公开(公告)号：US06949230B2

公开(公告)日：2005-09-27

申请号：US09929870

申请日：2001-08-14

Applicant: Michael Schwartz ,  James H. White ,  Anthony F. Sammells

Inventor： Michael Schwartz ,  James H. White ,  Anthony F. Sammells

IPC: B01D53/22 ,  B01D53/32 ,  B01D67/00 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/00 ,  B01J23/83 ,  B01J35/00 ,  B01J35/06 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01B17/04 ,  C01C3/02 ,  H01M8/12 ,  B01J35/02

CPC classification number: H01M8/1246 ,  B01D53/228 ,  B01D53/326 ,  B01D67/0041 ,  B01D67/0083 ,  B01D69/141 ,  B01D71/02 ,  B01D71/022 ,  B01D71/024 ,  B01D2323/08 ,  B01D2323/12 ,  B01J4/04 ,  B01J12/007 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0033 ,  B01J35/065 ,  B01J2219/00051 ,  B01J2219/00063 ,  B01J2219/0018 ,  B01J2219/00189 ,  B01J2523/00 ,  C01B3/36 ,  C01B3/386 ,  C01B13/0255 ,  C01B17/0465 ,  C01B2203/0261 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01B2210/0051 ,  C01B2210/0062 ,  C01B2210/0071 ,  C01B2210/0075 ,  C01C3/0216 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1231 ,  Y02E60/525 ,  Y02P20/52 ,  Y02P70/56 ,  Y10S505/701 ,  Y10S505/779 ,  Y10S505/785 ,  B01J2523/24 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/22 ,  B01J2523/32 ,  B01J2523/23

Abstract: This invention relates to gas-impermeable, solid state materials fabricated into membranes for use in catalytic membrane reactors. This invention particularly relates to solid state oxygen anion- and electron-mediating membranes for use in catalytic membrane reactors for promoting partial or full oxidation of different chemical species, for decomposition of oxygen-containing species, and for separation of oxygen from other gases. Solid state materials for use in the membranes of this invention include mixed metal oxide compounds having the brownmillerite crystal structure.

Abstract translation: 本发明涉及制备在用于催化膜反应器的膜中的气体不可渗透的固态材料。 本发明特别涉及用于催化膜反应器中用于促进不同化学物质的部分或全部氧化，用于分解含氧物质以及从其它气体中分离氧的固态氧阴离子和电子介质膜。 用于本发明的膜的固态材料包括具有褐砂岩晶体结构的混合金属氧化物化合物。

公开(公告)号：US06921517B2

公开(公告)日：2005-07-26

申请号：US10011785

申请日：2001-12-11

Applicant: Shuzo Matsumura ,  Masaji Yoneta ,  Rokuro Denda ,  Yoshito Umeda ,  Masao Hattori ,  Satoshi Hagi ,  Jun Funakoshi ,  Akira Kosaka

Inventor： Shuzo Matsumura ,  Masaji Yoneta ,  Rokuro Denda ,  Yoshito Umeda ,  Masao Hattori ,  Satoshi Hagi ,  Jun Funakoshi ,  Akira Kosaka

IPC: C08J11/12 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/24 ,  C01B3/24 ,  C01B3/34 ,  C10G1/10 ,  C10G9/00 ,  C10G9/20 ,  C10G9/38 ,  C10J3/00 ,  B01J8/06

CPC classification number: C10G9/38 ,  B01J4/04 ,  B01J12/005 ,  B01J19/2425 ,  B01J19/2475 ,  B01J2219/00123 ,  B01J2219/00157 ,  C01B3/24 ,  C01B3/34

Abstract: A hydrocarbon gas to be decomposed, optionally mixed with water vapor, is allowed to flow through the gap between various porous tubes 4 constituting a group of porous tubes provided extending vertically in a decomposition reaction column 1 while air or oxygen is jetted homogeneously from the interior to the exterior of the porous tubes in the direction perpendicular to the stream of the hydrocarbon gas to be decomposed, optionally mixed with water vapor. The mixture is then ignited to form a diffusion flame layer B on the outer surface of the porous tubes 4. With the diffusion flame layer as a heat source, the hydrocarbon gas to be decomposed, optionally mixed with water vapor, undergoes pyrolysis.

