METHOD FOR PRODUCING CROSS-LINKABLE MATERIALS BASED ON ORGANYLOXYSILANE-TERMINATED POLYMERS

    公开(公告)号:US20240010840A1

    公开(公告)日:2024-01-11

    申请号:US18038449

    申请日:2020-12-15

    CPC classification number: C08L101/10 C09J201/10 C09K3/10

    Abstract: A method for producing crosslinkable compositions (M) by mixing (A) 100 parts by weight of compounds of the formula Y—[(CR12)b—SiRa(OR2)3-a]x (I) and (B) 0.1 to 75 parts by weight of at least one thixotropic agent. The at least one thixotropic agent is selected from fatty acid amides, polyamide waxes, polyamide wax derivatives, hydrogenated castor oil, hydrogenated castor oil derivatives, polyester amides, polyureas, oxidized polyethylenes and metal soaps and optionally further components. The period of time from the start of the mixing step of (A) and (B) to the end of storage of the crosslinkable composition (M) is at least 7 days and during this period all process steps are carried out at temperatures below 59° C.

    LACTIDE POLYMERISATION
    119.
    发明申请
    LACTIDE POLYMERISATION 审中-公开
    乳胶聚合

    公开(公告)号:US20170022320A1

    公开(公告)日:2017-01-26

    申请号:US15302581

    申请日:2015-04-08

    Abstract: The present invention relates to a compound having the formula LaM(OR1)bR2cXd wherein M is a metal selected from Ti, Zr and Hf; L is a ligand selected from permethylpentalene, (hydro)permethyl-pentalene, (hydro)pentalene, cyclopentadiene, indene and ethylene- or silane-bridged indene, preferably (bis)indene; R1 is a 1-6C alkyl, substituted or unsubstituted phenyl, or a substituted or unsubstituted phenylalkylene group; R2 is Me or Et; X is halogen; a=1 to 3, b=1 to 3, c=0 or 1 and d=0, 1, 2 or 3; and dimers thereof, the use of the compound as an initiator in the polymerisation of lactide monomer and a process for producing a polylactide performed by contacting a lactide monomer with the compound.

    Abstract translation: 本发明涉及具有式LaM(OR1)bR2cXd的化合物,其中M是选自Ti,Zr和Hf的金属; L是选自permethylpentalene,(hydro)permethyl-pentalene,(hydro)皮卡内烯,环戊二烯,茚和乙烯或硅烷桥连的茚,优选(双)茚的配体; R1是1-6C烷基,取代或未取代的苯基或取代或未取代的苯基亚烷基; R2是Me或Et; X是卤素; a = 1至3,b = 1至3,c = 0或1,d = 0,1,2或3; 其二聚物,在丙交酯单体的聚合中使用化合物作为引发剂,以及通过使丙交酯单体与化合物接触而制备聚丙交酯的方法。

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