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公开(公告)号：KR1020140008676A
公开(公告)日：2014-01-22
申请号：KR1020120075480
申请日：2012-07-11
Applicant: 한국에너지기술연구원
IPC: D06M14/36 , D06M11/36 , D06M10/02 , H01M8/20 , D06M101/40
CPC classification number: Y02E60/528 , D06M14/36 , D06M10/02 , D06M11/36 , D06M2101/40 , D10B2101/12 , H01M8/20
Abstract: The present invention relates to a method for reforming the surface of a carbon fiber, which can be used as the carbon electrode of a redox flow battery, a carbon fiber having the surface thereof reformed thereby, and a carbon electrode and a redox flow battery including the carbon fiber having the surface thereof reformed thereby. The method for reforming the surface of a carbon fiber according to the present invention comprises the steps of: supporting the carbon fiber on a solvent containing a hydroxyl group; treating, with supersonic waves, the carbon fiber supported on the solvent containing a hydroxyl group; and thermally treating the carbon fiber treated with supersonic waves. The carbon fiber having the surface thereof reformed according to the present invention can improve the electrochemical properties of the carbon fiber by maximizing the specific surface area of the carbon fiber because the surface of the carbon fiber is reformed to be hydrophilic and has mesopores formed thereon. Therefore the carbon fiber having the surface thereof reformed according to the present invention can be used as the carbon electrode of a redox flow battery.
Abstract translation: 本发明涉及可用作氧化还原液流电池的碳电极的碳纤维表面改性方法，其表面由其重整的碳纤维，以及碳电极和氧化还原液电池，其包括 由此表面改性碳纤维。 根据本发明的碳纤维表面重整方法包括以下步骤：将碳纤维支撑在含有羟基的溶剂上; 用超声波处理负载在含有羟基的溶剂上的碳纤维; 并对用超声波处理的碳纤维进行热处理。 具有根据本发明重整表面的碳纤维可以通过使碳纤维的比表面积最大化来改善碳纤维的电化学性能，因为碳纤维的表面被重新形成为亲水性并且在其上形成介孔。 因此，根据本发明的具有重整表面的碳纤维可以用作氧化还原液流电池的碳电极。
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公开(公告)号：KR1020130140945A
公开(公告)日：2013-12-26
申请号：KR1020120052044
申请日：2012-05-16
Applicant: 한국에너지기술연구원
IPC: H01G11/22 , H01M10/052
Abstract: The present invention relates to an energy storage device to provide a lithium-ion capacitor including a negative electrode and a positive electrode to which a lithium based metallic oxide is added through a formation method (battery activation method) using simplified processing steps and a manufacturing method for the same. [Reference numerals] (AA) Start;(BB) End;(S10) Prepare a lithium metal oxide;(S20) Produce an anode electrode and a cathode electrode;(S30) Produce a capacitor using the produced electrodes
Abstract translation: 本发明涉及一种提供一种锂离子电容器的能量存储装置，该能量储存装置包括使用简化的处理步骤的形成方法（电池活化方法），通过使用简单的处理步骤和制造方法来添加锂基金属氧化物的负极和正极 相同的 （AA）开始;（BB）结束;（S10）准备锂金属氧化物;（S20）制造阳极电极和阴极电极;（S30）使用所制作的电极制造电容器
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公开(公告)号：KR1020130118756A
公开(公告)日：2013-10-30
申请号：KR1020130000959
申请日：2013-01-04
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A method for preparing an anode active material is provided to easily prepare titanium oxide with a size of several nanometers in a nitrogen-doped porous carbon nanotube, and allow an appropriate control of the nitrogen content, the titanium oxide content, the pore size, the diameter of the carbon nanotube, and the size of titanium oxide. CONSTITUTION: A method for preparing an anode active material comprises the following steps. An electro-spinning solution is prepared by mixing a first solution in which a metal oxide precursor is dissolved, a second solution in which a polymer as a carbon nanotube precursor is dissolved, and an ionic liquid solution for nitrogen doping and forming of a porous structure (S10). The electro-spinning solution is electro-spun to prepare a composite material of metal oxide-nitrogen-porous carbon nanotube (S20). The composite material is thermally treated (S30). Further, an anode is formed by coating a current collector with a slurry in which the anode active material, a conducting agent, a binding agent, and a solvent are mixed. [Reference numerals] (AA) Start; (BB) End; (S10) Produce electro-spinning solution; (S20) Produce metal oxide-nitrogen-porous carbon nanofiber composite; (S30) Thermally treat composite
Abstract translation: 目的：提供一种制备负极活性材料的方法，以便在氮掺杂的多孔碳纳米管中容易地制备尺寸为几纳米的氧化钛，并且可以适当地控制氮含量，氧化钛含量，孔径 ，碳纳米管的直径和氧化钛的尺寸。 构成：制备负极活性物质的方法包括以下步骤。 通过混合其中溶解有金属氧化物前体的第一溶液，其中溶解作为碳纳米管前体的聚合物的第二溶液和用于氮掺杂的离子液体溶液和多孔结构的形成来制备电纺丝溶液 （S10）。 电纺丝溶液电纺制备金属氧化物 - 氮多孔碳纳米管的复合材料（S20）。 复合材料进行热处理（S30）。 此外，通过将负极活性物质，导电剂，结合剂和溶剂混合的浆料涂布在集电体上而形成阳极。 （附图标记）（AA）开始; （BB）结束; （S10）生产电纺丝溶液; （S20）生产金属氧化物 - 氮多孔碳纳米纤维复合材料; （S30）热处理复合材料
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公开(公告)号：KR101309262B1
公开(公告)日：2013-09-16
申请号：KR1020120099919
申请日：2012-09-10
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528 , H01M8/18 , H01M8/02 , H01M8/24
Abstract: PURPOSE: A redox flow battery is provided to exclude a bipolar plate frame by integrating a manifold and a bipolar plate and to reduce a work time for laminating stacks. CONSTITUTION: A redox flow battery includes a pair of end plates which has an electrolyte inlet and an electrolyte outlet; a current collector inside the end plate; an end manifold which is placed inside the current collector, has a bipolar plate (110) mounted on a side corresponding to the current collector and an electrode inserted onto the opposite side; and an integrated composite electrode cell which is placed between the end manifolds and includes a first manifold (121) in which a first electrode is inserted, a second manifold (122) in which a second electrode is inserted, and the bipolar plate placed between the first and second manifolds.
