Abstract:
Disclosed are a cladding tube for a nuclear fuel and a nuclear fuel element incorporating the cladding tube. The cladding tube consists of an inner zirconium liner layer and an outer zirconium alloy layer. The cladding tube has at least one of the following features: (I) the ratio a/b of the oxygen content a to iron content b in the zirconium liner layer is greater than 1.0, (II) the zirconium liner layer is made of a zirconium into the matrix of which impurities are dissolved, and (III) the second phase particles having microscopic sizes and dispersed in the inner surface of the zirconium liner layer and/or the outer surface of the zirconium alloy layer have been removed substantially. Owing to these features, undesirable stress corrosion cracking and local corrosion are remarkably suppressed in the cladding tube and the nuclear fuel element of the invention.
Abstract:
A process for forming a boron-containing coating on the internal surface of a zirconium or zirconium alloy hollow tube by heating the internal surface to a temperature of between 200.degree.-450.degree. C. and passing through the tube a mixture of a volatilized boron compound in helium or argon, such that the boron compound decomposes to form an integral boron containing coating on the internal surface.
Abstract:
It has been found that modifying standard Zircaloy alloy processing techniques by limiting the working and annealing temperatures utilized after conventional beta treatment results in Zircaloy alloy product having superior high temperature steam corrosion resistance.
Abstract:
There is provided a nuclear fuel element having a zirconium alloy cladding tube with improved corrosion resistance. The cladding tube comprises a metallurgical gradient across the width of the tube wall wherein the tube has a more corrosion-resistant metallurgical condition at the outer circumference and a less corrosion-resistant metallurgical condition at the inner circumference. The metallurgical gradient can be generated by heating an outer circumferential portion of the tube to the high alpha or mixed alpha plus beta range while maintaining the inner surface at a lower temperature, followed by cooling of the tube.
Abstract:
A method of surface-treating a reactor member for effectively removing a Cr-deficient layer and a work-hardened layer considered to be a cause of stress corrosion cracking (SCC) under low-stress conditions. The method of surface-treating a reactor member which is worked by bending (step 1) and then processed by a heat treatment (step 2), in which a work-hardened layer is formed by the bending, and in which a Cr-deficient layer is formed due to an oxide film attached by the heat treatment, uses at least one of: acid wash; grinding; electrolytic polishing; electro-discharge machining; surface cutting; surface deoxidation and softening; wet blasting; laser machining; or surface plating (step 3) to remove the work-hardened layer and the Cr-deficient layer from the reactor member or to prevent contact of the work-hardened layer and the Cr-deficient layer of the reactor member with a primary coolant.
Abstract:
A method of surface-treating a reactor member for effectively removing a Cr-deficient layer and a work-hardened layer considered to be a cause of stress corrosion cracking (SCC) under low-stress conditions. The method of surface-treating a reactor member which is worked by bending (step 1) and then processed by a heat treatment (step 2), in which a work-hardened layer is formed by the bending, and in which a Cr-deficient layer is formed due to an oxide film attached by the heat treatment, uses at least one of: acid wash; grinding; electrolytic polishing; electro-discharge machining; surface cutting; surface deoxidation and softening; wet blasting; laser machining; or surface plating (step 3) to remove the work-hardened layer and the Cr-deficient layer from the reactor member or to prevent contact of the work-hardened layer and the Cr-deficient layer of the reactor member with a primary coolant.
Abstract:
One object of the present invention is to provide a production method for a nuclear fuel assembly support grid that improves the corrosion resistance of welded parts without impairing the characteristics of the support grid so as to be able adequately withstand highly efficient operation. In order to achieve the object, the present invention provide a production method for a nuclear fuel assembly support grid comprising the steps of: assembling a plurality of straps in a grid form; welding intersections of each strap; and carrying out annealing thereafter to precipitate an intermetallic compound on the welded parts.