公开(公告)号：JP2003128056A

公开(公告)日：2003-05-08

申请号：JP2001329957

申请日：2001-10-26

Applicant: TORAY INDUSTRIES

Inventor： HAMAGUCHI MITSUSHIGE ,  MATSUOKA HIDEO ,  KOBAYASHI KAZUHIKO

IPC: B65D1/00 ,  B29C45/16 ,  B29C69/00 ,  B29K23/00 ,  B29K77/00 ,  B29L22/00 ,  B32B1/02 ,  B65D1/09 ,  B65D6/00 ,  B65D65/40 ,  B65D77/06 ,  C08K7/00 ,  C08L23/00 ,  C08L77/00

Abstract: PROBLEM TO BE SOLVED: To provide a multi-layer hollow container with barrier property and its manufacturing method that is excellent in flexibility for container design, barrier property, inter-layer bonding ability, and mechanical characteristics. SOLUTION: The multi-layer hollow container comprises a barrier layer composed of (a) polyolefin resin, (b) polyamide resin, (c) liquid crystalline resin and/or (d) resin composition composed of layer-state silicate and a thermoplastic resin layer composed of (e) other thermoplastic resins than the resin compositions constituting the barrier layer, and is a barrier multi-layer hollow container characterized in that it contains, in one part therein, a fuse-bonding part whose strength is 60% or more of that of the non-fuse-bonding part.

公开(公告)号：JP2002275313A

公开(公告)日：2002-09-25

申请号：JP2001075473

申请日：2001-03-16

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  HAMAGUCHI MITSUSHIGE ,  KOBAYASHI KAZUHIKO

IPC: C08J5/00 ,  B29C45/00 ,  C08L23/00 ,  C08L23/02 ,  C08L23/06 ,  C08L51/06 ,  C08L67/00 ,  C08L77/00 ,  C08L81/02 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide a molded resin article which retains toughness and moldability inherent in polyolefin resins and exhibits a specifically improved permeability to chemicals and gases. SOLUTION: This molded resin article comprises (a) a polyolefin resin and (b) a thermoplastic resin other than a polyolefin resin. The phase structure of the article observed by an electron microscope contains parts wherein (a) the polyolefin resin forms a continuous phase and parts wherein (b) the resin other than a polyolefin resin forms a continuous phase.

公开(公告)号：JP2002249595A

公开(公告)日：2002-09-06

申请号：JP2001047245

申请日：2001-02-22

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  HAMAGUCHI MITSUSHIGE ,  KOBAYASHI KAZUHIKO

IPC: B65D1/00 ,  B29C45/00 ,  B65D1/09 ,  C08J5/00 ,  C08K3/00 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide an injection molded article which utilizes such essential features of a polyolefin resin as toughness, and molding and processing characteristics and which is excellent in resistance to permeation of a liquid chemical and a gas. SOLUTION: The injection molded article comprises a resin composition consisting of (a) 55-95 vol.% of a polyolefin resin and (b) 45-5 vol.% of an ethylene/vinyl alcohol copolymer, and forms a phase structure consisting of (a) a continuous phase comprising a polyolefin resin and (b) a disperse phase in the form of strips comprising an ethylene/vinyl alcohol copolymer in the resin phase separated structure observed with an electron microscope.

公开(公告)号：JP2002060567A

公开(公告)日：2002-02-26

申请号：JP2000246957

申请日：2000-08-16

Applicant: MITSUI CHEMICALS INC ,  TORAY INDUSTRIES

Inventor： KANDA HIROSHI ,  TODO AKIRA ,  MATSUOKA HIDEO ,  KOBAYASHI KAZUHIKO

IPC: C08J5/00 ,  C08F2/44 ,  C08F255/00 ,  C08K5/00 ,  C08L23/26 ,  C08L67/00 ,  C08L91/00

Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic elastomer composition excellent in oil resistance, rubber elasticity, mechanical characteristics, abrasion resistance, scratch resistance and moldability, and to obtain moldings from the composition. SOLUTION: This thermoplastic resin composition is characterized in that the composition comprises (A) 90-40 wt.% of a functional group containing olefin copolymer rubber composition modified with a polar functional group containing vinyl monomer and (B) 10-60 wt.% of a polyamide resin composition, the functional group containing olefin copolymer rubber composition (A) is composed of a functional group containing olefin copolymer rubber (a) and a softener (b) for a rubber, the polyamide resin (B) is composed of a polyamide resin (c) and a plasticizer (d) and the functional group-containing olefin copolymer rubber composition (A) is dispersed into the polyamide resin composition (B) to form a phase structure.