Abstract translation: 允许分解的烃气体，任选地与水蒸气混合，流过构成在分解反应塔1中垂直延伸的多孔管组的各种多孔管4之间的间隙，同时从内部均匀地喷射空气或氧气 在垂直于待分解的烃气体的方向上的多孔管的外部，任选地与水蒸气混合。 然后将混合物点燃以在多孔管4的外表面上形成扩散火焰层B. 以扩散火焰层作为热源，待分解的烃气体（任选地与水蒸气混合）经历热解。

公开(公告)号：US06911065B2

公开(公告)日：2005-06-28

申请号：US10331123

申请日：2002-12-26

Applicant: Tadaharu Watanabe ,  Robert Torres, Jr. ,  Joseph Vininski

Inventor： Tadaharu Watanabe ,  Robert Torres, Jr. ,  Joseph Vininski

IPC: B01D53/02 ,  B01J4/04 ,  C23C16/44 ,  F17C5/00 ,  F17C6/00 ,  F17C7/00 ,  F17C9/00 ,  F17C13/02 ,  B01D53/04

CPC classification number: F17C9/00 ,  B01D53/02 ,  B01J4/04 ,  C23C16/4402 ,  F17C5/00 ,  F17C6/00 ,  F17C7/00 ,  F17C13/026 ,  F17C2201/0104 ,  F17C2201/032 ,  F17C2203/0617 ,  F17C2205/0149 ,  F17C2205/0314 ,  F17C2205/0317 ,  F17C2205/0323 ,  F17C2205/0332 ,  F17C2205/0335 ,  F17C2205/0341 ,  F17C2205/0391 ,  F17C2221/05 ,  F17C2250/0631 ,  F17C2265/012 ,  Y02E60/321

Abstract: A fluid purifying apparatus that includes a manifold that includes a first branch and a second branch, a first check valve coupled to the first branch of the manifold, and a purifier unit that includes a first end and a second end, wherein the first end is coupled to the second branch of the manifold. Also, a fluid purifying apparatus that includes a vessel that includes a first interior compartment for containing a purifier material and a second interior compartment for containment of a fluid containing impurities, wherein the first interior compartment is separated from the second interior compartment by a fluid permeable support, and a rupturable seal.

Abstract translation: 一种流体净化装置，包括：歧管，包括第一分支和第二分支;第一止回阀，其联接到所述歧管的第一分支;以及净化器单元，其包括第一端和第二端，其中所述第一端为 耦合到歧管的第二分支。 此外，一种流体净化装置，其包括容器，该容器包括用于容纳净化剂材料的第一内部隔室和用于容纳含有杂质的流体的第二内部隔室，其中所述第一内部隔室与所述第二内部隔室分离， 支持和可破裂的印章。

公开(公告)号：US20050049444A1

公开(公告)日：2005-03-03

申请号：US10961316

申请日：2004-10-08

Applicant: Michael Benje

Inventor： Michael Benje

IPC: C07C17/10 ,  B01J4/04 ,  B01J19/24 ,  C07B61/00 ,  C07C17/02 ,  C07C17/06 ,  C07C19/045 ,  C07C21/08 ,  C07C17/093

CPC classification number: B01J19/2465 ,  B01J4/04 ,  B01J2219/00162 ,  B01J2219/00164 ,  C07C17/02 ,  C07C19/045

Abstract: With a method or a device for producing 1,2-dichloroethane or ethylene (di)chloride (EDC) with the use of a circulating reaction medium and a catalyst, whereby ethylene and chlorine are supplied to the reaction medium, the goal is to permit the catalytic chlorination of ethylene in a manner that is particularly gentle to the product. This is achieved in terms of the method and by other means in that the ethylene or chlorine gas are introduced into the reaction medium by means of microporous gas diffuser elements for producing gas bubbles with a diameter of 0.3 to 3 mm.

