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    PROCATALYSTS AND PROCESS FOR PREPARING SAME
    121.
    发明申请
    PROCATALYSTS AND PROCESS FOR PREPARING SAME 审中-公开
    处理方法和制备方法

    公开(公告)号：WO1998028314A1

    公开(公告)日：1998-07-02

    申请号：PCT/US1997023805

    申请日：1997-12-19

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  HAZIN, Paulette, Nasri

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/03

    Abstract: A metallocene procatalyst useful in a catalyst system for the polymerization of olefins, particularly to make stereospecific polymers, and more particularly polymerization to make isotactic polypropylene is obtained from a process in which the product of a reaction between a suitable ligand and an alkali-alkyl is reacted with a transition metal salt in the presence of an accelerant that has at least one lone pair of electrons in its outer valence shell. When the metallocene procatalyst produced is used in a catalyst system for the production of isotactic polymers, specifically isotactic polypropylene, the metallocene procatalyst can be used without isolating and separating the racemic modification from the meso form.

    Abstract translation: 用于烯烃聚合，特别是制备立体有择聚合物的催化剂体系的茂金属前催化剂，更具体地说，制备全同立构聚丙烯的聚合是从合适的配位体和碱金属烷基反应的产物为 在存在促进剂的情况下与过渡金属盐反应，该促进剂在其外价壳中具有至少一对单电子。 当所生产的茂金属前催化剂用于生产全同立构聚合物，特别是全同立构聚丙烯的催化剂体系中时，可以使用茂金属前催化剂，而无需从外消旋体形式分离和分离外消旋体。

    PROCESS FOR REDUCING POLYMER BUILD-UP IN RECYCLE LINES AND HEAT EXCHANGERS DURING POLYMERIZATIONS ENPLOYING BUTADIENE, ISOPRENE, AND/OR STYRENE
    122.
    发明申请
    PROCESS FOR REDUCING POLYMER BUILD-UP IN RECYCLE LINES AND HEAT EXCHANGERS DURING POLYMERIZATIONS ENPLOYING BUTADIENE, ISOPRENE, AND/OR STYRENE 审中-公开
    使用丁二烯，异丙苯和/或苯乙烯的聚合反应期间在回收线和热交换器中降低聚合物的方法

    公开(公告)号：WO1998020046A1

    公开(公告)日：1998-05-14

    申请号：PCT/US1997019077

    申请日：1997-10-21

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  APECETCHE, Maria, Angelica ,  BAI, Xinlai ,  CANN, Kevin, Joseph

    IPC: C08F02/00

    CPC classification number: C08F2/007

    Abstract: A method for inhibiting polymer build-up in a recycle line and a heat exchanger during a polymerization process of one or more alpha olefins, particularly sticky polymers, or of one or more diolefins such as butadiene, isoprene, styrene, or styrene and butadiene, which method comprises introducing as an antifouling agent an alcohol having 1 to 20 carbon atoms, an alkyl or cycloalkyl ether having 2 to 20 carbon atoms, ammonia, an ester of an inorganic acid, a compound of a group IV element of the periodic table, alkyl and aryl amines, a sulfur-containing compound, or a mixture thereof at one or more locations in the recycle gas line in an amount sufficient to inhibit polymer build-up.

    Abstract translation: 在一种或多种α-烯烃，特别是粘性聚合物或一种或多种二烯烃如丁二烯，异戊二烯，苯乙烯或苯乙烯和丁二烯的聚合过程中，抑制在循环管线和热交换器中聚合物积聚的方法， 该方法包括作为防污剂引入具有1至20个碳原子的醇，具有2至20个碳原子的烷基或环烷基醚，氨，无机酸的酯，周期表的IV族元素的化合物， 烷基和芳基胺，含硫化合物或它们在循环气体管线中的一个或多个位置上的混合物，其量足以抑制聚合物积聚。

    FUNCTIONALIZATION OF HYDROCARBYL-CONTAINING COMPOUNDS
    123.
    发明申请
    FUNCTIONALIZATION OF HYDROCARBYL-CONTAINING COMPOUNDS 审中-公开
    含有含烃化合物的功能化

    公开(公告)号：WO1998019983A1

    公开(公告)日：1998-05-14

    申请号：PCT/US1997011757

    申请日：1997-07-03

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  COOK, Gerald, Kenneth ,  BRIGG, John, Robert ,  MINAHAN, David, Micheael, Anthony

    IPC: C07C29/48

    CPC classification number: C07C29/48 ,  A01D34/63 ,  A01D2101/00 ,  C07C45/512 ,  C07C45/52 ,  C07C45/54 ,  C07D203/02 ,  C07D301/02 ,  C07C31/202

    Abstract: This invention is directed to processes for producing acyclic or cyclic alcohols or glycols, carbonyls, oxiranes or aziridines from hydrocarbyl group-containing compounds, particularly lower alkanes such as methane, ethane, propane or butanes, in which the hydrocarbyl group-containing compounds are converted under regioselective conditions to a functionalized ultimate precursor from which the final products can be produced. In its broadest sense, regioselective conditions are reaction zone conditions which are highly selective to the production and recovery of the desired functionalized compound, be it the ultimate precursor or an intermediate to the production of the ultimate precursor.