公开(公告)号：JP2001302910A

公开(公告)日：2001-10-31

申请号：JP2000219524

申请日：2000-07-19

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  HAMAGUCHI MITSUSHIGE ,  KOBAYASHI KAZUHIKO

IPC: B65D65/02 ,  C08J5/00 ,  C08K3/00 ,  C08K7/00 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08L23/26 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06

Abstract: PROBLEM TO BE SOLVED: To provide a resin molding for a gas and/or liquid barrier component exhibiting resistance to permeation of a gas and/or a liquid even when used at a high humidity and having excellent properties upon water absorption because it decreases little, for example, in dimensional change and mechanical properties such as rigidity upon moisture absorption. SOLUTION: Provided is a resin molding for a gas and/or liquid barrier component, comprising a resin composition substantially consisting of (a) a polyamide resin and (b) a polyolefin resin in a specified mixing ratio and, when observed with an electron microscope, having a specified resin phase separation structure such as one in which polyolefin resin (b) constitutes a matrix phase (continuous phase), and polyamide resin (a) constitutes a disperse phase.

公开(公告)号：JP2001072864A

公开(公告)日：2001-03-21

申请号：JP24917499

申请日：1999-09-02

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  KOBAYASHI KAZUHIKO

IPC: C08L77/00 ,  C08K7/14 ,  C08L71/00

Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition having excellent heat resistance, vibration welding property, etc., suitable for a hollow molding product such as an intake manifold of automobile by compounding a nylon resin with a bis unsaturated fatty acid ester of a specific polyalkylene glycol and a glass fiber in specific amounts, respectively. SOLUTION: This composition is obtained by compounding (A) 100 pts.wt. of a nylon resin (e.g. nylon 66, etc.), with (B) 0.1-30 pts.wt. of a bis unsaturated fatty acid ester of a polyalkylene glycol of the formula (R1 is a 6-40C unsaturated aliphatic hydrocarbon; n and m are each 0 or >=1; n+m is 5-100) and (C) 10-150 pts.wt. of a glass fiber. A bisoleic acid ester of polyethylene glycol, propylene glycol or polyethylene/propylene glycol copolymer is preferable as the component B. Preferably the composition is further compounded with 0.1-50 pts.wt. of a modified ethylene/α-olefin-based copolymer.

公开(公告)号：JP2001011307A

公开(公告)日：2001-01-16

申请号：JP24440099

申请日：1999-08-31

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  OKITA SHIGERU

IPC: C08L77/00 ,  C08K7/14 ,  C08L23/00

Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition for welding, exhibiting high weld strength in addition to excellent characteristic properties of nylon resin such as moldability, heat-resistance and toughness and giving a weld resin article having high weld strength by compounding a nylon resin, a polyolefin resin and glass fiber at specific ratios. SOLUTION: The objective composition is produced by compounding (A) 100 pts.wt. of a nylon resin with (B) 0.1-50 pts.wt. of a polyolefin resin and (C) 10-150 pts.wt. of glass fiber. Preferably, the composition is produced by melting and kneading 100 pts.wt. of the component A, 0.1-50 pts.wt. of the component B, 10-150 pts.wt. of the component C and (D) 0-3 pts.wt. of a copper compound and (E) 0-5 pts.wt. of a silicone compound or by melting and kneading 100 pts.wt. of the component A with 10-150 pts.wt. of the component C, 0-3 pts.wt. of the component D and 0-5 pts.wt. of the component E and kneading 0.1-50 pts.wt. of the component B to the obtained mixture. The welding is preferably carried out by vibration welding, injection welding, ultrasonic welding, etc.

