公开(公告)号：DE3167129D1

公开(公告)日：1984-12-20

申请号：DE3167129

申请日：1981-01-30

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: C01G17/00 ,  B01J29/00 ,  B01J29/04 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J31/02 ,  C01B33/20 ,  C01B33/26 ,  C01B35/12 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/12 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  C01G49/00 ,  C07C1/00 ,  C07C1/20 ,  C07C2/00 ,  C07C67/00 ,  C07F5/06 ,  C01B33/28

Abstract: Crystalline isotactic zeolites having the composition 2/ pi RxW2O3xm YO2xp H2O where R is an organic amine and n is the number of amine groups in the amine molecule, W is one or more of the elements B, Al, Ga and Fe and Y is Si and/or Ge, and a process for the preparation of these crystalline isotactic metal silicate zeolites from mixtures of YO2 and W(OH)3 by hydrothermal crystallization at from 100 DEG to 200 DEG C. with the aid of an organic amine, in the absence of an alkali metal base, alkaline earth metal base or quaternary nitrogen base or their intermediates, the number m depending on the chain length of the organic amine used in the crystallization.

公开(公告)号：DE3305805A1

公开(公告)日：1984-08-23

申请号：DE3305805

申请日：1983-02-19

Applicant: BASF AG

Inventor： MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR ,  PLUECKHAN JUERGEN DR ,  DEHLER JUERGEN DR

IPC: B01J23/96 ,  C07D301/10

Abstract: The subject invention relates to a process for regenerating silver-containing carrier catalysts used in the preparation of ethylene oxide which comprises treating a deactivated catalyst with a solution comprising a potassium, rubidium, or cesium compound and a reducing agent. The subject process provides improved catalyst regeneration.

公开(公告)号：DE3304479A1

公开(公告)日：1984-08-23

申请号：DE3304479

申请日：1983-02-10

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/04 ,  B01J29/86 ,  C07C1/20 ,  C07C11/02 ,  C07C1/24 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

Abstract: C2-C4-olefins are prepared by catalytic conversion of methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures, by a process in which the catalyst used is a pure borosilicate zeolite which has been tableted or extruded without a binder and treated with hydrofluoric acid and hydrochloric acid. The treatment of the catalyst with hydrofluoric acid is carried out using 0.001-1N HF, and that with hydrochloric acid is carried out using 3-25% strength acid. The time-on-stream of the catalyst is improved.

公开(公告)号：DE3163381D1

公开(公告)日：1984-06-07

申请号：DE3163381

申请日：1981-07-09

Applicant: BASF AG

Inventor： KRABETZ RICHARD DR ,  MERGER FRANZ DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/18 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  C01B25/45 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00

Abstract: An oxidation catalyst wherein the catalytically active component has the general formula Mo12PaRhbCucVdCseXfYgZhOx, where X is Cr and/or Fe, Y is Nb, Z is Na, Li, K and/or Rb, a is 0.1-4, b is 0.001-1, c is 0.05-2, d is 0.05-4, e is 0.1-5, f is 0-2, g is 0-3 and h is 0-2, and x is the number of oxygen atoms required to saturate the valencies of the other constituents, is very suitable for the preparation of methacrylic acid by gas phase oxidation of methacrolein with an oxygen-containing and steam-containing gas mixture.

公开(公告)号：DE3239886A1

公开(公告)日：1984-05-03

申请号：DE3239886

申请日：1982-10-28

Applicant: BASF AG

Inventor： MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR ,  PLUECKHAN JUERGEN DR ,  DEHLER JUERGEN DR

IPC: B01J21/20 ,  B01J23/50 ,  B01J23/96 ,  B01J38/48 ,  C07B61/00 ,  C07D301/10 ,  C07D303/04

公开(公告)号：DE3064006D1

公开(公告)日：1983-08-11

申请号：DE3064006

申请日：1980-03-12

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: C01B33/18 ,  C01B37/02

Abstract: A crystalline SiO2-modification, which is characterized by an X-ray diffraction diagram having certain diffraction lines, and a process for the preparation of this crystalline SiO2-modification by crystallizing reactive amorphous SiO2under hydrothermal conditions in the presence of hexamethylenediamine. Sodium ions, phosphate ions and/or sulfate ions may be added for the crystallization.

公开(公告)号：DE3062679D1

公开(公告)日：1983-05-19

申请号：DE3062679

申请日：1980-03-12

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/06 ,  B01J29/40 ,  B01J29/86 ,  C01B39/40 ,  C07C1/20 ,  C01B33/28

公开(公告)号：DE2963156D1

公开(公告)日：1982-08-12

申请号：DE2963156

申请日：1979-07-13

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: C01B39/08 ,  C01B33/28

公开(公告)号：DE3060461D1

公开(公告)日：1982-07-15

申请号：DE3060461

申请日：1980-03-12

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/06 ,  B01J37/02 ,  C01B37/02 ,  C07C1/20 ,  C07C11/02

公开(公告)号：DE3060088D1

公开(公告)日：1982-01-28

申请号：DE3060088

申请日：1980-03-12

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/04 ,  B01J29/072 ,  C07C1/20 ,  C07C11/02