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公开(公告)号：KR101271398B1
公开(公告)日：2013-06-11
申请号：KR1020110043542
申请日：2011-05-09
Applicant: 한국에너지기술연구원
CPC classification number: C01B3/382 , B01J19/0093 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00844 , B01J2219/00873 , B01J2219/00889 , C01B3/384 , C01B2203/0233 , C01B2203/0811 , H01M8/04067 , H01M8/0612 , H01M8/0631 , Y02E60/324 , Y02E60/50
Abstract: 본 발명은 연료의 연소열을 탄화수소의 개질에 필요한 에너지원으로 활용할 수 있는 미세유로 가열기를 이용한 탄화수소 개질장치에 관한 것으로, 미세유로를 갖는 금속박판을 다층으로 적층하여, 중소형의 컴팩트한 수소 제조 장치에 적합하며, 특히, 개질부를 복층 구조를 가지도록 설계하여 개질기의 용량을 사용자가 원하는 수치까지 향상시킬 수 있다.
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公开(公告)号：KR101270154B1
公开(公告)日：2013-05-31
申请号：KR1020110015883
申请日：2011-02-23
Applicant: 한국에너지기술연구원
Abstract: 수소정제분리막모듈이개시되어있다. 이러한수소성제분리막모듈은상부플랜지와하부플랜지를포함한다. 상부플랜지와하부플랜지사이의내부공간에는수소분리막과수소분리막에접촉하여외부가스의유입및 수소가스의유출을방지하기위한실(seal) 및/또는상부플랜지와하부플랜지사이에외부가스의유입및 수소가스의유출을방지하기위한실(seal)이제공된다. 수소분리막과실의접촉면에는확산억제층이제공된다. 확산억제층은분리막과실이맞닿는분리막표면에세라믹단독으로또는세라믹과금속이동시에또는임의적순서로코팅되어있는부분을포함한다. 다르게는, 확산억제층은바람직하게는알루미늄박막(호일)의외표면을산화시킴으로써얻은표면산화된알루미늄박막(호일)층일수 있다. 다르게는, 확산억제층는실링부재에형성하되실링부제전체혹은분리막과맞닿는부분에국부적으로형성되는것을포함한다.
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公开(公告)号：KR1020130048028A
公开(公告)日：2013-05-09
申请号：KR1020110112924
申请日：2011-11-01
Applicant: 한국에너지기술연구원
CPC classification number: C01B3/32 , C01B3/50 , C01B2203/0211 , C01B2203/0822
Abstract: PURPOSE: A manufacturing method of synthetic gas for final test process by a compact separation process and a device thereof are provided to be applied in a small and medium GTL (gas to liquid) process, to be compacted and to enhance efficiencies. CONSTITUTION: A manufacturing method of synthetic gas for final test process comprises the following steps: (50) reforming raw gas into synthetic gas which contains carbon monoxide and hydrogen; (52) cooling the synthetic gas; (54) steam isolation step which removes moisture only from frozen synthetic gas; and (56) partially isolating and filtering hydrogen from the synthetic gas in which moisture is removed. The hydrogen isolated from the hydrogen isolation step is used as fuel for the reformation reaction in the reformation reaction step. [Reference numerals] (14) FT reaction(180°C); (50) Reforming process(800°C); (52) Cool(180°C); (54) Steam separation(180°C); (56) Hydrogen separation(180°C); (AA) Operational temperature; (BB) Reforming gas flow direction(Unit process sequence)
Abstract translation: 目的：通过紧凑型分离方法的最终试验方法的合成气的制造方法及其装置被提供以应用于小型和中型GTL（气体 - 液体）方法中，以进行压实并提高效率。 构成：用于最终试验方法的合成气的制造方法包括以下步骤：（50）将原料气体重整成含有一氧化碳和氢气的合成气体; （52）冷却合成气体; （54）蒸汽分离步骤，仅从冷冻合成气中除去水分; 和（56）从除去水分的合成气体中部分地分离和过滤氢气。 从氢分离步骤中分离的氢气用作重整反应步骤中的重整反应的燃料。 （参考号）（14）FT反应（180℃） （50）重整工艺（800℃）; （52）冷却（180℃）; （54）蒸汽分离（180℃）; （56）氢分离（180℃） （AA）工作温度; （BB）重整气流方向（单位工序）
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公开(公告)号：KR1020130047207A
公开(公告)日：2013-05-08
申请号：KR1020110112092
申请日：2011-10-31
Applicant: 한국에너지기술연구원
CPC classification number: B01D53/228 , B01D53/22 , B01D63/06 , B01D63/08 , B01D63/087 , B01D69/10 , B01D71/022 , B01D2313/143 , B01D2313/32 , C01B3/503
