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    Carbamate-functional resins and their use in high solids coating compositions
    91.
    发明申请
    Carbamate-functional resins and their use in high solids coating compositions 有权
    氨基甲酸酯官能树脂及其在高固含量涂料组合物中的应用

    公开(公告)号：US20020119320A1

    公开(公告)日：2002-08-29

    申请号：US09793289

    申请日：2001-02-26

    Inventor： Swaminathan Ramesh ,  Marvin L. Green ,  Donald H. Campbell ,  Walter H. Ohrbom

    IPC: B32B027/00

    CPC classification number: C09D201/025 ,  C09D201/005 ,  Y10T428/31511 ,  Y10T428/31551

    Abstract: The present invention provides a coating composition containing 1) a carbamate-functional resin having in its structure a hyperbranched or star polyol core, a first chain extension based on a polycarboxylic acid or anhydride, a second chain extension based on an epoxy containing compound, and having carbamate functional groups on the core, the second chain extension, or both; and 2) a second resin containing functional groups reactive with the carbamate groups on the carbamate-functional resin. In one embodiment, the coating compositions are used as a clearcoat to be applied over a basecoat to form a composite coating. The compositions exhibit a combination of desirable properties, such as scratch and mar resistance, resistance to environmental etch, good intercoat adhesion, and high solids.

    Abstract translation: 本发明提供了一种涂料组合物，其含有1）氨基甲酸酯官能树脂，其结构为超支化或星形多元醇芯，基于多元羧酸或酸酐的第一链延伸，基于含环氧化合物的第二链延伸，以及 在芯上具有氨基甲酸酯官能团，第二链延伸部分或两者; 和2）含有与氨基甲酸酯官能树脂上的氨基甲酸酯基反应的官能团的第二树脂。 在一个实施方案中，涂料组合物用作透明涂层以涂布在底涂层上以形成复合涂层。 组合物显示出所需性能的组合，例如耐刮擦和耐擦伤性，耐环境腐蚀性，良好的涂层间粘合性和高固含量。

    Use of hyperbranched polymers and dendrimers comprising a particular group as film-forming agent, film-forming compositions comprising same and use particularly in cosmetics and pharmaceutics
    92.
    发明授权
    Use of hyperbranched polymers and dendrimers comprising a particular group as film-forming agent, film-forming compositions comprising same and use particularly in cosmetics and pharmaceutics 失效
    使用包含特定基团的超支化聚合物和树枝状大分子作为成膜剂，包含其的成膜组合物，特别用于化妆品和药物

    公开(公告)号：US06432423B1

    公开(公告)日：2002-08-13

    申请号：US09581752

    申请日：2000-06-23

    Applicant: Jean Maignan ,  Sylvie Genard

    Inventor： Jean Maignan ,  Sylvie Genard

    IPC: A61K600

    CPC classification number: A61K8/84 ,  A61K9/0014 ,  A61K9/7007 ,  A61Q19/00 ,  C08G73/00 ,  C08G73/0253 ,  C08G83/002 ,  C08G83/005 ,  C09D201/005 ,  Y10S424/16

    Abstract: The invention concerns the use of hyperbranched polymers and dendrimers, comprising at least one group of formula (I) in which: Y represents the oxygen atom or a NH group: and A represents a C1-C12 alkane di-yl group, linear, branched or cyclic, saturated or unsaturated; said group being optionally interrupted by one or several heteroatoms and/or substituted by a function selected among: amino (—NH2): acylamino (—NH—CO—R) in which R represents a C1-C10 alkyl group, linear, branched or cyclic, saturated or unsaturated; carboxylic acid (—COOH), ester (—COOR) in which R represents a C1-C10 alkyl group, linear, branched or cyclic, saturated or unsaturated, as film-forming agent. The invention also concerns a film-forming composition comprising said compound and its use particularly in cosmetics or pharmaceutics.

    Abstract translation: 本发明涉及使用超支化聚合物和树枝状大分子，其包含至少一个式（I）的基团，其中：Y表示氧原子或NH基团：A表示C1-C12烷烃二基，直链，支链 或环状，饱和或不饱和的; 所述基团任选地被一个或多个杂原子中断和/或被选自以下的官能团取代：氨基（-NH 2）：酰基氨基（-NH-CO-R），其中R代表C1-C10烷基，直链，支链或 环状，饱和或不饱和的; 羧酸（-COOH），酯（-COOR），其中R表示直链，支链或环状，饱和或不饱和的作为成膜剂的C 1 -C 10烷基。 本发明还涉及包含所述化合物的成膜组合物及其在化妆品或药物中的用途。

    Hyperbranched polyol macromolecule, method of making same, and coating composition including same
    93.
    发明申请
    Hyperbranched polyol macromolecule, method of making same, and coating composition including same 失效
    超支化多元醇大分子，其制造方法以及包含其的涂料组合物

    公开(公告)号：US20020082359A1

    公开(公告)日：2002-06-27

    申请号：US10040819

    申请日：2002-01-07

    Inventor： Swaminathan Ramesh

    IPC: C08F020/00

    CPC classification number: C08G83/005 ,  C08G63/123 ,  C08G63/60 ,  C08G63/91 ,  C09D167/00 ,  C09D201/005 ,  Y10S977/754 ,  C08L2666/36 ,  C08L61/04