Abstract translation: 目的：提供氧化还原液流电池，以通过集成歧管和双极板排除双极板框架，并减少层叠叠层的工作时间。 构成：氧化还原液流电池包括一对端板，其具有电解液入口和电解液出口; 端板内的集电器; 放置在集电体内部的端部歧管具有安装在与集电体对应的一侧上的双极板（110）和插入到相对侧的电极; 以及集成复合电极单元，其位于所述端部歧管之间并且包括插入有第一电极的第一歧管（121），插入有第二电极的第二歧管（122），并且所述双极板位于所述第二歧管 第一和第二歧管。
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公开(公告)号：KR1020130054548A
公开(公告)日：2013-05-27
申请号：KR1020110119983
申请日：2011-11-17
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528 , H01M8/02 , H01M8/18
Abstract: PURPOSE: A redox flow battery is provided to improve output of a battery by a simple method without sudden increase of volume. CONSTITUTION: A redox flow battery has a structure formed by laminating two or more unit cells which includes manifold(40) with reaction parts(43,73,73') having different polarity from each other. The redox flow battery has a first end plate(10) which has different electrolyte inlets(11,11'); a second end plate(20) which has electrolyte outlets(21,21'); two or more current collectors(30,30') having different polarities; and a series and parallel connection element(80) formed on the front side of the second end plate.
Abstract translation: 目的：提供氧化还原液流电池，通过简单的方法提高电池的输出，而不会突然增加体积。 构成：氧化还原液流电池具有通过层叠两个或更多个单元电池而形成的结构，所述单元电池包括具有彼此极性不同的反应部分（43,43,73'）的歧管（40）。 氧化还原液流电池具有第一端板（10），其具有不同的电解液入口（11,11'）; 具有电解液出口（21,21'）的第二端板（20）; 具有不同极性的两个或多个集电器（30,30'）; 以及形成在所述第二端板的前侧的串联并联连接元件（80）。
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Patent Agency Ranking
公开(公告)号：KR101179629B1
公开(公告)日：2012-09-10
申请号：KR1020110067394
申请日：2011-07-07
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A method for manufacturing a lithium-ion capacitor according to a pre-doping process of lithium ions and the lithium-ion capacitor therefrom are provided to supply stable charge-discharge characteristics in greater than 4.0V by including an cathode electrode between an anode electrode and a lithium metal electrode. CONSTITUTION: A lithium-ion capacitor(100) includes a case(110), electrolyte(120) and an electrochemistry cell(130). The chemistry cell includes an anode electrode(131), a cathode electrode(135) and a lithium metal electrode(139). A lithium ion of the lithium metal electrode is carried to the cathode electrode. The cathode electrode and the anode electrode are electrochemically contacted. The absorbed lithium ion on the anode electrode is carried to the cathode electrode. The lithium metal electrode and the cathode electrode are electrochemically contacted.
Abstract translation: 目的：提供根据锂离子的预掺杂工艺和其中的锂离子电容器制造锂离子电容器的方法，以通过在阳极之间包括阴极来提供大于4.0V的稳定的充电 - 放电特性 电极和锂金属电极。 构成：锂离子电容器（100）包括壳体（110），电解质（120）和电化学电池（130）。 化学电池包括阳极电极（131），阴极电极（135）和锂金属电极（139）。 锂金属电极的锂离子被输送到阴极。 阴极电极和阳极电极电化学接触。 阳极电极上吸收的锂离子被传送到阴极电极。 锂金属电极和阴极电极电化学接触。
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公开(公告)号：KR101139427B1
公开(公告)日：2012-04-27
申请号：KR1020100092862
申请日：2010-09-24
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/13
Abstract: PURPOSE: An electrode material for a capacitor and the capacitor manufactured by using the same are provided to maximize charging and discharging by preventing the decrease of specific capacitance due to a current density rise and implementing high energy density. CONSTITUTION: Electrode materials are obtained by thermally processing lithium starting materials and manganese starting materials at 300 to 600 degrees centigrade for 1 to 40 hours. Lithium is an electrode with an initial discharge capacitance of 20 to 100 mAh/g. A unit cell of a capacitor has energy density of 1 to 80 Wh/Kg within 0 to 5 V.