Abstract: PURPOSE: A hydrogen refining membrane module is provided to increase the hydrogen refining efficiency compared to the existing hydrogen refining membrane module, and to prevent deformation of the hydrogen membrane by supporting the hydrogen membrane through a mixing unit when the hydrogen membrane is made in a foil form. CONSTITUTION: A hydrogen refining membrane module(1) comprises a housing; a feeding port(62); an exhausting part; a hydrogen membrane(10); and a mixing unit. A hydrogen isolation space(70) is formed within the housing. The feeding port and the exhausting part are connected to the one side and the other side of the hydrogen isolation space, respectively. The hydrogen membrane is installed between the feeding port and the exhausting part in the hydrogen isolation space. At least one micro channel is formed within the mixing unit. The mixing unit is installed between an inlet unit and the hydrogen membrane.
Abstract translation: 目的：提供氢精制膜组件，以提高与现有氢气精炼膜组件相比的氢气精炼效率，并且当氢膜制成箔时，通过将混合单元支撑氢膜来防止氢膜的变形 形成。 构成：氢精制膜组件（1）包括壳体; 进料口（62）; 一个疲惫的部分; 氢膜（10）; 和混合单元。 在壳体内形成氢气隔离空间（70）。 进料口和排气部分别分别连接到氢气隔离空间的一侧和另一侧。 氢膜安装在氢气隔离空间的进料口和排气部分之间。 在混合单元内形成至少一个微通道。 混合单元安装在入口单元和氢膜之间。
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公开(公告)号：KR1020130042878A
公开(公告)日：2013-04-29
申请号：KR1020110107011
申请日：2011-10-19
Applicant: 한국에너지기술연구원
CPC classification number: Y02P20/52 , B01J23/892 , B01J21/04 , B01J21/06 , B01J23/10 , B01J35/02 , B01J37/02 , B01J2523/3712 , C01B3/40
Abstract: PURPOSE: A hydrocarbon reforming catalyst and a manufacturing method thereof are provided to actualize the reforming equipment of new concept which is not able to see in an existing commercial plant because the processing speed of a reaction material per catalyst unit volume is remarkably improved. CONSTITUTION: A hydrocarbon reforming catalyst includes a precious metal and a ceramic oxide in the outer surface of nickel powder. The precious metal is one or more selected among Pt, Pd, Ru, Rh, and Ag. The ceramic oxide is one or more selected among Al2O3, SiO2, TiO2, ZrO2, and CeO2. The size of nickel powder is 0.1-20 Mm. The manufacturing method of the hydrocarbon reforming catalyst includes a step for dipping a precious metal precursor and a ceramic oxide precursor on the outer surface of nickel powder in an excess solution impregnation or incipient wetness method. The manufacturing method of the hydrocarbon reforming catalyst includes a step for dipping the precious metal precursor after dipping, drying, and thermally treating the ceramic oxide precursor. The each dipping step is performed in the excess solution impregnation or incipient wetness method. [Reference numerals] (AA) Equilibrium conversion rate; (BB) Ni(comparative embodiment 2); (CC) Al2O3/Ni(comparative embodiment 1); (DD) Pd-AlO3/Ni(embodiment 1);
Abstract translation: 目的：提供烃重整催化剂及其制造方法，以实现由于每个催化剂单元体积的反应材料的处理速度显着提高而在现有的商业装置中不能看到的新概念的重整设备。 构成：烃重整催化剂在镍粉外表面含有贵金属和陶瓷氧化物。 贵金属是选自Pt，Pd，Ru，Rh和Ag中的一种以上。 陶瓷氧化物是选自Al2O3，SiO2，TiO2，ZrO2和CeO2中的一种或多种。 镍粉的大小为0.1-20Mm。 烃重整催化剂的制造方法包括在过量溶液浸渍或初湿法中将贵金属前体和陶瓷氧化物前体浸渍在镍粉末的外表面上的步骤。 烃重整催化剂的制造方法包括在浸渍，干燥和热处理陶瓷氧化物前体之后浸渍贵金属前体的步骤。 每个浸渍步骤在过量溶液浸渍或初始润湿方法中进行。 （标号）（AA）平衡转化率; （BB）Ni（比较例2）。 （CC）Al 2 O 3 / Ni（比较例1）。 （DD）Pd-AlO 3 / Ni（实施例1）;
