Abstract:
Golf ball incorporating polymer composition comprising: (i) a reaction mixture of ethylene-acid copolymer and C3-8 α, β-ethylenically unsaturated carboxylic acid(s); and (ii) poly-hydroxy crosslinking agent(s) such as polyvinyl alcohol, diols, glycols, sugar alcohols, and/or glycerols. Concentration of poly-hydroxy crosslinking agent(s) in polymer composition may be up to about 10% (or up to about 5%, or from 0.1% to about 2.5%, or from about 0.05% to 0.95%), by weight, based on 100% total weight of polymer composition. Reaction mixture may further comprise cation source and optionally organic acid(s) or salt thereof. Reaction mixture or polymer composition may include adjuvant(s). such as a silane compound, for example N-(2-aminoethyl-3 aminopropyl)trimethoxysilane and/or 3-glycidoxypropyl trimethoxysilane, in concentration of from 0.025% to 1.0% by weight, based on 100% total weight of reaction mixture or in concentration of up to 10% by weight, based on 100% total weight of the polymer composition.
Abstract:
A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.
Abstract:
Methods for making multi-piece golf balls comprising at least one component made of ethylene-propylene diene copolymer (EPDM) rubber and the resulting balls are provided. The multi-piece golf ball includes a cover, preferably a dual-cover having inner and outer cover layers. The outer cover is preferably made of a liquid rubber composition based on liquid EPDM rubber. In one version, the ball sub-assembly is dipped in a bath containing liquid EPDM rubber to form the outer cover. In another version, a casting method is used and the liquid EPDM rubber is dispensed into mold cavities to form the outer cover. The inner core of the ball may be made of polybutadiene rubber and the outer core layer may be made of EPDM rubber. The resulting golf ball has high resiliency, a soft feel, and good weatherability.
Abstract:
Multi-piece golf balls containing a core of at least one layer and cover of at least one layer are provided. At least one component is formed from a rubber composition comprising: i) about 10 to about 65 weight percent of a cycloalkene rubber having a trans-content of about 55% or greater and a melting point of 30° C. or greater; ii) about 30 to about 80 weight percent of an ionomeric resin; and 3) about 5 to about 40 weight percent of a polyamide. The rubber composition may further include other thermoplastic and thermosetting materials such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency, durability, scuff-resistance, and feel of the ball.
Abstract:
Multi-layered golf balls having at least one layer made of a polyester composition containing a polyester thermoplastic elastomer and plasticizer are provided. The plasticizers help reduce the glass transition temperature (Tg) of the composition and various plasticizers may be used. For example, the composition may include alkyl oleate plasticizers such as ethyl oleate and octyl oleate. Polyester-ether block copolymers are particularly preferred. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyester composition may be used to form any core, cover, or other layer in the golf ball.
Abstract:
Golf balls containing a core having at least two layers made from a polyalkenamer rubber composition are provided. At least one layer is made from a relatively low modulus polyalkenamer rubber composition and at least one layer is made from a relatively high modulus polyalkenamer rubber composition. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core.
Abstract:
Golf balls having cores with negative hardness gradients are provided. The cores are made of polyalkenamer rubber compositions that may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. In one version, a solid, single core having an outer surface and center is provided, wherein the outer surface has a hardness substantially the same or lower than the hardness of the center to define a zero or negative hardness gradient. Dual-cores having inner and outer cores can be made, wherein the inner core has a negative hardness gradient and the outer core has a positive or negative hardness gradient. The rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel.
Abstract:
Methods for making golf balls having a cover made from a polyurea composition are provided. The golf balls include a rubber core and intermediate layer made from an olefin-based ionomer composition. The methods for making the polyurea composition involve preparing an amine-terminated first polymer by reacting isocyanate compound A with a stoichiometric excess of polyamine. The first prepolymer is reacted with a stoichiometric excess of isocyanate compound B to form an isocyanate-terminated second prepolymer. The second prepolymer is then reacted with a chain extender.
Abstract:
The invention is directed to a method of making a neutralized non-ionomeric polymer composition (NNIPC) suitable for use in a golf ball component comprising the steps of: providing a non-acid copolymer composition (NACC); soaking the NACC in an organic acid to form a soaked non-acid copolymer composition (SNACC); providing a cation source in an amount sufficient to neutralize at least a portion of the organic acid; and melt processing the SNACC and cation source to form the NNIPC. The invention also relates to a method of making a golf ball incorporating the NNIPC made according to the inventive method and to the resulting golf ball.
Abstract:
Multi-piece golf balls having a core made of a polybutadiene rubber blend are provided. The golf ball contains a multi-layered core. The inner core is formed from a blend containing a non-metallocene catalyzed polybutadiene rubber and metallocene-catalyzed polybutadiene rubber. The surrounding outer core layer is made of a non-metallocene-catalyzed polybutadiene rubber. Catalysts such as neodymium, nickel, and cobalt based catalysts may be used to make the non-metallocene catalyzed rubber. Catalysts such as ferrocene, cobaltocene, nickelocene, titanocene dichloride, zirconocene dichloride, and samraocene based catalysts may be used to make the metallocene-catalyzed rubber. The multi-layered core is surrounded by a cover having at least one layer. The resulting ball has high resiliency and a soft compression feel.