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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    102.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2545082A1

    公开(公告)日：2013-01-16

    申请号：EP11705595.4

    申请日：2011-03-01

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： BRITA, Diego ,  COLLINA, Gianni ,  EVANGELISTI, Daniele ,  GADDI, Benedetta ,  CARBONARA, Maria ,  VINCENZI, Paolo

    IPC: C08F4/654 ,  C08F4/649

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F4/022 ,  C08F4/6543 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651

    Abstract: The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH
    2 =CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

    Abstract translation: 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物聚合的催化剂组分，其中R为具有1-12个碳原子的烷基，环烷基或芳基，包含Ti，Mg，卤素和电子给体 到1,2-二醚作为内部电子给体化合物。 本发明的催化剂适合用于乙烯的（共）聚合过程以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS
    104.
    发明公开
    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2029277A1

    公开(公告)日：2009-03-04

    申请号：EP07729982.4

    申请日：2007-06-07

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

    IPC: B01J27/135 ,  B01J27/138 ,  C08F4/642 ,  C08F10/00

    CPC classification number: C08F10/00 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature ranging from 0°C to 80°C and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C.

    Abstract translation: 包括Mg，Ti，卤素和电子给体的烯烃聚合的催化剂组分通过间歇方法获得，该方法包括：（A）第一步，该方法包括使式MgCl 2（ROH）n的加合物（其中R为C 1 -C 10 烷基，并且n为0.5-6，在包含至少具有Ti-Cl键的钛化合物的液体介质中，在0℃至80℃的温度范围内，然后除去液体介质; （B）随后的步骤包括使在（A）中获得的固体产物在包含选自醚，酯，酮，硅烷，胺，腈和酰胺的电子给体ED的液体介质中与具有至少一个Ti -Cl键的温度高于80℃，然后除去液体介质后， （C）随后的步骤包括使来自（B）的固体产物与包含至少具有Ti-Cl键的钛化合物的液体介质在高于80℃的温度下反应。

    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS
    110.
    发明公开
    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS 有权
    VERFAHREN ZUR HERSTELLEN VONPORÖSENPROPYLENPOLYMEREN

    公开(公告)号：EP3060588A1

    公开(公告)日：2016-08-31

    申请号：EP14786901.0

    申请日：2014-10-21

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GADDI, Benedetta ,  BOCCHINO, Marco ,  COLLINA, Gianni ,  FUSCO, Ofelia ,  GUIDOTTI, Simona ,  MAZZUCCO, Antonio ,  PANTALEONI, Roberto ,  PIEMONTESI, Fabrizio

    IPC: C08F10/06 ,  C08F210/06

    CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

    Abstract: Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH2=CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins producing said porous propylene (co)polymer.

    Abstract translation: 在催化剂体系存在下进行的多孔丙烯的制备方法，包括（a）含有至少两种电子给体化合物的齐格勒 - 纳塔催化剂，其中一种以50-90％ 相对于供体的总量，选自琥珀酸盐，另一种选自1,3-二醚，（b）烷基铝，包括以下步骤：i）使催化剂组分（a）和（b）接触一段时间 时间为1至60分钟，温度范围为35至55℃; 任选地，ii）使用一种或多种式CH 2 = CHR的烯烃进行预聚合，其中R是H或C1-C10烃基，直到每克固体催化剂组分约0.1至约1000g的聚合物的形成量 （一个）; 和iii）在少量乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，生产所述多孔丙烯（共）聚合物。

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