公开(公告)号：US07101621B2

公开(公告)日：2006-09-05

申请号：US10896664

申请日：2004-07-22

Applicant: Louis C. Haddad ,  James I. Hembre ,  Jerald K. Rasmussen ,  Daniel Sarpong

Inventor： Louis C. Haddad ,  James I. Hembre ,  Jerald K. Rasmussen ,  Daniel Sarpong

IPC: B32B27/00 ,  B32B27/02 ,  B32B27/08

CPC classification number: B82Y30/00 ,  B01J2219/00315 ,  B01J2219/00317 ,  B01J2219/00497 ,  B01J2219/00511 ,  B01J2219/00527 ,  B01J2219/00585 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00621 ,  B01J2219/00626 ,  B01J2219/00637 ,  B01J2219/00641 ,  B01J2219/00644 ,  B01J2219/00659 ,  B01J2219/00677 ,  B01J2219/00725 ,  C07B2200/11 ,  C08F8/32 ,  C08F8/42 ,  C08F220/54 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/50 ,  C08J3/075 ,  C08J3/244 ,  C08J3/246 ,  C08J7/047 ,  C08K5/17 ,  C08K5/544 ,  C09D133/26 ,  C09D139/04 ,  C09D157/10 ,  C09D201/06 ,  C12N11/08 ,  C40B40/10 ,  C40B60/14 ,  Y10T428/256 ,  Y10T428/29 ,  Y10T428/2907 ,  Y10T428/2913 ,  Y10T428/2924 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998 ,  Y10T428/31504 ,  Y10T428/31663 ,  Y10T428/31855 ,  Y10T428/31935 ,  C08L33/26 ,  C08L2666/36 ,  C08F220/56 ,  C08F226/06

Abstract: Surface coatings including azlactone-functional hydrogels and articles with the coatings disposed thereon are disclosed. Methods of making the coating and controlling the gellation time of the hydrogels are also disclosed.

公开(公告)号：US20040185267A1

公开(公告)日：2004-09-23

申请号：US10766940

申请日：2004-01-30

Applicant: ASAHI GLASS COMPANY LIMITED

Inventor： Hideyuki Takahashi ,  Bunji Uchino

IPC: B32B027/00

CPC classification number: C09D201/06 ,  C09D7/65 ,  C09D133/066 ,  C09D133/26 ,  C09D201/005 ,  Y10T428/31551

Abstract: The invention provides stain-proofing agents capable of forming coating films excellent in rain streak stain resistance and durability thereof, coating compositions comprising the stain-proofing agents, and articles coated therewith. A stain-proofing agent comprising a polymer which contains at least one repeating unit having at least two hydroxyl groups, wherein the content (by mass) of the repeating unit is more than 10%. A stain-proofing agent comprising a polymer which contains at least two repeating units having hydroxymethyl groups, wherein the content (by mass) of the repeating unit is more than 30%. A coating composition comprising such a stain-proofing agent and a coating resin such as a fluororesin.

Abstract translation: 本发明提供能够形成耐雨渍性和耐久性优异的涂膜的抗污染剂，包含防污剂的涂料组合物和涂覆的制品。 一种防污剂，其含有含有至少一个具有至少两个羟基的重复单元的聚合物，其中重复单元的含量（质量比）大于10％。 一种防污剂，其包含含有至少两个具有羟甲基的重复单元的聚合物，其中重复单元的含量（质量比）大于30％。 包含这种防污剂和涂料树脂如氟树脂的涂料组合物。

公开(公告)号：US20040044165A1

公开(公告)日：2004-03-04

申请号：US10642826

申请日：2003-08-19

Applicant: PPG Industries Ohio, Inc.

Inventor： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC: C08G077/04

CPC classification number: C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

Abstract: Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

Abstract translation: 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US06642311B2

公开(公告)日：2003-11-04

申请号：US10109948

申请日：2002-03-28

Applicant: Robert John Barsotti ,  Isidor Hazan ,  Bruce Lyle Neff

Inventor： Robert John Barsotti ,  Isidor Hazan ,  Bruce Lyle Neff

IPC: C08F12004

CPC classification number: C09D201/06 ,  C08G18/423 ,  C08G18/718 ,  C08G18/792 ,  C09D175/06 ,  Y10T428/31511 ,  Y10T428/31547 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31855

Abstract: A curable coating composition comprising functionalized oligomer components i and ii which cross-link at cure to form a three-dimensional network having chains of substantially uniform, controllable molecular weight between cross-links; oligomers i and ii having weight average molecular weights not exceeding about 3,000, a polydispersity for (i) not exceeding about 1.5, and functionalities that react with one another to cross-link i and ii at cure to yield coatings with an excellent balance of hardness and mar resistance.