Abstract translation: 使用循环反应介质和催化剂制备1,2-二氯乙烷或乙烯（二氯）（EDC）的方法或装置，由此向反应介质供应乙烯和氯，目的是允许 以对产品特别温和的方式催化氯化乙烯。 这是通过方法和其他手段来实现的，其中乙烯或氯气通过用于产生直径为0.3至3mm的气泡的微孔气体扩散器元件引入反应介质。

公开(公告)号：US20040007292A1

公开(公告)日：2004-01-15

申请号：US10394804

申请日：2003-03-21

Inventor： Hideto Fujita ,  Yoshiyuki Fujita ,  Ryoji Fujino ,  Yasutaka Ogawa

IPC: C23C008/24

CPC classification number: B01J4/04 ,  B01J19/185 ,  B06B1/10 ,  C23C8/24 ,  C23C8/26

Abstract: A nitriding method includes the steps of nitriding an object held under a nitriding gas atmosphere in a sealed furnace and applying vibration energy to one or both of the nitriding gas and the object W to facilitate nitriding. A nitriding apparatus includes a nitriding furnace for holding an object W to be nitrided in a sealed manner, means 30 for supplying a nitriding gas to the furnace, and means 2 for applying vibration to the atmosphere gas in the furnace 1 to faciliate nitriding. According to the method or apparatus, nitriding-resistant or complex-shaped materials can be nitrided at high efficiency and a nitrided layer can be formed at a lower temperature for a shorter time as compared with conventional processes.

Abstract translation: 氮化方法包括以下步骤：在密封的炉中将保护在氮化气体气氛下的物体氮化，并向氮化气体和物体W中的一个或两个施加振动能量以促进氮化。 氮化装置包括氮化炉，用于将密封的氮化的物体W保持，用于向炉内供给氮化气体的装置30，以及向炉1中的大气气体施加振动以进行氮化的装置2。 根据该方法或装置，可以高效率地渗氮或复合形状的材料，与常规方法相比，可以在更短的时间内在较低的温度下形成氮化层。

公开(公告)号：US06428666B1

公开(公告)日：2002-08-06

申请号：US09256586

申请日：1999-02-22

Applicant: Anup K. Singh ,  David W. Neyer ,  Joseph S. Schoeniger ,  Michael G. Garguilo

Inventor： Anup K. Singh ,  David W. Neyer ,  Joseph S. Schoeniger ,  Michael G. Garguilo

IPC: G01N2726

CPC classification number: G01N30/00 ,  B01J4/04 ,  B01J19/2475 ,  G01N1/40 ,  G01N27/44743 ,  G01N2030/0035 ,  G01N2030/285

Abstract: A method for separating and concentrating charged species from uncharged or neutral species regardless of size differential. The method uses reversible electric field induced retention of charged species, that can include molecules and molecular aggregates such as dimers, polymers, multimers, colloids, micelles, and liposomes, in volumes and on surfaces of porous materials. The retained charged species are subsequently quantitatively removed from the porous material by a pressure driven flow that passes through the retention volume and is independent of direction thus, a multi-directional flow field is not required. Uncharged species pass through the system unimpeded thus effecting a complete separation of charged and uncharged species and making possible concentration factors greater than 1000-fold.

