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    PROCESS FOR PRODUCING FLUOROSULFONYL FLUORIDE COMPOUND
    131.
    发明授权
    PROCESS FOR PRODUCING FLUOROSULFONYL FLUORIDE COMPOUND 有权
    生产氟磺酰氟化合物的方法

    公开(公告)号：EP1346980B1

    公开(公告)日：2011-05-18

    申请号：EP01998181.0

    申请日：2001-11-28

    Applicant: ASAHI GLASS COMPANY LTD.

    Inventor： ITO, Masahiro c/o Asahi Glass Company, Limited ,  WATANABE, Kunio c/o Asahi Glass Company, Limited ,  OKAZOE, Takashi c/o Asahi Glass Company, Limited ,  KANEKO, Isamu c/o Asahi Glass Company, Limited ,  SHIRAKAWA, D. c/o Asahi Glass Company, Limited

    IPC: C07C303/22 ,  C07C309/82 ,  C07C51/58 ,  C07C59/135 ,  C07C51/60

    CPC classification number: C07C309/82 ,  C07C51/60 ,  C07C303/22 ,  C07C59/135

    Abstract: A process by which a fluorosulfonyl fluoride compound useful as, e.g., a material for ion-exchange membranes can be efficiently produced at low cost without structural limitations while eliminating difficulties in production. The process comprises reacting XSO2RA-E1 (1) with RB-E2 (2) to obtain XSO¿2?R?A-E-RB¿ (3), reacting the compound (3) with fluorine in a liquid phase to obtain FSO¿2?R?AF-EF-RBF¿ (4), and decomposing the compound (4) to obtain FSO¿2?R?AF-EF1¿ (5). In the formulae, RA represents a divalent organic group; E1 represents a monovalent reactive group; RB represents a monovalent organic group; E2 represents a monovalent group reactive with E1; E represents a divalent connecting group formed by the reaction of E?1 with E2; RAF¿ represents a divalent organic group formed by the fluorination of RA, etc.; RBF represents the same group as RB, etc.; EF represents a divalent connecting group formed by the fluorination of E, etc.; EF1 represents a monovalent group formed by the decomposition of EF; and X represents a halogen atom.

    Abstract translation: 可以以低成本有效地生产用作例如离子交换膜材料的氟磺酰氟化合物，而没有结构限制，同时消除生产困难。 该方法包括使XSO2RA-E1（1）与RB-E2（2）反应以获得XSO 2 R 2 AE-RB 3（3），使化合物（3）与氟在液相中反应以获得FSO 2 （4），分解化合物（4）得到FSO 2 R→AF-EF 1（5）。 在式中，RA代表二价有机基团; E1代表一价反应性基团; RB代表一价有机基团; E2代表与E1反应的单价基团; E代表E 1与E2反应形成的二价连接基团; RAF代表由RA的氟化等形成的二价有机基团; RBF代表与RB等同的组; EF表示由E的氟化等形成的二价连接基团; EF1表示EF分解形成的一价基团; X代表卤素原子。

    METHOD FOR PRODUCING FLUORINE-CONTAINING ALKYL ETHER
    133.
    发明授权
    METHOD FOR PRODUCING FLUORINE-CONTAINING ALKYL ETHER 有权
    生产含氟烷基醚的方法

    公开(公告)号：EP1655278B1

    公开(公告)日：2010-11-10

    申请号：EP04771338.3

    申请日：2004-08-06

    Applicant: ASAHI GLASS COMPANY LTD.

    Inventor： NAGAI, Masazumi Asahi Glass Company, Limited ,  OKAMOTO, Hidekazu Asahi Glass Company, Limited ,  OHARU, Kazuya Asahi Glass Company, Limited

    IPC: C07C41/06 ,  C07C43/12

    CPC classification number: C07C41/06 ,  C07C43/123

    Abstract: A method for producing a fluorine-containing alkyl ether is disclosed wherein a sufficient reaction rate can be attained even under mild conditions. This method enables to efficiently perform post-processes such as distillation following the reaction. After introducing a polar non-protic solvent, a fluorine-containing ether, a catalyst, a fluorine-containing alkyl alcohol and a fluorinated olefin into a reaction vessel, the fluorine-containing alkyl alcohol and the fluorinated olefin are reacted with each other so as to produce a fluorine-containing alkyl ether. In this method for producing a fluorine-containing alkyl ether, the mass ratio between the polar non-protic solvent and the fluorine-containing ether introduced in the reaction vessel (polar non-protic solvent/fluorine-containing ether) is from 5/95 to 80/20.