    Abstract: A hyperbranched polyester polyol macromolecule, having a plurality of both embedded and exterior hydroxyl groups thereon, may be synthesized in a polymerization reaction having several steps. The hyperbranched polyol includes a central nucleus, a first chain extension, an intermediate substituent and a second chain extension. The central nucleus is a hydrocarbon structure with a plurality of oxygen atoms. The first chain extender is attached to the central nucleus and includes a carboxylic ester group and a plurality of hydroxyl groups. The intermediate substituent is attached to the first chain extender, and is a polyfunctional carboxylic acid or anhydride thereof. The preferred intermediate substituent is a cyclic compound. The second chain extension is attached to the intermediate substituent. The preferred second chain extension includes a glycidyl ester or epoxy. Methods of making a hyperbranched polyester polyol are also disclosed. Coating compositions in which the hyperbranched polyol is reacted with an aminoplast or with an isocyanate are also encompassed by the invention.

    Abstract translation: 可以在具有几个步骤的聚合反应中合成具有多个其上的多个嵌入和外部羟基的超支化聚酯多元醇高分子。 超支化多元醇包括中心核，第一链延伸，中间取代基和第二链延伸。 中心核是具有多个氧原子的烃结构。 第一扩链剂连接到中心核并包含羧酸酯基和多个羟基。 中间取代基连接到第一扩链剂上，并且是多官能羧酸或其酸酐。 优选的中间体取代基是环状化合物。 第二链延伸连接到中间取代基。 优选的第二链延伸包括缩水甘油酯或环氧基。 还公开了制备超支化聚酯多元醇的方法。 超支化多元醇与氨基塑料或与异氰酸酯反应的涂料组合物也包括在本发明中。

    Reactive hyperbranched polymers for powder coatings
    94.
    发明授权
    Reactive hyperbranched polymers for powder coatings 失效
    用于粉末涂料的反应性超支化聚合物

    公开(公告)号：US6114489A

    公开(公告)日：2000-09-05

    申请号：US826192

    申请日：1997-03-27

    Applicant: Richard Vicari ,  Olan Stanley Fruchey ,  Kathleen Nelson Juneau ,  Shelby Freland Thames ,  James Wayne Rawlins

    Inventor： Richard Vicari ,  Olan Stanley Fruchey ,  Kathleen Nelson Juneau ,  Shelby Freland Thames ,  James Wayne Rawlins

    IPC: C08G18/42 ,  C08G18/80 ,  C09D5/03 ,  C09D167/00 ,  C09D201/00

    CPC classification number: C09D201/005 ,  C08G18/4202 ,  C08G18/4283 ,  C08G18/8074 ,  C09D167/00 ,  C09D5/037 ,  C08G2150/20

    Abstract: Novel powder coating compositions containing reactive hyperbranched polymers are disclosed and claimed. Preferred embodiments include powder coating compositions formed from hyperbranched polyesters having terminal hydroxy, carboxy, epoxy, and isocyanate groups. Preferred hyperbranched polyesters are formed from .alpha.,.alpha.-bis-(hydroxymethyl)-propionic acid, which act either as crosslinkers, adhesion promotors, or flow and leveling agents. A process for the synthesis of powder coating compositions is also disclosed which involves (a) self condensation of one or more of the multifunctional monomers to form the hyperbranched polymer, optionally, in the presence of suitable reactive end-capping moieties which are described herein; (b) melt blending of the hyperbranched polymer with suitable amounts of one or more of polyesters, epoxy resins, blocked urethane resins, or acrylic resins, a crosslinker, and one or more of suitable additional ingredients including degassers or flow and leveling agents, to form a flake; and (c) grinding and sieving of the flake to form the powder coating composition. These compositions exhibit improved flow and curing properties. These compositions can therefore be formed into thin films and can be cured at low temperatures to form smooth surfaces. Additionally, these films are hard and exhibit enhanced impact resistance properties than the conventional polyester resins. Thus, these powder coating compositions find utilities in automotive, packaging, and appliances.

    Abstract translation: 公开并要求保护含有反应性超支化聚合物的新型粉末涂料组合物。 优选的实施方案包括由具有末端羟基，羧基，环氧基和异氰酸酯基的超支化聚酯形成的粉末涂料组合物。 优选的超支化聚酯由α，α-双（羟甲基） - 丙酸形成，其作为交联剂，粘合促进剂或流动剂和流平剂。 还公开了合成粉末涂料组合物的方法，其涉及（a）一种或多种多官能单体的自缩合形成超支化聚合物，任选地，在本文所述的合适的反应性封端部分存在下; （b）将超支化聚合物与适量的一种或多种聚酯，环氧树脂，封闭的聚氨酯树脂或丙烯酸树脂，交联剂和一种或多种合适的额外成分（包括脱气剂或流动和流平剂）熔融共混至 形成片状 和（c）研磨和筛分薄片以形成粉末涂料组合物。 这些组合物表现出改善的流动性和固化性能。 因此，这些组合物可以形成为薄膜，并且可以在低温下固化以形成光滑的表面。 此外，这些膜比常规聚酯树脂硬，表现出更好的抗冲击性能。 因此，这些粉末涂料组合物可在汽车，包装和电器中找到效用。