    Abstract translation: 本发明涉及从含烃基化合物，特别是低级烷烃如甲烷，乙烷，丙烷或丁烷生产无环或环状醇或二醇，羰基，环氧乙烷或氮丙啶的方法，其中含烃基化合物被转化 在区域选择性条件下可以产生最终产物的官能化的最终前体。 在最广泛的意义上，区域选择性条件是对所需官能化化合物的生产和回收具有高度选择性的反应区条件，无论是最终前体还是制备最终前体的中间体。

    PROCESSES FOR PRODUCING 1,6-HEXANEDIOLS
    126.
    发明申请
    PROCESSES FOR PRODUCING 1,6-HEXANEDIOLS 审中-公开
    生产1,6-庚二醇的方法

    公开(公告)号：WO1997039998A1

    公开(公告)日：1997-10-30

    申请号：PCT/US1997006880

    申请日：1997-04-23

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  GURAM, Anil, Sakharam ,  BRIGGS, John, Robert ,  PACKETT, Diane, Lee ,  OLSON, Kurt, Damar ,  EISENSCHMID, Thomas, Carl ,  TJADEN, Erick, Bruce

    IPC: C07C29/16

    CPC classification number: C07C47/12 ,  C07B2200/09 ,  C07C29/141 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C47/21 ,  Y02P20/582 ,  C07C31/20 ,  C07C33/03 ,  C07C33/025 ,  C07C47/02

    Abstract: This invention relates to processes for producing one or more substituted or unsubstituted 1,6-hexanediols, e.g., 1,6-hexanediol, which comprise subjecting one or more substituted or unsubstituted alkadienes to hydrocarbonylation in the presence of a hydrocarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted 1,6-hexanediols. The substituted and unsubstituted 1,6-hexanediols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted of unsubstituted 1,6-hexanediols as principal product(s) of reaction.

    Abstract translation: 本发明涉及用于生产一种或多种取代或未取代的1,6-己二醇（例如1,6-己二醇）的方法，其包括在烃基催化剂存在下使一种或多种取代或未取代的链烯二醇进行烃基化， 金属有机磷配体络合物催化剂，以及助催化剂和任选的游离配体，以产生所述一种或多种取代或未取代的1,6-己二醇。 通过本发明的方法制备的取代和未取代的1,6-己二醇可以进一步反应以提供其所需的衍生物，例如ε己内酯。 本发明还部分涉及含有一个或多个取代未取代的1,6-己二醇作为主要反应产物的反应混合物。

    PROCESSES FOR PRODUCING UNSATURATED ALCOHOLS
    127.
    发明申请
    PROCESSES FOR PRODUCING UNSATURATED ALCOHOLS 审中-公开
    生产不饱和醇的方法

    公开(公告)号：WO1997039995A1

    公开(公告)日：1997-10-30

    申请号：PCT/US1997004314

    申请日：1997-04-23

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  GURAM, Anil, Sakharam ,  BRIGGS, John, Robert ,  OLSON, Kurt, Damar ,  EISENSCHMID, Thomas, Carl ,  PACKETT, Diane, Lee ,  TJADEN, Erik, Bruce

    IPC: C07C29/16

    CPC classification number: C07C47/21 ,  C07B2200/09 ,  C07C29/16 ,  C07C45/49 ,  C07C47/12 ,  Y02P20/582 ,  C07C33/025

    Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted unsaturated alcohols which comprise reacting one or more substituted or unsubtituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted unsaturated alcohols. The substituted and unsubstituted unsaturated alcohols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted unsaturated alcohols as principal product(s) of reaction.

    Abstract translation: 本发明部分地涉及制备一种或多种取代或未取代的不饱和醇的方法，其包括在金属 - 配体配合物催化剂和助催化剂和任选的游离配位体的存在下使一种或多种取代或未取代的烷撑二醇与一氧化碳和氢反应 产生所述一种或多种取代或未取代的不饱和醇。 通过本发明方法制备的取代和未取代的不饱和醇可进一步反应以提供所需的衍生物。 本发明还部分涉及含有一种或多种取代或未取代的不饱和醇作为主要反应产物的反应混合物。

    OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS
    128.
    发明申请
    OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS 审中-公开
    氧化物向羧酸氧化

    公开(公告)号：WO1997014668A1

    公开(公告)日：1997-04-24

    申请号：PCT/US1996016682

    申请日：1996-10-18

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  BARNER, Bruce, Armin ,  KURLAND, Jonathan, Joshua ,  KINKADE, Nancy, Ellen

    IPC: C07C51/235

    CPC classification number: C07B33/00 ,  C07C51/235 ,  Y02P20/582

    Abstract: This invention relates to a process for preparing carboxylic acids by oxidising an aldehyde with molecular oxygen or a gas containing molecular oxygen in the presence of an amine and/or amine N-oxide promoter selected from the group consisting of a substituted or unsubstituted alkyl amine, alkyl amine N-oxide, aromatic amine, aromatic amine N-oxide, heterocyclic amine, heterocyclic amine N-oxide and mixtures thereof, to produce the carboxylic acid. Such carboxylic acids have utility for example as chemical intermediates.

    Abstract translation: 本发明涉及一种在胺和/或胺N-氧化物助催化剂存在下用分子氧或含有分子氧的气体氧化制备羧酸的方法，所述胺和/或胺N-氧化物促进剂选自取代或未取代的烷基胺， 烷基胺N-氧化物，芳族胺，芳香胺N-氧化物，杂环胺，杂环胺N-氧化物及其混合物，以产生羧酸。 这样的羧酸可用作例如化学中间体。

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