    Abstract translation: 公开了一种制备含氟烷基醚的方法，其中即使在温和条件下也可以获得足够的反应速率。 该方法能够有效地进行反应后的蒸馏等后处理。 向反应容器内导入极性非质子性溶剂，含氟醚，催化剂，含氟烷基醇和氟化烯烃后，使含氟烷基醇和氟化烯烃反应 生成含氟烷基醚。 在该含氟烷基醚的制造方法中，反应容器中导入的极性非质子性溶剂与含氟醚的质量比（极性非质子性溶剂/含氟醚）为5/95 到80/20。

    OPTICAL HEAD
    138.
    发明授权
    OPTICAL HEAD 有权
    光头

    公开(公告)号：EP1136993B1

    公开(公告)日：2009-12-16

    申请号：EP00956819.7

    申请日：2000-08-30

    Applicant: ASAHI GLASS COMPANY LTD.

    Inventor： NOMURA, Takuji, Asahi Glass Company, Limited ,  MURATA, Koichi, Asahi Glass Company, Limited

    IPC: G11B7/135 ,  G11B7/004 ,  G02B13/00 ,  G02F1/13

    CPC classification number: G02F1/134309 ,  G02F2203/18 ,  G11B7/0956 ,  G11B7/1369 ,  G11B7/13925

    Abstract: An optical head comprising a voltage-supply phase correction device for continuously varying the wave front profile of light emitted from a light source in a plane. An anisotropic optical medium is held between a pair of substrates each having a surface provided with an electrode for applying a voltage to the anisotropic optical medium. Two or more power supply parts are formed in different positions on at least one of the electrode, thus fabricating a phase correction device where a different voltage is supplied to each power supply part. The phase correction device is disposed between the collimating lens and the quarter-wave plate of the optical head. The optical head has a decreased number of control circuits for supplying a voltage to the phase correction device for varying the wave front profile continuously. Such a phase correction device having two or more power supply parts electrically connected through a thin film resistor made of a conductive thin film is fabricated and built in an optical head.

    OPTICAL ELEMENT USING LIQUID CRYSTAL HAVING OPTICAL ISOTROPY
    139.
    发明授权
    OPTICAL ELEMENT USING LIQUID CRYSTAL HAVING OPTICAL ISOTROPY 有权
    与液晶光学各向同性光学元件

    公开(公告)号：EP1688783B1

    公开(公告)日：2009-10-14

    申请号：EP04819455.9

    申请日：2004-11-26

    Applicant: ASAHI GLASS COMPANY LTD.

    Inventor： OOI, Yoshiharu, c/o Asahi Glass Company, Limited ,  NOMURA, Takuji ,  KOYANAGI, Atsushi

    IPC: G02F1/13 ,  G02F1/137

    CPC classification number: G02F1/134363 ,  G02F1/13306 ,  G02F1/13718 ,  G02F1/19 ,  G02F2001/13793 ,  G02F2001/294 ,  G02F2203/06 ,  G02F2203/18

    Abstract: An optical element able to realize a response equal to or faster than that of a conventional one without depending on an incident polarization. The optical element comprises transparent substrates (5, 6), a lattice (2A) formed on the transparent substrate (5) by using an isotropic-refractive-index solid material and having a sectional structure of a cyclic unevenness, blue-phase liquid crystals (2B) filled in the recesses of the lattice (2A) having cyclic unevenness and having refractive index thereof changed isotropically, and transparent electrodes (3, 4) for applying a voltage to the blue-phase liquid crystals (2B), wherein a diffraction element (10) is formed by diffraction lattices (1) each consisting of a lattice (2A) and a blue-phase liquid crystal (2B), and the refractive index of the blue-phase liquid crystals (2B) constituting the diffraction element (10) is changed by a voltage applied via the transparent electrodes (3, 4).

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