Abstract:
A method is proposed for providing an oxygen-containing gas stream for the endothermic reaction of an initial stream comprising one or more hydrocarbons, having a predetermined oxygen concentration and a predetermined temperature, wherein a fluid fuel stream is combusted with a primary air stream at λ values of the primary air stream to the fluid fuel stream of from 0.6 to 1.2 to obtain a combustion gas stream, and a secondary air stream is admixed to the combustion gas stream to obtain the oxygen-containing gas stream for the endothermic reaction, with the predetermined oxygen concentration and the predetermined temperature of the oxygen-containing gas stream being adjusted via the flow rate and the temperature of the secondary air stream.
Abstract:
A sulfuric acid-catalyzed alkylation reactor system is provided for alkylating isoparaffins with olefins to produce hydrocarbon alkylates. The reactor vessel has a vertical cylindrical wall, a top, an inverted conical bottom portion, internal perforated baffles and multiple emulsion injection inlet pipes, disposed tangentially to and communicating with the interior of the reactor vessel. The emulsion injection inlet pipes have static mixers incorporated therein and tangential injection of the emulsion imparts a circular motion to the contents of the reactor vessel, resulting in partial phase separation of the reacted products. The reactor vessel communicates with a settling vessel through a transfer pipe having a vertical portion suspended within the central portion of the reactor vessel and a horizontal portion sealably extending through the cylindrical wall of the reactor vessel. The transfer pipe has a first end near the conical bottom portion of the reactor vessel and a second end at a top portion of the settling vessel. The reactor system enables a sulfuric-acid catalyzed reaction of olefins with isoparaffins utilizing static mixing of the reactants, and minimizing leakage of the reactants to the environment.
Abstract:
The present invention provides a weir quench, an apparatus utilizing the weir quench and processes incorporating the same. The weir quench incorporates an inlet having an inner diameter (Di) and an upper chamber having an inner diameter (Duc), wherein the inlet inner diameter (Di) is at least 90% of the upper chamber inner diameter (Duc). The apparatus constitutes a reactor having an outlet with an inner diameter fluidly coupled with the weir quench inlet, wherein the ratio of the reactor oulet inner diameter (Dr) to the weir quench inlet diameter (Di) is greater than one. The weir quench, and apparatus are advantageously utilized in processes utilizing a limiting reagent.
Abstract:
The invention relates to a device for producing poly(meth)acrylate in powder form, comprising a reactor (1) for droplet polymerisation that has a device (5), with holes through which a monomer solution is introduced, for dropletising said monomer solution so as to produce the poly(meth)acrylate, a gas supply point (13) above said dropletisation device (5), at least one gas extraction point (19) on the periphery of the reactor (1), and a fluidised bed (11), said reactor (1) having, above the gas extraction point (19), a region that has a constant hydraulic inner diameter and, below said gas extraction point (19), a hydraulic inner diameter that continually reduces. In the region with the continually-reducing hydraulic inner diameter, knockers (35) are mounted on the outer side of the reactor (1), each of said knockers (35) generating an impact energy of between 25J and 165J, and the number of knockers (35) being selected such that a surface-specific impact energy of between 1 and 7J/m² is applied.
Abstract:
A liquid fuel catalytic partial oxidation (CPOX) reformer can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. At least the exterior surface of the CPOX reaction zone can include a hydrogen barrier. The liquid fuel CPOX reformer can include a vaporizer, one or more igniters, and a source of liquid reformable fuel.
Abstract:
Integrated gaseous fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the gaseous fuel CPOX reformer.
Abstract:
[Problem] To provide a gas mixing device capable of promptly mixing a combustible gas with a combustion supporting gas with its simple configuration, and a synthetic gas manufacturing apparatus using the device. [Means for Resolution] In a gas mixing device which supplies a combustible gas and a combustion supporting gas from flow channels of a double pipe including an inner pipe 21 and an outer pipe 22 and mixes the gases, a first guide member 23 guides the gas, flowing out from a gas outflow port on one end side of the inner pipe 21, outward, and a second guide member 24 is formed in an annular shape along an inner peripheral wall of the outer pipe 22 of the second guide member 24 so that the inner peripheral portion is located closer to the upstream side than the outer peripheral portion and the inner peripheral portion is located closer to the center than the outer peripheral portion of the first guide member 23. In addition, a third guide member 25 is provided so as to face a region surrounded by the second guide member 24.
Abstract:
Described herein is a highly heat integrated steam reformer/combustor assembly that can be used in a fuel processor for hydrogen production from a fuel source. The assembly comprises a reforming section and a combustion section separated by a wall. Catalyst able to induce the reforming reactions is coated on the wall facing the reforming section. Catalyst able to induce the combustion reactions is coated on the wall facing the combustion section. A setam and fuel mixture is supplied to the reforming section where it is reformed to product hydrogen. A fuel and air mixture is supplied to the combustion section where it is combusted to supply the heat for the reformer. Catalytic combustion takes place on the combustion catalyst coated on one side of the wall while catalytic reforming takes place on the reforming catalyst coated on the other side of the wall. Heat transfer is very facile and efficient across the wall. Multiple such assemblies can be bundled to form reactors of any size.