚合物的溶液中形成凝胶状物质，除去至少10重量％的凝胶状物质中所含的溶剂 使得凝胶状物体含有10〜90重量％的α-烯烃聚合物，使凝胶状物质的温度低于高于α-烯烃聚合物的熔点10℃的温度，除去 来自定向产物的残留溶剂。 通过在比α-烯烃聚合物的熔点低的温度下压制定向产物，从定向产物制备膜。