Abstract:
Polymeric compounds for lithographic printing plates, especially plates for use in printing utilizing UV curable inks, may include a structural unit (I) 1 wherein R1 represents an optionally-substituted cyclic or alkyl group, x represents 0 or 1 and A represents an optionally-substituted alkylene group. A range of compounds having different solubilities in selected solvents may be prepared by varying the identity or group R1. Such components may be prepared by reacting an amine of formula R1NH2 with the maleic anhydride derivative corresponding to moiety 1.
Abstract:
Radiation-sensitive element comprising a substrate and a radiation-sensitive coating comprising (a) at least one component selected from photoinitiators and sensitizer/coinitiator systems which absorbs radiation of a wavelength in the range of 250 to 1,200 nm; (b) at least one free-radical polymerizable oligomer A having an average molecular weight in the range of 3,500 to 9,000 determined by GPC, obtainable by reacting a triisocyanate with (i) at least one acrylic or methacrylic monomer with two free OH groups and at least one (meth)acrylic group and (ii) at least one compound comprising one OH group, at least one (meth)acrylic group and at least one poly(alkyleneoxide) chain in the molecule, wherein the (meth)acrylic monomer (i) is present in an amount of 2 to 20 mole-%, based on the total amount of (meth)acrylic compounds with OH functionality.
Abstract:
Radiation-sensitive element comprising (a) an optionally pretreated substrate and (b) a radiation-sensitive coating consisting of a composition comprising (i) one or more types of monomers and/or oligomers and/or polymers, each comprising at least one ethylenically unsaturated group accessible to a freeradical polymerization, (ii) at least one radiation-sensitive initiator or initiator system for free-radical polymerization absorbing radiation selected from the wavelength range of 300 to 1,200 nm; and (iii) at least one silsesquioxane comprising at least one substituent with at least one ethylenically unsaturated group each; applied onto the substrate.
Abstract:
Thermally imageable elements are described comprising on a substrate with hydrophilic surface (a) a first layer comprising a first polymer soluble or swellable in aqueous alkaline developer and insoluble in organic solvents with low polarity and (b) a second layer comprising a second polymer soluble or swellable in aqueous alkaline developer, wherein the first polymer is different from the second polymer and the second polymer comprises vinyl acetal repeating units and pendant acidic groups selected from COOH, -SO 3 H, -PO 3 H 2 , -PO 4 H 2 , aromatic OH and groups having acidic amide or imide groups.
Abstract:
Thermally imageable elements useful as lithographic printing plate precursors are disclosed. The elements may be either single layer or multilayer elements and comprise an alkali soluble co-polymer, or a mixture of alkali soluble co-polymers. The resulting printing plates have good resistance to pressroom chemicals.
Abstract:
A process for the post-treatment of an imaged lithographic printing plate comprises (a) Contacting a lithographic printing plate having image areas and non-image areas on a lithographic substrate with a solution comprising at least one phosphono-substituted siloxane of the following general formula (I) that is defined herein and (b) drying.
Abstract:
An imaging technique permits selective flattening of objects within page description files. The selective aspect of the flattening may pertain to the selection of particular objects to be flattened, selection of the degree of flattening to be applied to objects, or both. In some embodiments, selective flattening of objects in a page description file may be permitted based on an assessment of color correction efficacy. For example, the degree of flattening may be iteratively adjusted to achieve acceptable color correction results. Alternatively, a user may be notified in the event acceptable color correction results have not been achieved. A color error between bitmap files generated from a color corrected, unflattened page description file and from a color corrected, flattened page description file may be measured. When the measured error between the two bitmaps exceeds a predetermined value, an amount of file flattening may be adjusted to reduce the measured error.
Abstract:
A method for forming images useful as lithographic printing plate precursors is disclosed. An imageable element in which the imageable layer comprises an acid generator, a crosslinking agent, and a binder is imaged with ultraviolet radiation and developed with a solvent based developer. The acid generator is an iodonium, sulfonium, or diazonium salt in which the anion is an organic sulfate or thiosulfate anion. The binder comprises a copolymer that contains a reactive pendent group capable of undergoing acid crosslinking, in which the reactive pendent group is hydroxyl, carboxylic acid, sulfonamide, alkoxymethyl, or a mixture thereof. The method is especially suited for use with direct digital ultraviolet imaging devices. The resulting image is useful as a lithographic printing plate.
Abstract:
Radiation-sensitive element comprising (a) a substrate with at least one hydrophilic surface and (b) a radiation-sensitive coating on .at least one hydrophilic surface of the substrate, wherein the coating comprises: (i) at least one free-radical polymerizable monomer and/or oligomer and/or polymer with at least one ethylenically unsaturated group each, (ii) at least one absorber selected from photoinitiators and sensitizers, which is capable of absorbing radiation of a ,wavelength in the range of 250 to 1,200 nm and (iii) at least one stabilizer comprising in its molecule at least one group capable of inhibiting free-radical polymerization, and at least one other group capable of sorption at the hydrophilic surface of the substrate.
Abstract:
A media transfer sheet includes a light absorbing layer. The light absorbing layer is selected to absorb light at a wavelength that is close to light produced by a focusing light source. The light absorbing layer is placed in the media transfer sheet at a desired focus level for an imaging light source, within the media transfer sheet. The light absorbing layer does not allow any significant portion of the light from the focusing layer to pass therethrough, but does allow for reflectance of some portion of that light by the media transfer sheet. By limiting the level of reflection of focusing light, an improved reflected focusing light signal is produced that is more representative of the depth to be measured.