Abstract translation: 目的：提供一种用于电容器的电极材料和使用该电极的电容器，以通过防止由于电流密度升高而降低比电容并实现高能量密度来使充电和放电最大化。 构成：通过在300〜600摄氏度下将锂原料和锰原料热处理1〜40小时得到电极材料。 锂是具有20至100mAh / g的初始放电电容的电极。 电容器的晶胞在0〜5V内具有1〜80Wh / Kg的能量密度。
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公开(公告)号：KR1020110072284A
公开(公告)日：2011-06-29
申请号：KR1020090129144
申请日：2009-12-22
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/528 , H01M4/8878 , H01M4/96 , H01M8/188
Abstract: PURPOSE: A method for manufacturing a carbon electrode through electrochemical activation is provided to rapidly activate a carbon electrode, to increase an oxygen functional group of the carbon electrode, to improve the capacity and efficiency of the redox flow battery, and to reduce the resistance of an electrode. CONSTITUTION: A method for manufacturing a carbon electrode(30) through electrochemical activation comprises the steps of: filling a mixed solution of distilled water and acid in a cell electrode part in which a unit cell or a stack is assembled; and electrochemically activating the electrode part. The mixed solution is a solution of 0.1~10 M molarity in which one or two or more from the group consisting of sulfuric acids, nitric acids, and phosphoric acids are mixed.
Abstract translation: 目的：提供通过电化学活化制造碳电极的方法，以快速激活碳电极，增加碳电极的氧官能团，提高氧化还原液电池的容量和效率，并降低电阻 电极。 构成：通过电化学活化制造碳电极（30）的方法包括以下步骤：将蒸馏水和酸的混合溶液填充到组装单元电池或电池组的电池电极部分中; 和电化学活化电极部分。 混合溶液为0.1〜10M摩尔浓度的溶液，其中混合由硫酸，硝酸和磷酸组成的组中的一种或两种以上。
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公开(公告)号：KR1020110052758A
公开(公告)日：2011-05-19
申请号：KR1020090109414
申请日：2009-11-13
Applicant: 한국에너지기술연구원
IPC: H01G11/46
Abstract: PURPOSE: Oxide electrode materials for an electrochemical capacitor are provided to implement high energy density and prevent the reduction of specific capacitance. CONSTITUTION: An electrode for a capacitor includes oxide made of Li2O1-zXz yMO2-zXz and LiaMbOc-2zX2z. The a, b, and c are integral numbers and satisfy 6
Abstract translation: 目的：提供用于电化学电容器的氧化物电极材料，以实现高能量密度并防止比电容的降低。 构成：用于电容器的电极包括由Li2O1-zXz yMO2-zXz和LiaMbOc-2zX2z制成的氧化物。 a，b和c是整数，满足6 <= a + b + c <33。 Y满足1 <= y <= 5。 M是Ti，Cr，Mn或Zr。 X是F，Cl，S，Br或I.Z满足0
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公开(公告)号：KR100931963B1
公开(公告)日：2009-12-15
申请号：KR1020070098290
申请日：2007-09-28
Applicant: 한국에너지기술연구원
CPC classification number: Y02E60/13
Abstract: An electrolyte additive for a super capacitor, a manufacturing method thereof, and an electrolyte solution including the same are provided to perform an overcharge protection effect by suppressing decomposition of an electrolyte. A 4-DAP(Dimethylamino Pyridine) as a compound having a polymer precursor, a compound including a reversible redox function, and a reaction activator is added to a solvent. A mixing solution is agitated in a room temperature. An N,N'-DCC(Dicyclohexylcarbodiimide) solution is slowly added to an agitated mixing solution. The mixing solution is agitated in a room temperature again. A re-agitated mixing solution is filtered. The solvent is evaporated in a rotation evaporator. A solid sample remaining after evaporation is re-crystallized.
Abstract translation: 提供用于超级电容器的电解质添加剂，其制造方法以及包含该电解质溶液的电解质溶液，以通过抑制电解质的分解来执行过充电保护效果。 作为具有聚合物前体的化合物的4-DAP（二甲基氨基吡啶），含有可逆氧化还原功能的化合物和反应活化剂被添加到溶剂中。 混合溶液在室温下搅拌。 将N，N'-DCC（二环己基碳化二亚胺）溶液缓慢加入到搅拌的混合溶液中。 混合溶液再次在室温下搅拌。 重新搅动的混合溶液被过滤。 溶剂在旋转蒸发器中蒸发。 蒸发后剩余的固体样品重新结晶。
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