FLAME RESISTANT POLYMER, POLYMER SOLUTION, FLAME RESISTANT FIBER, CARBON FIBER, AND METHODS FOR PRODUCING SAME
    115.
    发明公开
    FLAME RESISTANT POLYMER, POLYMER SOLUTION, FLAME RESISTANT FIBER, CARBON FIBER, AND METHODS FOR PRODUCING SAME 有权
    阻燃聚合物,聚合物溶液,防火纤维,碳纤维和方法及其生产

    公开(公告)号:EP3020735A1

    公开(公告)日:2016-05-18

    申请号:EP14823361.2

    申请日:2014-07-11

    Abstract: Provided are: a flame resistant polymer which is obtained by reacting polyacrylonitrile with amine and nitro compounds, the polyacrylonitrile being polymerized by aqueous suspension polymerization using a redox initiator and containing an S component at an amount of 3,000 µg/g or less; a polymer solution using the polymer; a flame resistant fiber using the polymer solution; a carbon fiber using the flame resistant fiber; and methods for producing the same. A PAN-based polymer in which both yarn producing properties and flame resistance are improved can be realized. Also provided are a polymer solution which is suitable for spinning using the polymer and a method for producing the same, a desirable flame resistant fiber using the polymer solution and a method for producing the same, and a desirable carbon fiber using the flame resistant fiber and a method for producing the same.

    Abstract translation: 提供有:一个阻燃聚合物所有这一切是通过使与胺和硝基化合物聚丙烯腈获得,聚丙烯腈由wässrige悬浮聚合使用氧化还原引发剂,并在S成分在含有3.000微克/克或更少量聚合; 使用聚合物的聚合物溶液; 一个阻燃纤维使用的聚合物溶液; 使用阻燃纤维的碳纤维; 以及用于生产同样的方法。 其中两个纱线生产性能和阻燃性提高阿PAN类聚合物即可实现。 这样提供了聚合物溶液的所有使用该聚合物和其制造方法,其是适于纺丝,使用该聚合物溶液和用于生产其的方法,以及所期望的碳纤维使用阻燃纤维所希望的阻燃纤维和 其制造方法。

    METHOD FOR PREPARING CELLULOSE NANOFIBER CAPABLE OF BEING STABLY DISPERSED
    116.
    发明公开
    METHOD FOR PREPARING CELLULOSE NANOFIBER CAPABLE OF BEING STABLY DISPERSED 审中-公开
    方法产生稳定分散的纤维素纳米碳纤

    公开(公告)号:EP2787105A4

    公开(公告)日:2015-07-29

    申请号:EP12852751

    申请日:2012-11-06

    Abstract: Disclosed is a method for preparing stably dispersed cellulose nanofibers. The method comprises following steps: 1) mixing cellulose and an organic solvent, the percentage of the cellulose being 1% to 15% in weight; 2) adding an esterification agent into the resultant mixture of step 1), the molar ratio of the esterification agent to the cellulose being from 1: 0.1 to 4; 3) physically breaking the resultant mixture of step 2) until a suspension liquid with stably dispersed cellulose nanofibers of 2-1000 nm in diameter and 100-100 µm in length is obtained, an esterification reaction of hydroxyl group(s) on the surface of cellulose fibers being occurring at the meantime of the breaking. Since the surface of the cellulose nanofibers with the esterified surface is hydrophobized by alkyl molecular chains, the dispersant solvent may be DMF, or may be replaced by other solvents. Moreover, when recombining the cellulose nanofibers of the invention with the synthetic resins, compatibility of the cellulose nanofibers to the matrix is better than that of the untreated cellulose, and thus the strength of the composite material may be improved.