    Dendritic polymer coatings
    96.
    发明授权
    Dendritic polymer coatings 失效
    树枝状聚合物涂层

    公开(公告)号：US5731095A

    公开(公告)日：1998-03-24

    申请号：US735883

    申请日：1996-10-23

    Applicant: Larry A. Milco ,  Donald A. Tomalia

    Inventor： Larry A. Milco ,  Donald A. Tomalia

    IPC: C08F2/16 ,  C08F8/30 ,  C08G83/00 ,  C09D201/00 ,  B32B27/06 ,  C08F2/32 ,  C08F20/00

    CPC classification number: C08G83/003 ,  C08F8/30 ,  C09D201/005 ,  Y10S977/754 ,  Y10T428/31794

    Abstract: A water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, and which is suitable for use in preparing protective coating compositions is disclosed. The water-soluble or water-dispersible fluorine-containing dendritic polymer surfactants are represented by the general formula: ##STR1## where D represents a dendritic polymer, R.sub.F represents a fluorocarbon containing moiety, A.sup.- represents an anionic containing moiety, C.sup.+ represents a cation, T represents a terminal group of the dendritic polymer which has not been functionalized with a fluorocarbon or anionic moiety, n and m are at least each at least one, and the sum of n+m+q is the total number of terminal groups on the dendritic polymer. Also disclosed is a coating composition capable of forming a highly crosslinked, non-stick, protective coating. The coating composition includes a water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, an oxazoline crosslinking agent, and a water-based solvent.

    Abstract translation: 公开了具有至少一个末端碳氟化合物部分和至少一个末端阴离子部分并且适合用于制备保护性涂料组合物的水溶性或水分散性含氟树枝状聚合物表面活性剂。 水溶性或水分散性的含氟树枝状高分子表面活性剂由以下通式表示：其中D表示树枝状聚合物，RF表示含氟碳的部分，A-表示含阴离子的部分，C +表示阳离子 ，T表示尚未用碳氟化合物或阴离子部分官能化的树枝状聚合物的末端基团，n和m至少分别为至少一个，n + m + q的总和为 树枝状聚合物。 还公开了能够形成高度交联，不粘的保护涂层的涂料组合物。 涂料组合物包括具有至少一个末端碳氟化合物部分和至少一个末端阴离子部分，恶唑啉交联剂和水基溶剂的水溶性或水分散性含氟树枝状聚合物表面活性剂。

    Dendrimeric toner particles for liquid electrophotography
    97.
    发明授权
    Dendrimeric toner particles for liquid electrophotography 失效
    用于液体电子照相术的树枝状三色调色剂颗粒

    公开(公告)号：US5558968A

    公开(公告)日：1996-09-24

    申请号：US378425

    申请日：1995-01-26

    Applicant: Dale D. Russell ,  James G. Bearss

    Inventor： Dale D. Russell ,  James G. Bearss

    IPC: C08G83/00 ,  C09B69/10 ,  C09D201/00 ,  G03G9/13 ,  G03G9/135 ,  G03G13/10 ,  G03G9/00

    CPC classification number: C08G83/003 ,  C09B68/22 ,  C09B68/44 ,  C09B69/10 ,  C09D201/005 ,  G03G13/10 ,  G03G9/133 ,  G03G9/135 ,  G03G9/1355

    Abstract: This invention comprises a single-component dendrimeric toner particle, and methods of making and using the toner particle in the liquid EP process. By using dendrimeric chemistry, a dendrimeric toner particle may be made that has controlled content, structure and size and that includes a colorant, a binder, and a charge director. The toner particles made this way will have high uniformity, so that toner dispersions containing them may be made to have good stability, print performance, and quality control. The colorant of choice for the toner particle is made the core of the dendrimer toner particle. Dendrons, which are made of generations of building or polymer units, branch out from the core and include a resin or other binder molecule, for binding the colorant to the paper in the EP process. One or more of the final polymer units, located at the terminus of the dendrons, comprise a coordinating or chelating agent for the toner charge director.

    Abstract translation: 本发明包括单组分树枝状大分子调色剂颗粒，以及在液体EP方法中制备和使用调色剂颗粒的方法。 通过使用树枝状大分子化学，可以制备具有受控含量，结构和尺寸并且包括着色剂，粘合剂和电荷导向剂的树枝状大分子调色剂颗粒。 以这种方式制造的调色剂颗粒将具有高均匀性，使得含有它们的调色剂分散体可以制成具有良好的稳定性，印刷性能和质量控制。 调色剂颗粒选择的着色剂是树枝状大分子调色剂颗粒的核心。 由建筑或聚合物单元的代代制造的树皮由树脂或其它粘合剂分子分散出来，用于在EP工艺中将着色剂粘合到纸上。 位于树突的末端的一个或多个最终聚合物单元包含用于调色剂电荷导向剂的配位剂或螯合剂。

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