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    Fabrication method of nanomaterials by using polymeric nanoporous templates
    137.
    发明申请
    Fabrication method of nanomaterials by using polymeric nanoporous templates 审中-公开
    使用聚合纳米多孔模板制备纳米材料的方法

    公开(公告)号：US20110003069A1

    公开(公告)日：2011-01-06

    申请号：US12655342

    申请日：2009-12-29

    Applicant: Rong-Ming Ho ,  Han-Yu Hsueh ,  Ming-Shiuan She ,  Wen-Hsien Tseng ,  Chun-Ku Chen ,  Yeo-Wan Chiang

    Inventor： Rong-Ming Ho ,  Han-Yu Hsueh ,  Ming-Shiuan She ,  Wen-Hsien Tseng ,  Chun-Ku Chen ,  Yeo-Wan Chiang

    IPC: B05D5/12 ,  B05D3/02 ,  B05D3/06

    CPC classification number: C01G23/006 ,  C01B33/18 ,  C01G23/053 ,  C01P2004/04 ,  C08J9/26 ,  C08J2201/0462

    Abstract: A fabrication method of a nanomaterial by using a polymeric nanoporous template is disclosed. First, a block copolymer bulk is made from a block copolymer polymerized from decomposable and undecomposable monomers. By removing the decomposable portion of the block copolymer bulk, the polymeric nanoporous template with a plurality of holes is obtained, and these holes have nanostructures with regular arrangement. By exploiting a nanoreactor concept, a sol-gel process or an electrochemical synthesis, for example, is then carried out within the template such that the holes are filled with various filler materials, such as ceramics, metals and polymers, so as to prepare a nanocomposite material having the nanostructure. After removing the polymeric nanoporous template, the nanomaterial with the nanostructure is manufactured.

    Abstract translation: 公开了通过使用聚合物纳米多孔模板制备纳米材料的方法。 首先，由可分解和不可分解的单体聚合的嵌段共聚物制成嵌段共聚物体。 通过除去嵌段共聚物本体的可分解部分，获得具有多个孔的聚合纳米多孔模板，并且这些孔具有规则排列的纳米结构。 通过利用纳米反应器的概念，例如在模板内进行溶胶 - 凝胶法或电化学合成，使得孔用诸如陶瓷，金属和聚合物的各种填充材料填充，从而制备 具有纳米结构的纳米复合材料。 在去除聚合物纳米多孔模板之后，制造具有纳米结构的纳米材料。

    Functionalized porous poly(aryl ether ketone) materials and their use
    139.
    发明授权
    Functionalized porous poly(aryl ether ketone) materials and their use 有权
    官能化多孔聚（芳醚酮）材料及其用途

    公开(公告)号：US07368526B2

    公开(公告)日：2008-05-06

    申请号：US11548078

    申请日：2006-10-10

    Applicant: Youxin Yuan ,  Yong Ding

    Inventor： Youxin Yuan ,  Yong Ding

    IPC: C08F6/06 ,  C08F6/12 ,  C08G12/00

    CPC classification number: C08J9/26 ,  B01D67/0093 ,  B01D71/52 ,  B01D71/82 ,  B01D2323/36 ,  B01D2323/38 ,  B01J20/26 ,  B01J20/262 ,  B01J20/265 ,  B01J20/28033 ,  B01J20/28092 ,  B01J20/285 ,  C08J2201/0462 ,  C08J2379/08 ,  C08L71/00 ,  C08L79/08 ,  Y10T428/249953 ,  C08L2666/22

    Abstract: Functionalized porous poly(aryl ether ketone) articles are prepared by reacting ketone groups in the backbone of poly(aryl ether ketone) polymer with a primary amine reagent. Preferred functional primary amines are primary aliphatic amines or substituted hydrazines containing one or more target functional groups including polar groups, such as hydroxyl groups, ˜OH, amino groups, ˜NH2, ˜NHR, ˜NRR′, and ethylene oxide groups, ˜OCH2CH2—, negatively or positively charged ionic groups, such as ˜SO3−, ˜COO−, and ˜NH4+ groups, hydrophobic groups such as siloxane or perfluorcarbone groups, and non-polar groups, such as linear or branched hydrocarbon groups. The functionalized porous poly(aryl ether ketone) article can be prepared by reacting primary amine with a pre-formed, shaped porous poly(aryl ether ketone) article or by functionalizing the surface of a non-porous precursor article that is subsequently converted into a porous article.

    Abstract translation: 官能化多孔聚（芳醚酮）制品是通过使聚（芳基醚酮）聚合物的主链中的酮基与伯胺试剂反应来制备的。 优选的官能伯胺是含有一个或多个靶官能团的主要脂族胺或取代肼，包括极性基团，例如羟基，-OH，氨基，〜NH 2，〜NHR，〜NRR' ，和环氧乙烷基团，-OCH 2 CH 2 - ，带正电或带正电荷的离子基团，例如SO 3 - 和/或者NH 4基团，疏水基团如硅氧烷或全氟咔唑基团，和非极性基团 基团，例如直链或支链烃基。 官能化的多孔聚（芳醚酮）制品可以通过使伯胺与预形成的多孔聚（芳醚酮）制品反应或通过官能化无孔前体制品的表面来制备，随后将其转化为 多孔制品。

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