    METHOD FOR PREPARING CELLULOSE NANOFIBER CAPABLE OF BEING STABLY DISPERSED
    117.
    发明公开
    METHOD FOR PREPARING CELLULOSE NANOFIBER CAPABLE OF BEING STABLY DISPERSED 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINER STABIL DISPERGIERBAREN ZELLULOSENANOFASER

    公开(公告)号:EP2787105A1

    公开(公告)日:2014-10-08

    申请号:EP12852751.2

    申请日:2012-11-06

    Abstract: Disclosed is a method for preparing stably dispersed cellulose nanofibers. The method comprises following steps: 1) mixing cellulose and an organic solvent, the percentage of the cellulose being 1% to 15% in weight; 2) adding an esterification agent into the resultant mixture of step 1), the molar ratio of the esterification agent to the cellulose being from 1: 0.1 to 4; 3) physically breaking the resultant mixture of step 2) until a suspension liquid with stably dispersed cellulose nanofibers of 2-1000 nm in diameter and 100-100 µm in length is obtained, an esterification reaction of hydroxyl group(s) on the surface of cellulose fibers being occurring at the meantime of the breaking. Since the surface of the cellulose nanofibers with the esterified surface is hydrophobized by alkyl molecular chains, the dispersant solvent may be DMF, or may be replaced by other solvents. Moreover, when recombining the cellulose nanofibers of the invention with the synthetic resins, compatibility of the cellulose nanofibers to the matrix is better than that of the untreated cellulose, and thus the strength of the composite material may be improved.

    Abstract translation: 公开了一种制备稳定分散的纤维素纳米纤维的方法。 该方法包括以下步骤:1)混合纤维素和有机溶剂,纤维素的重量百分比为1%至15%; 2)在步骤1)的所得混合物中加入酯化剂,酯化剂与纤维素的摩尔比为1:0.1至4; 3)将得到的步骤2)的混合物物理破碎,直至得到直径为2-1000nm,长度为100-100μm的纤维素纳米纤维稳定分散悬浮液,其表面上的羟基的酯化反应 纤维素纤维在破碎的同时发生。 由于具有酯化表面的纤维素纳米纤维的表面被烷基分子链疏水化,所以分散剂溶剂可以是DMF,或者可以被其它溶剂代替。 此外,当将本发明的纤维素纳米纤维与合成树脂重新组合时,纤维素纳米纤维与基质的相容性优于未处理的纤维素,因此可以提高复合材料的强度。

    NICHT-WÄSSRIGE ANTIDRÖHNMASSE MIT NICHT-PULVERFÖRMIGEM POLYACRYLATBINDEMITTEL UND RADIKALISCH POLYMERISIERBARER VERBINDUNG
    119.
    发明申请
    NICHT-WÄSSRIGE ANTIDRÖHNMASSE MIT NICHT-PULVERFÖRMIGEM POLYACRYLATBINDEMITTEL UND RADIKALISCH POLYMERISIERBARER VERBINDUNG 审中-公开
    非水性ANTIDRÖHNMASSE与无粉和聚丙烯酸酯自由基聚合CONNECTION

    公开(公告)号:WO2015165753A1

    公开(公告)日:2015-11-05

    申请号:PCT/EP2015/058363

    申请日:2015-04-17

    Applicant: BASF SE

    Abstract: Beschrieben wird eine nicht-wässrige Antidröhnmasse, enthaltend (a) ein nicht-pulverförmiges Polyacrylatbindemittel mit einem K-Wert im Bereich von 10 bis 35, gemessen als 1%ige Lösung in Tetrahydrofuran; (b) anorganische Füllstoffe; und eine radikalisch polymerisierbare Verbindung, welche mindestens eine radikalisch polymerisierbare C-C-Doppelbindung aufweist und einen Siedepunkt bei Normaldruck von größer 160°C besitzt. Beschrieben wird auch ein Verfahren zur Dämpfung von Vibrationen oder Schwingungen von Bauteilen von Fahrzeugen und Maschinen unter Verwendung der erfindungsgemäßen Antidröhnmasse.

    Abstract translation: 描述了一种非水性Antidröhnmasse含有(a)具有在10至35范围内,如在四氢呋喃中的1%溶液测定的K值的非粉状聚丙烯酸酯; (B)无机填料; 并且其具有至少一个可自由基聚合的C-C双键,并且具有大于160℃的大气压下的沸点的自由基聚合性化合物 还描述了一种用于车辆的阻尼,并使用Antidröhnmasse发明机器零件的振动或振荡的方法。

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