公开(公告)号：US5939514A

公开(公告)日：1999-08-17

申请号：US906538

申请日：1997-08-05

Applicant: Ward Thomas Brown ,  Donald Craig Schall ,  Francis Joseph Landy ,  Ann Robertson Hermes

Inventor： Ward Thomas Brown ,  Donald Craig Schall ,  Francis Joseph Landy ,  Ann Robertson Hermes

IPC: C09D201/02 ,  C08K5/00 ,  C08L33/14 ,  C09D4/02 ,  C09D5/00 ,  C09D133/06 ,  C09D201/00 ,  C08L79/00 ,  C08L101/00 ,  C09D5/02

CPC classification number: C09D201/00 ,  C08K5/0025 ,  C09D133/064 ,  C09D201/02 ,  C09D5/004 ,  C08L33/14

Abstract: The present invention relates to the preparation of water based coating compositions having extended storage stability. The composition includes separately stored polymeric binder component and a crosslinking component.These components are mixed prior to application over surfaces, such as, road surfaces. The polymeric binder component includes an anionically stabilized binder polymer having at least one reactive functional pendent moiety, or a blend of the binder polymer with a polyfunctional amine. The pot mix of the coating composition has extended storage stability. The waterborne road marking paints of the present invention exhibit improved wear resistance on road surfaces in terms of paint remaining on the road longer than waterborne road marking paints based on the storage stable component alone. The present invention provides road marking paints that can be applied by conventional road striping equipment and do not require special two component spray equipment.

Abstract translation: 本发明涉及具有延长储存稳定性的水基涂料组合物的制备。 组合物包括单独存储的聚合物粘合剂组分和交联组分。 这些组分在施加在诸如路面之类的表面之前被混合。 聚合物粘合剂组分包括具有至少一个反应性官能侧基部分的阴离子稳定的粘合剂聚合物，或粘合剂聚合物与多官能胺的共混物。 涂料组合物的罐混合物具有延长的储存稳定性。 基于仅存储稳定组分，本发明的水性道路标线涂料在路面上保留的油漆表现出比水性道路标线漆更好的耐磨性。 本发明提供了可以通过常规路线设备应用的道路标线涂料，并且不需要特殊的双组分喷涂设备。

公开(公告)号：US5922633A

公开(公告)日：1999-07-13

申请号：US844050

申请日：1997-04-18

Applicant: Yoshinori Nakane ,  Hiroki Mizutani ,  Hayato Ishibashi ,  Masahiro Ishidoya

Inventor： Yoshinori Nakane ,  Hiroki Mizutani ,  Hayato Ishibashi ,  Masahiro Ishidoya

IPC: C08L101/02 ,  C09D133/06 ,  C09D157/04 ,  C09D201/02 ,  B01J31/04 ,  B01J31/26

CPC classification number: C08L101/02 ,  C09D133/062 ,  C09D157/04 ,  C09D201/02

Abstract: A thermal latent acid catalyst which comprises (i) a compound having an epoxy group, (ii) a compound having a sulfur atom of the following formula: R.sup.5 --S--R.sup.6, wherein R.sup.5 and R.sup.6 are the same or different from each other and are a hydrogen atom or an organic group of 1 to 40 carbon atoms, R.sup.5 and R.sup.6 optionally are bonded with each other to form a cyclic structure; and (iii) a Lewis acid of the following formula: (X.sup.1).sub.n1 --M.sup.1 --(R.sup.7).sub.n2, wherein M.sup.1 is a boron atom, an aluminium atom, a tin atom, a lead atom or a transition element, X.sup.1 is one or more halogen atoms, R.sup.7 is one or more organic groups of 1 to 40 carbon atoms, R.sup.7 optionally forms a chelate ring by coordinating to the M.sup.1 atom, n1 and n2 are each an integer of 0 through 6, and n1 plus n2 equals an integer of 1 to 6. The ratio of the epoxy group of the epoxy compound (i) to the M.sup.1 atom of the Lewis acid is 0.2 to 10 and the ratio of the sulfur atom of the compound (ii) to the M.sup.1 atom of the Lewis acid is 0.2 to 10.

Abstract translation: 一种热潜潜酸催化剂，其包含（i）具有环氧基的化合物，（ii）具有下式的硫原子的化合物：R5-S-R6，其中R5和R6彼此相同或不同， 是氢原子或1〜40个碳原子的有机基团，R5和R6任选地相互结合形成环状结构; 和（iii）下式的路易斯酸：（X1）n1-M1-（R7）n2，其中M1是硼原子，铝原子，锡原子，引线原子或过渡元素，X1是一个 或更多的卤素原子，R7是一个或多个1至40个碳原子的有机基团，R7任选地通过与M1原子配位形成螯合环，n1和n2各自为0至6的整数，n1加上n2等于 环氧化合物（i）的环氧基与路易斯酸的M1原子的比例为0.2〜10，化合物（ii）的硫原子与M1原子的比例 路易斯酸为0.2〜10。

