Abstract:
A multiple chamber sample holding cartridge is used with a supercritical fluid extractor that causes membranes dividing the cartridge into chambers to rupture upon the pressurization of the sample cartridge, thereby allowing the intermixing of materials contained in the chambers. The neutral oil and loss determination of soybean and other oilseed oils by supercritical fluid extraction is efficient with this two-chambered sample cartridge.
Abstract:
In order to enhance the seizure resistance of a swash plate, which is the sliding part of a swash-plate type compressor, copper alloy is flame-sprayed on the swash plate. Depending upon the necessity, the following control of structure/composition: (a) a mixed structure is provided such that atomized bronze powder, which is melted during flame spraying, and an unmelted atomized structure are mixed; (b) Pb is not contained or contained slightly in the melted structure: (c) Sn, P, Al, Ag, Si, Mn, Cr, Ni, Zn, Pb and/or Bi is added to the copper; (d) hard matters are added to copper alloy; and, (e) an intermediate layer of Ni or the like is formed between the flame-sprayed layer and the substrate, is carried out.
Abstract:
A variable-orifice fluid restrictor for use with a supercritical extractor or chromatograph includes an inlet line for fluid at a pressure above its critical pressure, an extended tubular probe having an inner and an outer surface and a proximal and a distal end. The proximal end of the probe is disposed toward the inlet line. The distal end of the probe includes an adjustable orifice means adapted for metering the fluid and having first and second orifice members and an adjusting stem having first and second ends. The adjustable orifice means is adjacent to the outer surface of the probe and the orifice means is adjustable with the adjusting stem. The end of the adjusting stem is located at the distal end of the probe and is adapted for moving the first orifice member with respect to the second orifice member to control the adjustable orifice for varying the restriction of fluid passing through the adjustable orifice.
Abstract:
A swash plate type compressor having a cylinder block with cylinder bores disposed parallel to the axis of the cylinder block. A rotary shaft rotatably mounted within the cylinder block carries an aluminum swash plate. The swash plate is fixed to the rotary shaft and has two facial surfaces and an end surface. The facial surfaces have a coating of between 0.0005 inches to 0.002 inches of a heat curable, cross-linked polyfluoro elastomer bonded directly to the aluminum, a lubricious additive and a load bearing additive. A piston reciprocally fitted within the cylinder bore contains shoes which slideably intervene between the piston and the swash plate facial surfaces and reciprocate the pistons by rotation of the swash plate. The coating on the swash plate permits the use of slow silicon alloy aluminum without the need of metal plating or high finish polishing.
Abstract:
To collect analyte in a supercritical fluid extraction process, the extractant flows to a collection container under pressure. In one embodiment, the collection container contains collection solvent through which the extractant flows to partition analyte. The extractant adds to the liquid and when the collection solvent-extractant mixture rises to a heating zone, the extractant vaporizes selecively since its vapor pressure is higher than the vapor pressure of the collection solvent. When its pressure exceeds a preset valve pressure it is vented so that extractant continually leaves the collection container. After the extraction is complete, the analyte is concentrated in the collection solvent. In another embodiment, the collection vessel includes a solid material on which the analyte collects. It is removed under pressure by a solvent that is concentrated under pressure.
Abstract:
A sealed-type compressor used with HFC refrigerant. The sealed-type compressor houses a motor and compression machinery in a sealed case. The compression machinery includes at least a pair of sliding members wherein one sliding member having aluminum as its main body and having its surface alumite treated and the other sliding member having a metal material. The compressor includes an at least quadrivalent ester oil for the refrigerating machine oil which lubricates the sliding members.
Abstract:
An apparatus for supercritical fluid extraction incorporates a removable extraction cartridge which in operation has insignificant pressure difference between its inside and outside walls. In one embodiment, the extractor includes a fraction collector for extractants, an automatic sample changer and an automatic cartridge transfer mechanism which provide completely automated extractions. To automatically perform extraction, valves for the fluids are automatically opened and closed in synchronism with the insertion and removal of the cartridges. These valves force a hard valve element into a softer valve seat with a valve stem that does not rotate significantly under the control of a rotary motor.
Abstract:
To avoid deposits on the restrictor that channels extractant into a collector, a heated capillary tube pressure release restrictor, has a thermally insulated outlet end in a collecting trap substantially colder than the capillary tube. The restrictor is heated between the insulation and the capillary tube by Joulean heating. The solvent in the trap is at a pressure of 5 to 200 psi above atmospheric pressure. The thermal resistance of the insulation is selected to reduce the heat added to the extractant to a minimum and yet cause the temperature of the extractant to be in a range within which it is sufficiently hot so it does not freeze when added to the collection solvent but not so hot as to reduce partitioning of the extract and extractant before the extractant leaves the collection solvent. It has a thermal conductivity no greater than 60 BTU's per hour, per square foot, per inch for a one degree Fahrenheit difference.
Abstract:
An apparatus for supercritical fluid extraction incorporates a removable extraction cartridge which in operation has insignificant pressure difference between its inside and outside walls. Because of the low pressure difference, the extraction cartridge need not have the strength to withstand significant pressure and can be made out of molded plastic for disposable use as well as stainless steel and/or machined plastic for reusability. The extraction cartridge can be removed and opened for sample access without the use of tools. The outside of the cartridge can be purged after it is installed in a heated high pressure vessel to remove contamination from its exterior. In one embodiment, the extractor includes a fraction collector fr extractants, an automatic sample changer and an automatic cartridge transfer mechanism which provide completely automated extractions.
Abstract:
Disclosed is a sliding shoe for a rotatable swash-plate type refrigerant gas compressor. This shoe is slidably connected between a rotatable swash-plate and a ball rotatably engaged with a piston. One of the major surfaces of the shoe slidably contacts a sliding surface of the swash-plate. A sliding surface of the shoe facing the swash-plate is formed with a flat plane at its center portion and chamfered surface at the remaining portion of the sliding surface. At least the sliding plane of the shoe is coated with a lead alloy. According to the present invention, even if the swash-plate type compressor has no lubrication, abrasion and seizing of the shoe can be reduced to a great extent.