Abstract:
A golf ball including a core; an inner cover layer formed from a thermoplastic composition and having a thickness of about 0.005 inches to 0.40 inches and a surface hardness of about 60 Shore D or greater; and an outer cover layer formed from a thermoset material and having a thickness of about 0.01 inches to 0.05 inches and a surface hardness of about 60 Shore D or less. The thermoplastic composition has a first melt flow index at 280° C. under a 10-kg load of less than about 35 g/10 min and a second melt flow index at 265° C. under a 5-kg load of less than about 10 g/10 min.
Abstract translation:包括芯的高尔夫球; 由热塑性组合物形成并具有约0.005英寸至0.40英寸的厚度和约60肖氏D或更高的表面硬度的内覆层; 以及由热固性材料形成并且具有约0.01英寸至0.05英寸的厚度和约60肖氏D或更低的表面硬度的外覆盖层。 热塑性组合物在280℃下的第一熔体流动指数在小于约35g / 10min的10kg负载下和在265℃下的第二熔体流动指数在5kg负荷下小于约 10 g / 10 min
Abstract:
Disclosed herein are heterogeneous golf ball compositions comprising a thermosetting polymer matrix and discrete particles of thermoplastic polymer dispersed within the matrix.
Abstract:
A golf ball includes a core including a thermoplastic inner core and a thermoset outer core layer. The inner core has a surface hardness of about 40 to 80 Shore C and a center hardness of about 30 to 75 Shore C. The center hardness is less than the surface hardness to define a positive hardness gradient. A cover is formed over the core and includes an inner cover layer and an outer cover layer. The thermoplastic inner core includes a highly-neutralized ionomer formed from a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater. The outer core layer comprises a polybutadiene rubber and has a positive hardness gradient of less than 25 Shore C.
Abstract:
The present invention is directed to a golf ball and, more particularly, a golf ball having a polybutadiene based core, a cover disposed about the core, and optionally an intermediate layer disposed between the core and the cover. In one embodiment, at least one or more portions of the core, cover, or intermediate layer comprises a blend of thermoplastic or thermoset material and about 1 to 10 pphr of a nanocrystalline cellulose material.
Abstract:
A golf ball comprising a core and a cover disposed about the core; wherein at least one of the core and the cover comprises a tri-blend composition of the non-E/X/Y type (TBC) formed from a blend of an ethylene acid (E/X) ionomer, a non-ionomeric softening copolymer (NISC) and a low viscosity component (LVC). A portion of the TBC comprising the ethylene acid (E/X) ionomer and the NISC has a Melt Flow Index MF1 and a CoR1 and the TBC has a Melt Flow Index MF2 and a CoR2 such that MF2>MF1 and CoR1 and CoR2 differ by less than about 0.1. In one embodiment, the TBC has a composition property relationship ΔCoR/ΔMFI≦˜10, wherein ΔCoR is the amount by which CoR1 and CoR2 differ, and ΔMFI=(MFI2−MFI1). In one embodiment, the TBC comprises a phase-separated blend. The invention is also directed to a method of making the golf ball.
Abstract:
A golf ball includes a core and a three-layer cover disposed adjacent the core. The three-layer cover includes an inner cover, an intermediate cover, and an outer cover. The inner cover includes a non-ionomeric E/Y copolymer where E is an olefin and Y is a carboxylic acid. The inner cover has a hardness of about 45 to 68 Shore D. The outer cover includes a castable thermoset polyurethane and has a hardness of about 40 to 62 Shore D. The intermediate cover layer, disposed between the inner and outer cover layers, is formed from a polyester composition including about 40 wt % to about 99 wt % of a polyester thermoplastic elastomer and about 1 wt % to about 60 wt % of a plasticizer.
Abstract:
A golf ball includes a thermoplastic HNP inner core layer having a center hardness less than the surface hardness to define a positive hardness gradient. An outer core layer is disposed about the inner core and is formed from a thermoset rubber composition. The core layer has an inner surface hardness less than the outer surface hardness to define a positive hardness gradient. Inner and outer cover layers are disposed about the outer core layer. The HNP composition includes an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid; a non-acid polymer comprising polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, or functionalized derivatives thereof; an organic acid or salt thereof; and a cation source in an amount sufficient to neutralize at least about 80% of the acid groups.
Abstract:
Golf balls having a core comprising a polyalkenamer rubber composition are provided. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel. In one version, a solid, single core having an outer surface and geometric center is provided, wherein the outer surface has a hardness greater than the hardness of the geometric center to define a positive hardness gradient of at least 10 Shore C. In a second version, a dual-core having an inner core and surrounding outer core layer is provided. The inner core has a positive hardness gradient, while the outer core has a zero; negative; or positive hardness gradient.
Abstract:
The invention is directed to a method of making a neutralized non-ionomeric polymer composition (NNIPC) suitable for use in a golf ball component comprising the steps of: providing a non-acid copolymer composition (NACC); soaking the NACC in an organic acid to form a soaked non-acid copolymer composition (SNACC); providing a cation source in an amount sufficient to neutralize at least a portion of the organic acid; and melt processing the SNACC and cation source to form the NNIPC. The invention also relates to a method of making a golf ball incorporating the NNIPC made according to the inventive method and to the resulting golf ball.
Abstract:
Multi-layered golf balls having at least one layer made of polyamide/acid anhydride-modified polyolefin blended compositions are provided. Preferably, a transparent polyamide is used. In one version, the composition comprises a blend of polyamide, acid anhydride-modified polyolefin, and plasticizer. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyamide/acid anhydride-modified polyolefin composition may be used to form any core, cover, or other layer in the golf ball. In one version, the polyamide/acid anhydride-modified polyolefin composition is used to form the outer core layer, and a rubber composition is used to form the inner core.