POLYPROPYLENE COMPOSITION
    134.
    发明公开
    POLYPROPYLENE COMPOSITION 有权
    聚丙烯组合物

    公开(公告)号:EP1680468A1

    公开(公告)日:2006-07-19

    申请号:EP04798761.5

    申请日:2004-11-03

    Abstract: A propylene polymer composition comprising the following components: a) from 50% to 90% by weight of a propylene homopolymer or a propylene copolymer containing up to 5% by mol of derived units of C2-C20 alpha-olefins, having the following features: (i) a polydispersity index PI>3; (ii) melt flow rate (MFR), as measured at 230°C under a load of 2.16 kg, MFR>1 dg/min; and (iii) fraction soluble in xylene at 25°C (XSRT)>1% b) from 5% to 25% by weight a copolymer of ethylene and one or more derived units of C4-C20 alpha-olefins having the following features: (i) content of ethylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 1.2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm3; and (iv) a crystallinity content, expressed as the enthalpy of fusion, lower than 62 J/g c) from 5% to 25% by weight of a copolymer of propylene and ethylene having the following features: (i) content of propylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm3; (iv) the value of the product of reactivity ratios rlxr2 lower than 2; and (v) a crystallinity content, expressed as the enthalpy of fusion, lower than 45 J/g wherein the weight ratio between the ethylene copolymer (component b) and the sum of component b) and component c) is equal to or higher than 0.5 and less than or equal to 0.9.

    Abstract translation: 一种丙烯聚合物组合物,其包含以下组分:a)按重量计50%至90%的丙烯均聚物或含至多5%摩尔衍生单元的C 2 -C 20α-烯烃的丙烯共聚物,其具有以下特征: (i)多分散指数PI> 3; (ii)在230℃和2.16kg的负荷下测量的MFR> 1dg / min的熔体流动速率(MFR); 和(iii)25℃下可溶于二甲苯的部分(XSRT)> 1%b)5%至25%重量的乙烯与一种或多种C4-C20α-烯烃衍生单元的共聚物,其具有以下特征: (i)乙烯衍生单元的含量高于50摩尔%且低于92摩尔%; (ii)特性粘度(IV)高于1.2dL / g且低于6dL / g; (iii)密度为0.850-0.890g / cm 3; 和(iv)以5重量%至25重量%的丙烯与乙烯的共聚物表示的具有以下特征的结晶度含量,以熔融焓表示,低于62J / gc):(i)丙烯衍生单元 高于50摩尔%且低于92摩尔%; (ii)特性粘度(IV)高于2dL / g且低于6dL / g; (iii)密度为0.850-0.890g / cm 3; (iv)反应性比率rlxr2的乘积的值低于2; 和(v)以熔融焓表示的结晶度含量低于45J / g,其中乙烯共聚物(组分b)与组分b)和组分c)之和的重量比等于或高于 0.5且小于或等于0.9。

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