COMPOSITION WITH A POLYMER AND AN OXIDATION-CATALYST

    公开(公告)号:US20110034637A1

    公开(公告)日:2011-02-10

    申请号:US12811757

    申请日:2009-01-09

    CPC classification number: C08K5/07 C08K5/15 C08K2201/012

    Abstract: The present invention relates to a polymer composition with an increased rate of oxygen-uptake by the presence of a co-catalyst and an oxidation catalyst. The oxidation catalyst has the following structure with R1: a group selected independently from one another from the groups consisting of H, an optionally substituted C1-C20 alkyl group, an optionally substituted C6-C20 aryl group, an optionally substituted C7-C20 alkylaryl group, and an optionally substituted C7-C20 arylalkyl group; R2: OR, SR, NRR′, R, O−M+; in which R, R′: a group selected independently from one another from the groups consisting of H, an optionally substituted C1-C20 alkyl group, an optionally substituted C6-C20 aryl group, an optionally substituted C7-C20 alkylaryl group, and an optionally substituted C7-C20 arylalkyl group; M+: an alkaline metal cation or earth alkaline metal cation, or an ammonium ion; R3: SR, NRR′, R, O−M+; in which R, R′: a group selected independently from one another from the groups consisting of H, an optionally substituted C1-C20 alkyl group, an optionally substituted C6-C2 aryl group, an optionally substituted C7-C20 alkylaryl group, and an optionally substituted C7-C20 arylalkyl group; M+: an alkaline metal cation or earth alkaline metal cation, or an ammonium ion. R1-R3 may be joined together to form a cyclic structure. Or R3: OR in which R: a group selected independently from one another from the groups consisting of H, an optionally substituted C1-C20 alkyl group, an optionally substituted C6-C20 aryl group, an optionally substituted C7-C20 alkylaryl group, and an optionally substituted C7-C20 arylalkyl group and at least one of R1, R2 and R3 are joined together and form a cyclic structure containing less than 5 carbon atoms. The co-catalyst is at least one of an alkaline metal salt, earth alkaline metal salt or an ammonium salt. The invention further relates to a process to increase the rate of oxygen-uptake by a polymer composition. The invention also relates to a process to increase the oxo-biodegradability of a polymer composition and to the use of such a composition for the preparation of a product having a controlled lifetime. The invention further relates to a process to increase the rate of oxygen-scavenging in a composition containing a carbon-containing polymer, the composition obtained by this method and its use in the preparation of an oxygen-scavenging product. The present invention further relates to objects containing an oxygen scavenging layer containing such a composition.

    Oxygen-absorbing container cap
    107.
    发明授权
    Oxygen-absorbing container cap 失效
    吸氧容器盖

    公开(公告)号:US07704407B2

    公开(公告)日:2010-04-27

    申请号:US11921769

    申请日:2005-06-15

    Abstract: The present invention provides an oxygen-absorbing resin composition, which is superior in oxygen absorbability, absorbs oxygen remaining in the container after sealing, keeps the contents in the container in good preservation, and improves moldability, dispersibility of the oxygen absorbent, stability of the oxygen absorbing performance, performance of preventing peeling and separation of the oxygen absorbent from the base resin, rigidity of the sealing part, and the like, which become problems in the case of including an oxygen absorbent having high oxygen absorbability and low compatibility with the base resin, as well as provides an oxygen-absorbing container cap and an oxygen-absorbing container plug using the same.The present invention provides an oxygen-absorbing resin composition characterized by being obtained by dispersing and blending an oxygen absorbent containing 20% or more of particles having a particle diameter of 1000 μm or less at a ratio of 20% or less to a base resin.

    Abstract translation: 本发明提供吸氧性优异的氧吸收性树脂组合物,其吸收密封后的容器中剩余的氧气,保持容器内容物的良好保存性,提高成型性,吸氧剂的分散性, 氧吸收性能,防止氧吸收剂从基础树脂剥离和分离的性能,密封部的刚性等,在包含具有高氧吸收性的氧吸收剂和与碱的相容性低的情况下成为问题 树脂,并且提供吸氧容器盖和使用其的吸氧容器塞。 本发明提供一种氧吸收性树脂组合物,其特征在于,通过将含有20%以上的粒径为1000μm以下的粒子的氧吸收剂与基础树脂以20%以下的比例分散混合而获得。

    Water Activated Organic Scavenger
    109.
    发明申请
    Water Activated Organic Scavenger 审中-公开
    水活化有机清除剂

    公开(公告)号:US20060261307A1

    公开(公告)日:2006-11-23

    申请号:US11383799

    申请日:2006-05-17

    Abstract: Disclosed is a polyester composition of a polyester, an oxygen sensitive compound, such as a polyamide and a promoter which causes the oxygen sensitive compound to become reactive with oxygen and the promoter is strategically placed into the polyester or present at less than critical moisture activation ratio of the amount of oxygen sensitive compound to the amount of promoter, whereby there is more oxygen reactivity when the composition is wet, than when the composition is dry.

    Abstract translation: 公开了一种聚酯的聚酯组合物,氧敏感化合物如聚酰胺和助催化剂,其使氧敏感化合物变得与氧反应,并且促进剂被战略性地置于聚酯中或以低于临界水分活化比存在 的氧敏感化合物的量相对于促进剂的量,由此当组合物湿时,比组合物干燥时氧反应性更高。

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