公开(公告)号：EP2870280B1

公开(公告)日：2019-03-06

申请号：EP13730182.6

申请日：2013-06-13

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  PANTALEONI, Roberto ,  MAZZUCCO, Antonio ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  COLLINA, Gianni

IPC: D01F6/06 ,  C08F4/651 ,  C08F10/06

公开(公告)号：EP2931513B1

公开(公告)日：2018-05-23

申请号：EP13798295.5

申请日：2013-11-25

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  COLLINA, Gianni ,  CAPUTO, Tiziana ,  SQUARZONI, Stefano ,  MAZZUCCO, Antonio

IPC: B32B1/08 ,  B32B27/32 ,  C08F210/06 ,  C08J5/18 ,  F16L9/12 ,  C08F10/00 ,  B32B27/08 ,  C08F10/14

CPC classification number: C08F10/14 ,  B32B1/08 ,  B32B27/08 ,  B32B27/32 ,  B32B2307/558 ,  B32B2597/00 ,  C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08L2314/02 ,  F16L9/12 ,  C08F4/651 ,  C08F2/001 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/21 ,  C08F4/6492 ,  C08F4/6548

Abstract: A terpolymer containing propylene, ethylene and 1-hexene obtainable by the step of copolymerizing propylene, ethylene and 1-hexene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound. wherein in the terpolymer (i) the content of 1-hexene derived units ranges from 0.5 to 5.0 wt%; (ii) the content of ethylene derived units is higher than 1.4 t% and fulfils the following relation (1): C �¢ 2

公开(公告)号：EP2443159B1

公开(公告)日：2018-04-25

申请号：EP10725462.5

申请日：2010-06-16

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COLLINA, Gianni ,  CIARAFONI, Marco ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  GALVAN, Monica ,  MORINI, Giampiero ,  PANTALEONI, Roberto ,  VERROCCHIO, Francesca

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/649

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6494

Abstract: A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.

公开(公告)号：EP3063186B1

公开(公告)日：2017-10-18

申请号：EP14771919.9

申请日：2014-09-24

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  CATHELIN, Caroline ,  TISI, Francesca ,  PELLEGATTI, Giampaolo

IPC: C08F210/06 ,  C08L23/14 ,  B32B27/32 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08L23/14 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/20

公开(公告)号：EP2598544B1

公开(公告)日：2016-11-02

申请号：EP11736386.1

申请日：2011-07-29

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： CIARAFONI, Marco ,  GALVAN, Monica ,  MARZOLLA, Roberta ,  MASSARI, Paola

IPC: C08F210/06 ,  C08J5/18 ,  C08F210/16

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/14 ,  Y10T428/31938 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/21 ,  C08F2500/26

公开(公告)号：EP2970534A2

公开(公告)日：2016-01-20

申请号：EP14707993.3

申请日：2014-03-03

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  CAPUTO, Tiziana ,  SQUARZONI, Stefano ,  MAZZUCCO, Antonio ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  COLLINA, Gianni ,  BIONDINI, Gisella ,  CAVALIERI, Claudio ,  PANTALEONI, Roberto

IPC: C08F210/16

CPC classification number: C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F110/06 ,  C08F4/6492 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

Abstract translation: 丙烯三元通过聚合丙烯，乙烯和在通过使固体催化剂组分，包括镁卤化物得到的催化剂体系的存在下选自C 4 -C 8α-烯烃中选择的α-烯烃制得，其具有至少一个钛化合物 一个Ti-卤键和至少两种给电子体化合物，其中的一个存在于在相对于供体的总量为40〜90％的量（摩尔），从磺基琥珀选定，而另一个选自1,3-二醚中选择，以 烃基铝化合物，和任选的外部电子给体化合物。

公开(公告)号：EP2852624A1

公开(公告)日：2015-04-01

申请号：EP13724253.3

申请日：2013-05-21

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MARZOLLA, Roberta ,  GALVAN, Monica ,  CAPUTO, Tiziana

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt% to 2.2 wt% of ethylene derived units and from 6.0 wt% to 20.0 wt% of 1 butene derived units; wherein: i) the ratio C2wt%/C4wt% ranges from 0.09 to 0.06; wherein C2wt% is the weight per cent of ethylene derived units and C4wt% is the weight per cent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25°C is lower than 15.0 wt% the minimum value being 5.0 wt%.

Abstract translation: 含有0.5重量％至2.2重量％的乙烯衍生单元和6.0重量％至20.0重量％的1个丁烯衍生单元的丙烯，乙烯，1-丁烯三元共聚物; 其中：i）C2wt％/ C4wt％的比率为0.09至0.06; 其中C2wt％是乙烯衍生单元的重量百分数，C4wt％是1-丁烯衍生单元的重量百分数; ii）熔体流动速率范围为0.4至54g / 10min; iii）25℃下的二甲苯可溶部分低于15.0重量％，最小值为5.0重量％。

公开(公告)号：EP2788388A1

公开(公告)日：2014-10-15

申请号：EP12795438.6

申请日：2012-12-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MARZOLLA, Roberta ,  GALVAN, Monica ,  CAPUTO, Tiziana

IPC: C08F2/00 ,  C08F2/34 ,  C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/26 ,  C08F2/001 ,  C08F4/6492

Abstract: A propylene ethylene 1-butene terpolymer wherein: (i) the content of ethylene derived units ranges from 0.5 wt% to 2.0 wt%, (ii) the content of 1-butene rangesfrom 5.0 wt% to 8.0 wt%, (iii) the melting point (Tm) ranges from 136°C to 148°C; wherein said terpolymer is obtained with a polymerization process carried out in a gas-phase polymerization reactor comprising at least two interconnected polymerization zones.

公开(公告)号：EP2768898A1

公开(公告)日：2014-08-27

申请号：EP12775021.4

申请日：2012-10-19

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MARZOLLA, Roberta ,  GALVAN, Monica ,  FERRARO, Angelo

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L23/0815 ,  C08L2666/06

Abstract: A polyolefin compositions comprising: A) From 77 wt% to 90 wt%, of a propylene homopolymer having the fraction soluble in xylene at 25°C lower than 2 wt%; B) from 10 wt% to 23 wt% of a copolymer of ethylene with one C 4 -C 10 alpha-olefin containing from 20 wt% to 30 wt%, of said C 4 -C 10 alpha-olefin derived units; said composition having - the value of melt flow rate (MFR) at 230 °C, 2.16 kg of from 0.5 to 4.5 g/10 min; - the total content of ethylene of from 10 wt% to 18 wt%; - the value of the intrinsic viscosity of the total fraction soluble in Xylene at 25°C (AMXSIVtot) is less than 1.5 dl/g.

公开(公告)号：EP2488583B1

公开(公告)日：2014-01-15

申请号：EP10771046.9

申请日：2010-10-04

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： CAVALIERI, Claudio ,  PRADELLA, Fiorella ,  GALVAN, Monica

IPC: C08L23/14 ,  C08F210/06 ,  C08L23/08 ,  C08L23/16

CPC classification number: C08F210/06 ,  C08L23/0815 ,  C08L23/142 ,  C08L23/16 ,  C08F2/001 ,  C08L2666/06 ,  C08F210/16 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/12