Abstract translation: 一种用于从不带电荷或中性物质分离和浓缩带电物质的方法，而不考虑大小差异。 该方法在多孔材料的体积和表面上使用可逆电场诱导的带电物质的保留，其可以包括分子和分子聚集体，例如二聚体，聚合物，多聚体，胶体，胶束和脂质体。 随后通过通过保持体积的压力驱动流从多孔材料中定量地除去保留的带电物质，并且不依赖于方向，因此不需要多方向流场。 不带电荷的物质无阻碍地通过系统，从而完全分离带电荷和不带电荷的物质，并使得可能的浓度因子大于1000倍。

公开(公告)号：US06426057B1

公开(公告)日：2002-07-30

申请号：US09987698

申请日：2001-11-15

Applicant: Bernhard Maurer

Inventor： Bernhard Maurer

IPC: C01B15023

CPC classification number: B01J19/2465 ,  B01J4/04 ,  B01J10/002 ,  B01J19/26 ,  B01J2219/00033 ,  B01J2219/00096 ,  B01J2219/185 ,  B01J2219/1943 ,  C01B15/023

Abstract: A continuous process for oxidation, in which the substance to be oxidized and the oxidizing gas flow countercurrently and the oxidizing gas is mixed with a split stream containing preoxidized substance before it enters the reactor. A Venturi nozzle is particularly suitable as the mixing organ in the reactor.

Abstract translation: 一种连续的氧化方法，其中待氧化物质和氧化气体逆流流动，氧化气体在进入反应器之前与含有预氧化物质的裂解流混合。 文丘里喷嘴特别适用于反应器中的混合器。

公开(公告)号：US20020022568A1

公开(公告)日：2002-02-21

申请号：US09905651

申请日：2001-07-13

Inventor： Richard Mackay ,  Anthony F. Sammells

IPC: B01J023/10 ,  C01B003/26 ,  C04B035/50

CPC classification number: B01D53/228 ,  B01D53/326 ,  B01D67/0041 ,  B01D67/0083 ,  B01D69/141 ,  B01D71/02 ,  B01D71/022 ,  B01D71/024 ,  B01D2323/08 ,  B01D2323/12 ,  B01J4/04 ,  B01J12/007 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0033 ,  B01J35/065 ,  B01J2219/00051 ,  B01J2219/00063 ,  B01J2219/0018 ,  B01J2219/00189 ,  B01J2523/00 ,  C01B3/36 ,  C01B3/386 ,  C01B13/0255 ,  C01B17/0465 ,  C01B2203/0261 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01B2210/0051 ,  C01B2210/0062 ,  C01B2210/0071 ,  C01B2210/0075 ,  C01C3/0216 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1231 ,  H01M8/1246 ,  Y02E60/525 ,  Y02P20/52 ,  Y02P70/56 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/842 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/845 ,  B01J2523/22 ,  B01J2523/32

Abstract: Ceramics of the composition:Ln1-xSryCax-yMO3-nullwhere Ln is an element selected from the f block lanthanides and yttrium or mixtures thereof; M is an element selected from the d block transition metals or mixtures thereof; 0.1nullxnull0.4; 0.01nullynull0.25 and null is a number that varies to maintain charge neutrality are provided along with methods of their use. These ceramics are useful in making and using gas-impermeable ceramic membranes that exhibit high electronic and ionic conductivity, low coefficients of expansion and high chemical and thermal stability under catalytic membrane reactor conditions. The ceramics provided are particularly useful for promotion of oxidation-reduction reactions and for separating molecular oxygen from oxygen containing gases.

Abstract translation: 陶瓷的组成：<段落lvl =“0”> Ln1-xSryCax-yMO3-delta 其中Ln是从f块中选择的元素镧系元素和钇或混合物 的; M是选自d嵌段过渡金属或其混合物的元素; 0.1 <= x <= 0.4; 0.01 <= y <= 0.25，并且delta是维持电荷中性而变化的数字及其使用方法。 这些陶瓷可用于制造和使用气体不可渗透的陶瓷膜，其在催化膜反应器条件下表现出高电子和离子电导率，低膨胀系数和高的化学和热稳定性。 提供的陶瓷对于促进氧化还原反应和从含氧气体中分离分子氧是特别有用的。