公开(公告)号：JP2000290441A

公开(公告)日：2000-10-17

申请号：JP9929699

申请日：1999-04-06

Applicant: MITSUI CHEMICALS INC ,  TORAY INDUSTRIES

Inventor： TODO AKIRA ,  MATSUNAGA SHINYA ,  MATSUOKA HIDEO ,  MIYAMOTO KAZUKI ,  OKITA SHIGERU

IPC: C08L23/08 ,  C08L51/06 ,  C08L77/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition of low specific gravity, excellent in oil resistance, heat resistance, mechanical properties and moldability, and to obtain a molded form by using the composition. SOLUTION: This composition comprises a total 100 wt.% of (A) 10-60 wt.% of a functional group-contg. olefin-based copolymer rubber obtained by modifying the corresponding olefin-based copolymer rubber with a vinyl monomer having at least one functional group selected from acid anhydride group, epoxy group, carboxyl group and carboxylic ester, (B) 10-60 wt.% of an ethylene-based copolymer obtained from ethylene and a >=6C α-olefin, and (C) 10-50 wt.% of a polyamide resin.

公开(公告)号：JP2000095948A

公开(公告)日：2000-04-04

申请号：JP26703898

申请日：1998-09-21

Applicant: TORAY INDUSTRIES

Inventor： NISHIMURA TORU ,  MATSUOKA HIDEO ,  YAMANAKA TORU

IPC: C08J5/00 ,  C08K3/34 ,  C08K3/40 ,  C08L67/00 ,  C08L77/00 ,  C08L81/02 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide welding resin compositions which are proportionately excellent in heat stability, external appearance of molded articles, mechanical strength and vibration weldability and are suitable for hollow products which can be obtained by the vibration welding of two or more molded articles after melt molding. SOLUTION: Vibration welding resin compositions comprise (A) 100 pts.wt. thermoplastic resin and (B) 0.1-50 pts.wt. layer silicate which is a swelling layer silicate and vibration welding resin compositions comprise (A) 100 pts.wt. thermoplastic resin, (B) 0.1-50 pts.wt. layer silicate which is a swelling layer silicate, and (C) 10-150 pts.wt. glass fibers having an average fiber diameter of 5-15 μm. Further, the layer silicate (B) is the one in which exchangeable cationic ions present between layers have been exchanged with organic onium ions, and the thermoplastic resin (A) is at least one resin selected from a polyamide resin, a polyester resin, and a polyphenylene sulfide resin.

公开(公告)号：JP2000044796A

公开(公告)日：2000-02-15

申请号：JP21151298

申请日：1998-07-27

Applicant: TORAY INDUSTRIES

Inventor： MATSUOKA HIDEO ,  ONISHI KOJI ,  OKITA SHIGERU

IPC: C08K3/00 ,  C08K3/02 ,  C08K7/14 ,  C08L77/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compsn. having excellent mechanical characteristics, heat resistance, moldability, and dimensional stability, and also a small change in the toughness deterioration and in the dimension at the time of water absorption. SOLUTION: A resin compsn. comprises 100 pts.wt. of component (A) of a polyamide resin which consists of 75-45 mole % of (a) hexamethylene terephthalamide unit, 10-25 mole % of (b) hexamethylene terephthalamide and/or hexamethylene hexahydro-terephthalamide units and 15-30 mole % of (c) an aliphatic polyamide unit having the number of carbon atoms per one amide group (amide group concn.) of 8 or more and which has the properties within the range described below and 0.1-50 pts.wt. of component (B) of a nonhalogen- based flame retardant. (1) an m.p.: not lower than 280 deg.C to lower than 325 deg.C. (2) a glass transition point at the time of satd. water absorption which is determined by a viscoelastic measurement, of 40 deg.C or above, and also a loss elastic modulus having at least one peak of plurally observed ones, at 80 deg.C or above.