公开(公告)号：US5908877A

公开(公告)日：1999-06-01

申请号：US852303

申请日：1997-05-07

Applicant: Xiaohong Ci ,  David RIchard Amick ,  Richard Foster Merritt

Inventor： Xiaohong Ci ,  David RIchard Amick ,  Richard Foster Merritt

IPC: C09D5/03 ,  C09D5/02 ,  C09D201/00 ,  C09D201/02 ,  C08F8/00

CPC classification number: C04B41/48 ,  C04B26/02 ,  C09D201/00 ,  C09D201/02 ,  C09D5/02 ,  C04B2103/0057 ,  C04B2111/00482 ,  C04B2111/1037 ,  Y10S525/902

Abstract: A water dispersible powder composition is provided. The powder composition contains at least one film-forming polymer having at least one functional group and at least one reactive component that reacts to form a non-ionic bond with the polymer functional group following dispersion of the powder composition in water. The reaction between the polymer particles in the admixture and the reactive component renders the resulting coating water-resistant. The powder composition of this invention is useful for producing water-resistant coatings.

Abstract translation: 提供了水分散性粉末组合物。 该粉末组合物含有至少一种具有至少一个官能团的成膜聚合物和至少一种在粉末组合物分散在水中后与聚合物官能团反应形成非离子键的反应性组分。 混合物中的聚合物颗粒与反应性组分之间的反应使所得到的涂层具有防水性。 本发明的粉末组合物可用于生产防水涂料。

公开(公告)号：US5872195A

公开(公告)日：1999-02-16

申请号：US886321

申请日：1997-07-01

Applicant: Marvin L. Green ,  John W. Rehfuss

Inventor： Marvin L. Green ,  John W. Rehfuss

IPC: C09D175/04 ,  C08G59/14 ,  C08G71/00 ,  C08L61/20 ,  C09D133/06 ,  C09D167/00 ,  C09D179/04 ,  C09D201/02 ,  C08G8/28 ,  C08L63/00 ,  C08L67/04

CPC classification number: C09D201/025 ,  C08G59/1438 ,  C08G59/1477 ,  C08G59/1494 ,  C08G71/00 ,  C09D133/06 ,  C09D133/062 ,  C09D167/00 ,  C09D201/02 ,  C08L61/20 ,  Y10T428/31551

Abstract: Curable coating compositions are described comprising(a) a polymer resin comprising active hydrogen-containing functional groups,(b) a curing agent having groups that are reactive with said functional groups on (a), and(c) a compound comprising at least one carbamate group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a compound comprising a carbamate group.

Abstract translation: 描述了可固化涂料组合物，其包含（a）包含含活性氢的官能团的聚合物树脂，（b）具有与（a）上的所述官能团反应的基团的固化剂，和（c）包含至少一种 氨基甲酸酯基，其为：（1）作为环氧基和有机酸基之间的开环反应的结果的羟基，以及（2）氰酸或包含氨基甲酸酯基的化合物的反应产物。

公开(公告)号：US5756213A

公开(公告)日：1998-05-26

申请号：US698528

申请日：1996-08-15

Applicant: Walter H. Ohrbom ,  John W. Rehfuss ,  John D. McGee ,  Gregory G. Menovcik ,  Paul J. Harris

Inventor： Walter H. Ohrbom ,  John W. Rehfuss ,  John D. McGee ,  Gregory G. Menovcik ,  Paul J. Harris

IPC: C09D161/20 ,  C08G71/00 ,  C08G71/04 ,  C09D167/04 ,  C09D169/00 ,  C09D175/04 ,  C09D201/00 ,  C09D201/02 ,  C09D161/28

CPC classification number: C09D175/04 ,  C08G71/00 ,  C08G71/04 ,  C09D167/04 ,  C09D169/00 ,  C09D201/02 ,  Y10T428/31507 ,  Y10T428/31942

Abstract: A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).

Abstract translation: 描述了可固化涂料组合物，其包含（A）包含多个官能交联基团的化合物，其中至少一个是氨基甲酸酯或脲官能团，该化合物还包括至少一个具有以下结构的碳酸酯基团：和 （B）包含与化合物（A）上的官能团反应的多个基团的固化剂。

公开(公告)号：US5661219A

公开(公告)日：1997-08-26

申请号：US297588

申请日：1994-08-29

Applicant: Yoshinori Nakane ,  Hiroki Mizutani ,  Hayato Ishibashi ,  Masahiro Ishidoya

Inventor： Yoshinori Nakane ,  Hiroki Mizutani ,  Hayato Ishibashi ,  Masahiro Ishidoya