公开(公告)号：US5798119A

公开(公告)日：1998-08-25

申请号：US489888

申请日：1995-06-13

Applicant: Scott M. Herbig ,  Eric J. Miller

Inventor： Scott M. Herbig ,  Eric J. Miller

IPC: A61K9/00 ,  A61K9/52 ,  B01J4/04 ,  A61K9/22 ,  A61K9/24 ,  A61K9/32 ,  A61K9/34

CPC classification number: A61K9/0004 ,  B01J4/04

Abstract: An osmotic device that, following the imbibition water vapor, provides for the controlled release of a beneficial agent to a non-aqueous environment. The device comprises a hydrophilic formulation and a beneficial agent, surrounded by a wall. The wall is formed at least in part of a semipermeable hydrophobic microporous membrane having an average pores size between about 0.1 .mu.m and 30 .mu.m. The pores are substantially filled with a gas phase. The hydrophobic membrane is permeable to water in the vapor phase and the hydrophobic membrane is impermeable to an aqueous medium at a pressure less than about 100 Pa. The beneficial agent is released, for example, by osmotic pumping or osmotic bursting upon imbibition of sufficient water vapor into the hydrophilic formulation. The high water fluxes attendant with these vapor-permeable hydrophobic membranes facilitate the delivery of large quantities of beneficial agents without requiring large surface areas (quantities) of hydrophobic microporous membrane. In addition, use of vapor-permeable hydrophobic microporous membranes allow osmotic devices to be used in environments having limited water availability, such as air or soil.

Abstract translation: 渗透装置，其在吸收水蒸汽之后提供有益剂受控释放到非水环境中。 该装置包括由壁包围的亲水制剂和有益剂。 所述壁至少部分形成有平均孔径在约0.1μm至30μm之间的半透性疏水性微孔膜。 孔基本上充满气相。 疏水膜在气相中对水是可渗透的，并且疏水膜在低于约100Pa的压力下对水性介质是不可渗透的。有益剂例如通过渗透泵送或在渗透足够的水 蒸气进入亲水制剂。 与这些透气疏水膜伴随的高水通量有助于大量有益剂的输送，而不需要疏水微孔膜的大表面积（量）。 此外，使用透气疏水性微孔膜允许渗透装置用于具有有限水可用性的环境中，例如空气或土壤。

公开(公告)号：US5739384A

公开(公告)日：1998-04-14

申请号：US717016

申请日：1996-09-20

Applicant: Miguel Angel Melgosa Albillos ,  Jorge Molina Marsans ,  Lorenzo Ortega Calvo

Inventor： Miguel Angel Melgosa Albillos ,  Jorge Molina Marsans ,  Lorenzo Ortega Calvo

IPC: B01J4/04 ,  C07C51/265

CPC classification number: C07C51/265 ,  B01J4/04 ,  Y02P20/584

Abstract: The process that involves liquid phase catalytic oxidation of a mono- or poly-substituted alkyl aromatic compound comprises: (i) microdispersion of the air in the reactor at a pressure between 15 and 25 atmospheres and at a rate between 200 and 500 kg/sec.m.sup.2 ; and (ii) recycling the catalyst by evaporation of the purge that contains it and leaching the resulting paste with distilled water at 20.degree.-40.degree. C. to dissolve the catalyst separating it from the rest of the components. Aromatic carboxylic acids are basic products used in a large number of industrial fields.

Abstract translation: 涉及单取代或多取代的烷基芳族化合物的液相催化氧化的方法包括：（i）空气在15和25个大气压之间并以200-500kg / sec的速率在反应器中微分散 .m2; 和（ii）通过蒸发含有它的吹扫再循环催化剂，并用蒸馏水在20℃-40℃下浸出所得糊状物以溶解其与其余组分分离的催化剂。 芳族羧酸是用于大量工业领域的基本产品。