公开(公告)号：US20030119980A1

公开(公告)日：2003-06-26

申请号：US10266593

申请日：2002-10-09

Inventor： Tetsuo Ogawa ,  Hisashi Isaka

IPC: B05D001/36 ,  B05D005/06 ,  B05D003/06 ,  C08K003/00

CPC classification number: C09D201/06 ,  B05D1/02 ,  B05D3/061 ,  B05D3/067 ,  B05D7/536 ,  B05D7/576 ,  C08G18/341 ,  C08G18/4291 ,  C08G18/6254 ,  C08G18/792 ,  C08G18/8077 ,  C09D175/06 ,  G03F7/032 ,  G03F7/038 ,  C08L2666/16

Abstract: This invention provides a high-solids coating composition which comprises (A) a compound which has at least one radically polymerizable unsaturated group per molecule, (B) a hydroxyl group-containing ester compound which is obtained by ester-forming addition reaction between 2,2-dimethylolalkanoic acid having 6 to 8 carbon atoms and alkanoic acid monoglycidylester, and which has an acid value of 20 mgKOH/g or less, (C) a curing agent which is reactive with the above-mentioned hydroxyl group-containing ester compound (B), and (D) a photopolymerization initiator, and also provides a process to form a coating film by spray coating of said coating composition, which process is characterized by irradiating flying paint particles which have been sprayed and/or paint which has been applied onto a substrate with active energy ray so as to make the coating composition partially react, and by subsequently heating the coating composition.

Abstract translation: 本发明提供了一种高固含量涂料组合物，其包含（A）每分子具有至少一个可自由基聚合的不饱和基团的化合物，（B）含羟基的酯化合物，其通过酯化形成加成反应获得， 具有6至8个碳原子的2-二羟甲基链烷酸和链烷酸单缩水甘油酯，其酸值为20mgKOH / g以下，（C）与上述含羟基酯化合物反应的固化剂（ B）和（D）光聚合引发剂，并且还提供通过所述涂料组合物的喷涂形成涂膜的方法，该方法的特征在于照射已经喷涂的飞溅涂料颗粒和/或涂布的涂料 到具有活性能量射线的基底上，以使涂料组合物部分反应，随后加热涂料组合物。

公开(公告)号：US06462124B2

公开(公告)日：2002-10-08

申请号：US09808996

申请日：2001-03-16

Applicant: Werner Wilfinger ,  Ingo Kriessmann ,  Friedrich Herrmann ,  Angelika Boehme

Inventor： Werner Wilfinger ,  Ingo Kriessmann ,  Friedrich Herrmann ,  Angelika Boehme

IPC: C08K320

CPC classification number: C09D133/06 ,  C08K5/42 ,  C09D201/06 ,  C08L33/06 ,  C08L2666/14 ,  C08L2666/28 ,  C08L2666/02

Abstract: A base-neutralized, water-diluted coating comprises (A) a polyhydroxyl-functional resin of an acrylate resin or an oil-free polyester containing urethane groups, (B) an amino resin partially etherified with an alcohol, (C) a basic neutralizing agent, (D) water, and (E) a water-insoluble crosslinking catalyst of a strong organic or inorganic acid such as p-toluenesulfonic acid blocked with a monoepoxide, diepoxide or lactone.

Abstract translation: 碱中和的水稀释涂层包含（A）丙烯酸酯树脂的多羟基官能树脂或含有氨基甲酸酯基团的无油聚酯，（B）与醇部分醚化的氨基树脂，（C）碱性中和 试剂，（D）水和（E）用单环氧化物，二环氧化物或内酯封端的强有机或无机酸如对甲苯磺酸的水不溶性交联催化剂。

公开(公告)号：US06245855B1

公开(公告)日：2001-06-12

申请号：US08968105

申请日：1997-11-12

Applicant: Shanti Swarup ,  Gregory J. McCollum ,  Debra L. Singer ,  Michael A. Mayo

Inventor： Shanti Swarup ,  Gregory J. McCollum ,  Debra L. Singer ,  Michael A. Mayo

IPC: C08L3700

CPC classification number: C09D167/00 ,  C08F8/30 ,  C08L61/20 ,  C08L61/32 ,  C09D133/062 ,  C09D201/06 ,  C08L2666/14 ,  C08L2666/16

Abstract: An aminoplast-curable film-forming composition is disclosed. The film-forming composition is a crosslinkable composition comprising (1) a material containing a plurality of carbamate and/or urea functional groups and (2) an aminoplast crosslinking agent. The composition provides a coating with improved acid etch resistance, making the coating particularly useful as an automotive clear coat.

