Abstract:
Disclosed are polyester-ether polyols and their use in urethane prepolymers, urethane foams and non-foam urethane coatings, adhesives, sealants and/or elastomers Methods for producing such polyester-ether polyols using double metal cyanide catalysts are disclosed, along with methods for producing urethane prepolymers The polyester-ether polyols of the instant invention are preferably the reaction product of phthalic anhydnde, diethylene glycol, and propylene oxide The polyester-ether polyols impart greatly improved solubility and compatibility to mixtures of either polyether and/or polyester polyols The polyester-ether polyols are desirably of lower viscosity than their precursor intermediate polyester polyols and are generally soluble in either polyester- and/or polyether-based polyols Additionally, the polyester-ether polyols generally provide improved hydrolytic stability to CASE materials in which they are utilized.
Abstract:
The present technology relates generally to the production of HMF-glycerin acetal, ethers, diethers, esters, and diesters derived therefrom, and aliphatic or aromatic polyester polymers derived therefrom. For example, HMF-glycerin acetal of the present technology can be formed as a product of the condensation reaction of glycerin with HMF. Compounds produced in accordance with the present technology may have many desirable attributes. For example, the incorporation of rigid furan and dioxolane five membered rings in the backbone of both polyurethanes and polyesters should result in polymers with high Tg and, hence, high service temperatures. Such polymers are also believed to be sensitive to bio- and photo-degradation.
Abstract:
Alkyl lactyllactate and alkoxylated alkyl lactyllactate compounds that are useful as solvents in a variety of applications are disclosed. The compounds are derived from a hydroxyl containing compound and a lactide or lactic acid source that has a specific chirality. The alkyl lactyllactate and alkoxylated alkyl lactyllactate compounds are particularly suitable for use as solvents in applications requiring cold tolerance performance without inclusion of additional volatile components.
Abstract:
The presently described technology relates to acyl lactylate containing compositions having improved stability and multifunctional performance characteristics (e.g., pH stability, phase stability, hydrolytic stability (e.g., aqueous stability), cleansing, foaming, skin softness and skin moisturization) that may be utilized in rinse-out and leave-on skin and hair applications. The acyl lactylate compositions of the present technology may be delivered to the skin or hair via a conventional delivery vehicle such as a body wash, a shampoo, a bubble bath, a skin cream, or a lotion.
Abstract:
A process for manufacturing polymers of glycerin and hydroxyl fatty acids, for example, polyglycerol polyricinoleates, which mix a polyglycerol with a hydroxyl fatty acid directly to form a reaction mixture, and then heat the reaction mixture to a temperature sufficient to cause it to polymerize through an esterification mechanism until the reaction mixture reaches a desired acid value.
Abstract:
A personal cleansing composition exhibiting enhanced skin feel (i.e., enhanced skin softness, reduced skin irritation, reduced residue, and reduced greasy, tacky, or tight skin feel), enhanced foaming and lather, and good cleansing, more specifically, a personal cleansing composition comprising a mixture of alpha sulfonated alkyl esters or sulfonated fatty acids, or salts thereof, with an alkyl sulfoacetate or ethoxylated alkyl sulfoacetate, or salts thereof, secondary surfactants, and optional additives.
Abstract:
A composition for cleaning hard surfaces, specifically, an acidic hard surface cleaner, includes a nonionic surfactant, a non-germicidal alkoxylated quaternary compound, an organic solvent, an acid, water, and optionally hydrogen peroxide, which provides excellent soap scum and/or greasy soil removal while exhibiting low filming and streaking.
Abstract:
A process for producing surfactant products by reacting, in a jacketed vacuum neutralizing reactor, the acid form of an anionic surfactant with a neutralizing agent, and supplementing heat to the reactor via a heat transfer medium on the jacket, which is not cooling water. The surfactant product made by such a process may exhibit a solids concentration of from about 50% by weight or greater . A vacuum reactor that has a heating jacket using a heat transfer medium, such as steam, that is not cooling water, and can function both as a neutralizing reactor and an evaporator, is also contemplated.
Abstract:
A process for enzymatic production of glyceride compositions, specifically industrially practicable production of triglycerides, including conjugated linoleic and linolenic acid triglycerides, and the compositions produced by such process. An enzymatic reaction zone is first utilized, in which a mixture of glycerol and fatty acids or fatty acid derivatives is reacted in the presence of an enzymatic catalyst to form 1,3 diglycerides. The mixture is then circulated through a second thermal rearrangement zone, maintained at a higher temperature, to promote rearrangement of the 1,3 diglycerides to 1,2 diglycerides. Triglycerides are produced by re-circulating the mixture through the enzymatic production zone.
Abstract:
A process to refine esters of conjugated linoleic acids via distillation in a single or multi-pass distillation operation is provided. Thermal rearrangement of conjugated linoleic acid components during distillation is prevented or reduced by the use of a low residence time and/or reduced pressure distillation apparatus. A process to produce refined esters of conjugated linoleic acids is also provided. The process transesterifies a linoleic acid-containing oil to generate an alkyl ester composition which further undergoes isomerization at a temperatures typically between about 90-140 °C to form an ester stream containing conjugated linoleic acid esters, which is then distilled to obtain the refined esters of conjugated linoleic acids. The transesterification and isomerization steps can be performed in one reaction vessel without an intervening distillation step. The transesterification and isomerization steps can occur concurrently in a continuous reaction system using a dual reaction zone apparatus. Refined ester compositions produced by the processes and enriched in desirable conjugated linoleic acid isomers are also contemplated.