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Patent Agency Ranking
公开(公告)号：KR101246714B1
公开(公告)日：2013-03-25
申请号：KR1020110030357
申请日：2011-04-01
Applicant: 한국에너지기술연구원
Abstract: 본 발명은 마이크로 채널의 확산조립으로 인한 고압에의 취약성을 해소할 수 있는 투과형 고압 마이크로 채널 반응장치에 관한 것으로, 일측에 원료가스 공급관이 설치되는 봄베; 및 상기 봄베 내에 배치되며, 상기 원료가스 공급관으로부터 공급된 원료가스가 내부로 유통가능한 반응부를 포함하고, 상기 반응부는 상기 반응부와 상기 봄베 내부의 공간에 유통되고 상기 원료가스가 반응하여 발생되는 반응가스가 흐르는 반응가스유로와, 상기 봄베 외부로부터 유입되고 상기 봄베 외부로 배출되는 열전달가스가 흐르고 상기 반응가스유로에 대하여 격리되며 상기 반응가스유로와 접하여 열전달이 이루어지는 열전달가스유로를 가지며, 상기 반응가스유로에는 개질촉매가 배치되고, 원료가스가 상기 개질촉매의 수직한 방향으로 관통이동하며 접촉되는 것을 특징으로 한다.
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公开(公告)号：KR1020130011890A
公开(公告)日：2013-01-30
申请号：KR1020110133914
申请日：2011-12-13
Applicant: 한국에너지기술연구원
CPC classification number: B01D71/022 , B01D53/228 , B01D67/0088 , B01D2256/16 , B01D2325/06 , B01D2325/24 , B01D2325/28 , C01B3/503
Abstract: PURPOSE: A separation film protective layer and a manufacturing method thereof are provided to prevent deformation or destruction of a separation film by a particle which can be contained in gas during many processes using a hydrogen separation film, and to strengthen competitiveness with improved durability by a high priced separation film. CONSTITUTION: A cermet type separation protective layer(210) is formed by coating a dense hydrogen separation layer(204) with a metal and a ceramic which cannot move hydrogen molecules and atoms along the surface. The thickness of the separation protective layer is 50nm-3Mm, and the average diameter of the coated metal and ceramic is 5nm-2Mm. The porosity of the separation film protective layer is 5-50%. The ceramic composition includes an oxide, a non-oxide, and a nitride system, or the mixture thereof. The cermet has a column shape. An air gap is formed between the cermet. A part of the surface of the dense hydrogen separation layer is exposed.
Abstract translation: 目的：提供一种分离膜保护层及其制造方法，以防止在使用氢分离膜的许多工艺期间由气体中包含的颗粒形成或破坏分离膜，并且通过改善耐久性来提高竞争力 高价分离膜。 构成：金属陶瓷型分离保护层（210）通过用不能沿着表面移动氢分子和原子的金属和陶瓷涂覆致密氢分离层（204）而形成。 分离保护层的厚度为50nm-3Mm，涂覆的金属和陶瓷的平均直径为5nm-2Mm。 分离膜保护层的孔隙率为5-50％。 陶瓷组合物包括氧化物，非氧化物和氮化物体系，或其混合物。 金属陶瓷具有柱状。 在金属陶瓷之间形成气隙。 暴露浓氢分离层表面的一部分。
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公开(公告)号：KR1020120134867A
公开(公告)日：2012-12-12
申请号：KR1020110054066
申请日：2011-06-03
Applicant: 한국에너지기술연구원
CPC classification number: C10G45/62 , B01D61/00 , C10G49/007 , Y02C10/10 , Y02E50/13
Abstract: PURPOSE: A hydrocarbon upgrading method using a hydrogen separation membrane is provided to use the hydrotreating reaction using the hydrogen separation membrane with proton conductivity. CONSTITUTION: A hydrocarbon upgrading method using a hydrogen separation membrane comprises the following steps: supplying hydrogen gas to one side of the hydrogen separation membrane(12); supplying proton to the other side of the hydrogen separation membrane; and removing carbon double-bonds and oxygen from materials supplied from one side of the hydrogen separation membrane using a hydrotreating catalyst(14) coated on the membrane, by contacting the materials with the proton.