Abstract translation: 公开了一种形成氨基塑料的成膜组合物。 成膜组合物是可交联组合物，其包含（1）含有多个氨基甲酸酯和/或脲官能团的材料和（2）氨基塑料交联剂。 该组合物提供具有改善的耐酸蚀性的涂层，使得该涂层作为汽车透明涂层特别有用。

公开(公告)号：US06204332B1

公开(公告)日：2001-03-20

申请号：US09080298

申请日：1998-05-18

Applicant: Werner Wilfinger ,  Ingo Kriessmann ,  Friedrich Herrmann ,  Angelika Boehme

Inventor： Werner Wilfinger ,  Ingo Kriessmann ,  Friedrich Herrmann ,  Angelika Boehme

IPC: C08K320

CPC classification number: C09D133/06 ,  C08K5/42 ,  C09D201/06 ,  C08L33/06 ,  C08L2666/14 ,  C08L2666/28 ,  C08L2666/02

Abstract: A water-dilutable coating after base neutralization comprises a polyhydroxyl-functional resin including a condensation resin such as a polyester or alkyd resin, and/or a polyhydroxyl-functional addition resin such as an acrylate resin or the reaction product of a carboxyl-functional acrylate resin and a hydroxyl-functional acrylate resin, and/or an emulsion copolymer, an at least partially monoalcohol-etherified amino resin, and a strong organic or inorganic acid crosslinking catalyst non-ionically blocked with a monoepoxide, a diepoxide or a lactone.

Abstract translation: 碱中和后的水可稀释涂层包括包含缩聚树脂如聚酯或醇酸树脂的多羟基官能树脂和/或多羟基官能加成树脂如丙烯酸酯树脂或羧基官能丙烯酸酯的反应产物 树脂和羟基官能的丙烯酸酯树脂，和/或乳液共聚物，至少部分一元醇醚化的氨基树脂和用单环氧化物，二环氧化物或内酯非离子封闭的强有机或无机酸交联催化剂。

公开(公告)号：US06160058A

公开(公告)日：2000-12-12

申请号：US184196

申请日：1998-11-02

Applicant: Walter H. Ohrbom ,  Gregory G. Menovcik ,  Donald L. St. Aubin ,  John E. Boisseau ,  John W. Rehfuss

Inventor： Walter H. Ohrbom ,  Gregory G. Menovcik ,  Donald L. St. Aubin ,  John E. Boisseau ,  John W. Rehfuss

IPC: C07D251/34 ,  C08F8/30 ,  C08G12/40 ,  C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G18/46 ,  C08G18/66 ,  C08G18/80 ,  C08G59/14 ,  C08G71/00 ,  C08G81/02 ,  C08K5/3492 ,  C08L61/20 ,  C09D133/00 ,  C09D133/06 ,  C09D161/20 ,  C09D167/00 ,  C09D167/04 ,  C09D169/00 ,  C09D175/00 ,  C09D175/02 ,  C09D175/04 ,  C09D201/02 ,  C09D201/06 ,  C08G8/28 ,  C08L63/00 ,  C08L67/04

CPC classification number: C09D201/025 ,  C07D251/34 ,  C08F8/30 ,  C08G12/40 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/2865 ,  C08G18/302 ,  C08G18/3829 ,  C08G18/3831 ,  C08G18/3853 ,  C08G18/4615 ,  C08G18/6633 ,  C08G18/8077 ,  C08G59/1438 ,  C08G59/1477 ,  C08G59/1494 ,  C08G71/00 ,  C08G81/021 ,  C08K5/34924 ,  C08L61/20 ,  C09D133/06 ,  C09D133/062 ,  C09D161/20 ,  C09D167/00 ,  C09D167/04 ,  C09D169/00 ,  C09D175/00 ,  C09D175/02 ,  C09D175/04 ,  C09D201/02 ,  C09D201/06 ,  C08L2666/16 ,  C08L2666/14 ,  C08L2666/28 ,  C08L2666/02

Abstract: The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes an acrylic polymer comprising active hydrogen-containing functional groups reactive with the third component(c). Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.

Abstract translation: 本发明提供了包含至少三种组分的可固化涂料组合物。 涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或 具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。 涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的丙烯酸聚合物。 涂料组合物的组分（c）是与前两种组分反应的固化剂。 还公开了使用本发明组合物制备涂层制品。

公开(公告)号：US6087464A

公开(公告)日：2000-07-11

申请号：US621171

申请日：1996-03-21

Applicant: Vijay Swarup ,  Frank N. Jones ,  Albert I. Yezrielev ,  Ramachandran P. Subrayan

Inventor： Vijay Swarup ,  Frank N. Jones ,  Albert I. Yezrielev ,  Ramachandran P. Subrayan

IPC: C08G18/32 ,  C08G18/65 ,  C08G18/66 ,  C08G18/72 ,  C08G18/80 ,  C09D161/32 ,  C09D175/04 ,  C09D201/06 ,  C08G18/42 ,  C08G18/58 ,  C08G18/62

CPC classification number: C09D175/04 ,  C08G18/3215 ,  C08G18/3221 ,  C08G18/6511 ,  C08G18/664 ,  C08G18/728 ,  C08G18/8067 ,  C09D201/06

Abstract: The present invention is directed to a polymeric vehicle, a formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a polyol, an isocyanate compound and a phenolic ester alcohol having at least one aliphatic hydroxyl group and at least one phenolic hydroxyl group.

Abstract translation: 本发明涉及聚合物载体，配制的涂料组合物和由聚合物载体制成的涂料粘合剂，以及制备聚合物载体的方法，其中聚合物载体包含多元醇，异氰酸酯化合物和酚酯醇，至少具有 一个脂族羟基和至少一个酚羟基。