PROCESS FOR PREPARING POROUS POLYOLEFIN PARTICLES
    118.
    发明公开
    PROCESS FOR PREPARING POROUS POLYOLEFIN PARTICLES 失效
    用于生产聚烯烃多孔

    公开(公告)号:EP0986602A1

    公开(公告)日:2000-03-22

    申请号:EP98928644.8

    申请日:1998-06-02

    Applicant: DSM N.V.

    CPC classification number: C08J9/28 C08J2201/052 C08J2201/0542 C08J2323/02

    Abstract: The invention relates to a process for preparing porous polyolefin particles. The process according to the invention is characterized in that it comprises the following steps: 1) dissolving at least one crystallizable polyolefin in a solvent, in the absence of a nucleating agent; 2) dispersing the polyolefin solution obtained in a non-solvent in the presence of a surfactant, at a temperature that is higher than the crystallization temperature of the polyolefin in the polyolefin solution; 3) cooling the multi-phase system obtained with stirring, at a rate of between 0.05 and 10 °C/min to a temperature that lies below the crystallization temperature of the polymer in the polymer solution, so that firm polyolefin particles are formed; 4) separating the polyolefin particles; 5) drying the polyolefin particles. The invention also relates to a porous polyolefin particle with a high effective loadability and a narrow particle size distribution.

    Porous membranes based on unstable polymer solutions
    120.
    发明公开
    Porous membranes based on unstable polymer solutions 失效
    聚合物聚合物。

    公开(公告)号:EP0533262A1

    公开(公告)日:1993-03-24

    申请号:EP92202785.9

    申请日:1992-09-11

    Inventor: Soldani, Giorgio

    Abstract: Porous, distensible, gel-like membranes which in tubular form are suitable as implants, e.g., vascular prostheses and a process for the preparation thereof is described. The membranes are formed by a spraying, phase-inversion technique which employs thermodynamically unstable polymer solutions and is accomplished by separately spraying the unstable solution and a nonsolvent onto a rotating surface. Prostheses from the highly porous tubular membranes have shown a high degree of patency and completeness of the healing process and are useful for direct implantation in the body or for extracorporeal vascular accesses.

    Abstract translation: 描述了管状形式的多孔,可扩张,凝胶状膜适合作为植入物,例如血管假体及其制备方法。 膜通过喷雾,相转化技术形成,其采用热力学不稳定的聚合物溶液,并且通过将不稳定溶液和非溶剂分别喷涂到旋转表面上来实现。 来自高度多孔的管状膜的假体显示出高度的通畅和愈合过程的完整性,并且可用于直接植入体内或用于体外血管通路。

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