Abstract translation: 目的：提供使用氢分离膜的烃升级方法，使用氢分离膜进行加氢处理反应，具有质子传导性。 构成：使用氢分离膜的烃升级方法包括以下步骤：向氢分离膜（12）的一侧供给氢气; 向氢分离膜的另一侧供应质子; 并使用涂覆在膜上的加氢处理催化剂（14），通过使材料与质子接触，从氢分离膜的一侧供给的材料中除去碳双键和氧。
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公开(公告)号：KR1020120111703A
公开(公告)日：2012-10-10
申请号：KR1020110030358
申请日：2011-04-01
Applicant: 한국에너지기술연구원
CPC classification number: B01J19/0093 , B01J3/00 , B01J8/02
Abstract: PURPOSE: A high pressure micro channel reactor is provided to increase the reaction temperature region of reaction gas by suppressing the heat transmission of a pressurized gas path. CONSTITUTION: A high pressure micro channel reactor includes a bomb(102) and a reactor(114). A pressurized gas feeding pipe(104) is installed at one side of the bomb. The reactor is arranged in the bomb. The reactor includes a reaction gas flow path and a heat transmission flow path. The reaction gas flow path is separately arranged in the bomb. Reactive gas generated from the reaction of feed gas, which is fed through the bomb, flows through the reactive gas flow path. Heat transmission gas, which is fed through the bomb and is discharged to the external side of the bomb, flows through the heat transmission flow path.
Abstract translation: 目的：提供高压微通道反应器，通过抑制加压气体通道的传热来提高反应气体的反应温度范围。 构成：高压微通道反应器包括一个炸弹（102）和一个反应器（114）。 加压气体供给管（104）安装在炸弹的一侧。 反应堆安置在炸弹中。 反应器包括反应气体流路和热传递流路。 反应气体流动路径分别布置在炸弹中。 由通过炸药进料的进料气体的反应产生的反应气体流过反应性气体流动路径。 通过炸弹进料并被排放到炸弹的外侧的传热气体流过热传递流路。
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公开(公告)号：KR1020120111702A
公开(公告)日：2012-10-10
申请号：KR1020110030357
申请日：2011-04-01
Applicant: 한국에너지기술연구원
CPC classification number: B01J19/0093 , B01J3/00 , B01J8/02
Abstract: PURPOSE: A high pressure micro-channel reactor is provided to function as a hydrogen manufacturing system of high efficiency by inducing stable reactions under high pressures. CONSTITUTION: A high pressure micro-channel reactor includes a bomb(102) and a reactor(114). A feed gas supplying pipe(104) is installed at one side of the bomb. The reactor is arranged in the bomb. The feed gas supplying pipe feeds feed gas into the reactor. The reactor includes a reactive gas flow path and a heat transmission flow path. The reactive gas flows in the reactor and a space in the bomb. The reactive gas is generated by the reaction of the feed gas and flows through the reactive gas flow path. Heat transmission gas flows through the heat transmission flow path. The heat transmission flow path is separated from the reactive gas flow path and transmits heat when the heat transmission flow path is in contact with the reactive gas flow path.
Abstract translation: 目的：提供高压微通道反应器，通过在高压下进行稳定反应，起到高效制氢系统的作用。 构成：高压微通道反应器包括一个炸弹（102）和一个反应器（114）。 进料气体供给管（104）安装在炸弹的一侧。 反应堆安置在炸弹中。 进料气供给管将进料气体送入反应器。 反应器包括反应性气体流动路径和热传递流动路径。 反应性气体在反应器中流动并在炸弹中流动。 反应气体通过进料气体的反应产生并流过反应气体流动路径。 传热气体流过热传递流路。 传热流路与反应性气体流路分离，在传热流路与反应性气体流路接触时传递热量。
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