Treatment of low concentration H2S gas streams in liquid phase Claus reactor
    114.
    发明公开
    Treatment of low concentration H2S gas streams in liquid phase Claus reactor 失效
    在Flüssigphase-Claus-Reaktoren的Behandlung vonGasströmenmit Niedriger H2S-Konzentration。

    公开(公告)号:EP0124162A2

    公开(公告)日:1984-11-07

    申请号:EP84200498.8

    申请日:1984-04-09

    CPC classification number: C01B17/05 B01D53/52

    Abstract: Gas streams containing low concentrations, e.g., under 20 vol. %, of H 2 S can be treated in a liquid phase Claus reactor under superatmospheric pressure. The use of such higher pressures aids in solubilizing the H 2 S and allows for its removal from such streams even though it is present in very dilute form.

    Abstract translation: 含有低浓度的气流,例如低于20体积% %的H 2 S可以在液相Claus反应器中在超大气压下进行处理。 使用这种较高的压力有助于溶解H2S,并且允许其从这种流中除去,即使其以非常稀的形式存在。

    Method for preparation of salts of N-phosphonomethylglycine
    119.
    发明公开
    Method for preparation of salts of N-phosphonomethylglycine 失效
    一种用于N-膦的盐的制备方法。

    公开(公告)号:EP0117337A1

    公开(公告)日:1984-09-05

    申请号:EP83306353.0

    申请日:1983-10-19

    CPC classification number: C07F9/3813

    Abstract: A process for the preparation of sulfonium or sulfoxonium salts of N-phosphonomethylglycine which comprises:

    (1) reacting N-phosphonomethylglycine, a compound of the formula

    with a compound selected from the group consisting of those having the formula
    wherein R 1 , R 2 and R 3 are the same or different and are alkyl groups having from 1 to 4 carbon atoms or aromatic alkyl groups, X is chloride, bromide or iodide and Z is an electron pair or oxygen, or
    wherein R" R 2 and R 3 are the same of different and are alkyl groups having from 1 to 4 carbon atoms and are the same as in (a) above, R 4 is an alkyl group having from 1 to 12 carbon atoms, aromatic or aromatic alkyl groups, X is chlorine or iodine, and Y is nitrogen or phosphorus, said reaction being conducted in the presence of a trialkylamine of the formula
    wherein each R is the same or different and is an alkyl group ranging from 4 to 13 carbon atoms, all in the presence of water and a polar functional organic solvent which is immiscible in water, said reaction being conducted at a temperature and for a sufficient period of time to cause completion of the reaction, and

    (2) isolating the end product by phase separation.

    The process is simpler and less expensive than other processes.

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