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    PROCESS FOR THE PREPARATION OF PROPYLENE RANDOM COPOLYMERS
    112.
    发明公开
    PROCESS FOR THE PREPARATION OF PROPYLENE RANDOM COPOLYMERS 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON RANDOM-PROPYLENCOPOLYMEREN

    公开(公告)号：EP2909244A1

    公开(公告)日：2015-08-26

    申请号：EP13773713.6

    申请日：2013-10-03

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  CAPUTO, Tiziana ,  SQUARZONI, Stefano ,  MAZZUCCO, Antonio ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  COLLINA, Gianni

    IPC: C08F210/06 ,  C08F4/651

    Abstract: A process for the preparation of random copolymer of propylene containing up to 6.0 % by weight of ethylene units, suitable for the manufacture of pipes, by copolymerizing propylene and ethylene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) n aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound.

    Abstract translation: 一种制备含有至多6.0重量％乙烯单元的丙烯的无规共聚物的方法，该乙烯单元通过在包含通过接触以下组分获得的产物的催化剂体系的存在下共聚丙烯和乙烯来制备管道： （a）固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以相对于总量为40至90摩尔％的量存在 选自琥珀酸盐，另一种选自1,3二醚，（b）n烃基铝化合物和（c）任选的外电子给体化合物。

    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    113.
    发明公开
    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的预聚合的组分催化剂

    公开(公告)号：EP2794680A1

    公开(公告)日：2014-10-29

    申请号：EP12806005.0

    申请日：2012-12-11

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： BRITA, Diego ,  COLLINA, Gianni ,  MORINI, Giampiero

    IPC: C08F10/00 ,  C08F4/649

    CPC classification number: C08F210/02 ,  C08F10/00 ,  C08F4/6492

    Abstract: A pre-polymerized catalyst component for the polymerization of olefins endowed with high activity and morphological stability comprises (i) a non-stereospecific solid catalyst component comprising Ti, Mg and a halogen and having a porosity, due to pores with radius up to 1 μm, ranging from 0.2 to 0.8 cm
    3 /g and (ii) an amount of an ethylene/alpha-olefm block (co)polymer ranging from 0.1 up to 5g per g of said solid catalyst component (i), said pre-polymerized catalyst component being characterized by a mercury porosity due to pores up to 1 μm of less than 70% the mercury porosity value of the said non-stereospecific solid catalyst component (i).

    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS
    115.
    发明公开
    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS 有权
    VERFAHRENFÜRDIE HERSTELLUNG VON HOCHREINEN PROPYLENPOLYMEREN

    公开(公告)号：EP2758440A1

    公开(公告)日：2014-07-30

    申请号：EP12759441.4

    申请日：2012-09-17

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GALVAN, Monica ,  PANTALEONI, Roberto ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  NEUMANN, Andreas ,  MAZZUCCO, Antonio ,  COLLINA, Gianni ,  SARTORI, Gabriella

    IPC: C08F4/651 ,  C08F4/654 ,  C08F10/06 ,  C08J5/18 ,  C08F4/649

    CPC classification number: C08F10/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F4/651 ,  C08F4/6543 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15

    Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

    Abstract translation: 一种制备高纯度丙烯聚合物的方法，所述丙烯聚合物在催化剂存在下进行，所述催化剂包括通过使（a）包含Mg，Ti和至少第一内部电子给体化合物（HD）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内给电子体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物，并且任选地与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分的摩尔比 （b）:( a）低于5。

    MAGNESIUM DICHLORIDE-ALCOHOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM
    118.
    发明公开
    MAGNESIUM DICHLORIDE-ALCOHOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 有权
    金刚石二极管 - 阿尔霍尔德·杜卡克斯达拉斯GEWONNENE KATALYSATORKOMPONENTEN

    公开(公告)号：EP2699605A1

    公开(公告)日：2014-02-26

    申请号：EP12714009.3

    申请日：2012-04-13

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GADDI, Benedetta ,  EVANGELISTI, Daniele ,  COLLINA, Gianni

    IPC: C08F10/00 ,  B01J37/00

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F10/00 ,  C08F110/06 ,  C08F4/022 ,  C08F4/6545

    Abstract: Process for the preparation of solid particles of a magnesium-chloride alcohol adduct comprising (a) forming an emulsion between a MgCl2 .alcohol adduct in molten form and a liquid phase which is immiscible with the said adduct in the presence of a polyalkyl-methacrylate used as a solution having viscosity ranging from 100 to 5000 mm2/s and (b) rapidly cooling the emulsion to solidify the disperse phase and collecting the solid adduct particles.

    Abstract translation: 用于制备氯化镁醇加合物的固体颗粒的方法，包括（a）在熔融形式的MgCl 2醇加合物与在所述加合物中不混溶的液相之间形成乳液，所述液相在作为 粘度范围为100至5000mm 2 / s的溶液和（b）快速冷却乳液以固化分散相并收集固体加合物颗粒。

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