Removal of phosphates from solns contg fluoride ions - - by addn of a water-soluble barium cpd

    公开(公告)号:DE2327596A1

    公开(公告)日:1974-12-19

    申请号:DE2327596

    申请日:1973-05-30

    Applicant: ALLIED CHEM

    Abstract: Cl process for removing phosphate ion from an aq. soln. contg. fluoride and phosphate ion comprises adding to the soln. at a pH >=8.5 a water-soluble Ba cpd. in an amt. at least stoichiometrically equiv. to the phosphate ion, and sepg. the resulting Ba phosphate ppte. The main use of the process is in the purificn. of solns. contg. inter alia, H2SiF6, obtained by the absorption of den. gases produced in the mfre. of phosphoric acid; pptd. silica may be ioncomitantly removed. Aq. ammonia is pref. used to achieve the required pH, desirably 9.0.

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