IPC: C08L101/02 ,  C09D133/06 ,  C09D157/04 ,  C09D201/02 ,  C08L67/02 ,  C08L29/00 ,  C08L33/02 ,  C08L37/00

CPC classification number: C08L101/02 ,  C09D133/062 ,  C09D157/04 ,  C09D201/02

Abstract: A curable composition comprising (A) a compound having in the molecule two or more specific blocked carboxyl groups: (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a catalytic component selected from the following: (a) a thermal latent acid catalyst which comprises a compound having a epoxy group, a specific compound having a sulfur atom and a specific Lewis acid; (b) a thermal latent acid catalyst which comprises a specific compound, having at least one of a nitrogen atom, an oxygen atom, a phosphorus atom or a sulfur atom, a specific compound having a halogen atom and a specific Lewis acid having at least one of an aluminum atom, a zinc atom or a tin atom; or a mixture which comprises (c) a metallic chelate compound and a specific organic silicon compound or a condensate thereof. A two component curable composition is prepared by mixing (I) a main material composition or a solution thereof comprising the compound (A) and the compound (B) or a self-crosslinkable compound (D), and (II) an acid catalyst or the solution comprising at least one of a Bronsted acid, a Lewis acid or a mixture of a metallic chelate compound and a compound having a silanol group. The curable composition provides cured products having excellent chemical properties and physical properties and having desirable weathering resistance, stain resistance and appearance.

Abstract translation: 一种可固化组合物，其包含（A）在分子中具有两个或更多个特定的封端羧基的化合物：（B）分子中具有两个或更多个与所述封端羧基形成化学键的反应性官能团的化合物，和（C ）选自以下的催化组分：（a）包含具有环氧基的化合物，具有硫原子的特定化合物和特定路易斯酸的热潜伏酸催化剂; （b）含有具有氮原子，氧原子，磷原子或硫原子中的至少一个的特定化合物的热潜伏酸催化剂，具有卤素原子的特定化合物和特定的路易斯酸具有至少 铝原子，锌原子或锡原子之一; 或包含（c）金属螯合物和特定有机硅化合物或其缩合物的混合物。 通过混合（I）包含化合物（A）和化合物（B）的主要组合物或其溶液或自交联化合物（D），和（II）酸催化剂或 所述溶液包含Br + E，O + EE + nsted酸，路易斯酸或金属螯合物与具有硅烷醇基团的化合物的混合物中的至少一种。 可固化组合物提供具有优异的化学性质和物理性质的固化产物，并具有期望的耐候性，耐污染性和外观。

公开(公告)号：US5608003A

公开(公告)日：1997-03-04

申请号：US494157

申请日：1995-06-23

Applicant: Dong-Wei Zhu

Inventor： Dong-Wei Zhu

IPC: C08L101/02 ,  C08K3/34 ,  C08L33/14 ,  C08L39/00 ,  C09D133/14 ,  C09D133/16 ,  C09D139/00 ,  C09D143/04 ,  C09D201/02 ,  C09D201/06

CPC classification number: C09D201/02 ,  C09D133/16 ,  C09D143/04 ,  C09D201/06

Abstract: Water-based coating compositions comprise an aqueous solution, emulsion, or dispersion of (a) a water-soluble or water-dispersible polymer or oligomer having at least one anionic moiety which is capable of reacting with an oxazoline or oxazine moiety; (b) a water-soluble or water-dispersible polymer or oligomer having at least one oxazoline or oxazine moiety; and (c) colloidal silica; at least one of the components (a) and (b) further comprising at least one fluoroaliphatic moiety. The compositions can be used to form hard coatings having low surface energy and high abrasion resistance.

Abstract translation: 水性涂​​料组合物包含（a）具有至少一个能够与恶唑啉或恶嗪部分反应的阴离子部分的水溶性或水分散性聚合物或低聚物的水溶液，乳液或分散体; （b）具有至少一个恶唑啉或恶嗪部分的水溶性或水分散性聚合物或低聚物; 和（c）胶体二氧化硅; 组分（a）和（b）中的至少一种还包含至少一个氟脂族部分。 该组合物可用于形成具有低表面能和高耐磨性的硬涂层。

公开(公告)号：US5523363A

公开(公告)日：1996-06-04

申请号：US122561

申请日：1993-09-30

Applicant: Toshio Fujibayashi ,  Haruo Nagaoka

Inventor： Toshio Fujibayashi ,  Haruo Nagaoka

IPC: C09D5/44 ,  C09D163/04 ,  C09D201/02 ,  C08F283/00 ,  C08K3/20

CPC classification number: C09D163/04 ,  C09D201/02 ,  C09D5/4473

Abstract: A resin composition for aqueous coating, comprising, as the main components, a resin having hydroxyl group(s) and cationic group(s) and a certain novolac-substituted phenol type epoxy resin. This composition has excellent bath stability and low-temperature curability and is useful in cationic electrocoatings, in particular.

Abstract translation: PCT No.PCT / JP93 / 00102 Sec。 371日期：1993年9月30日 102（e）1993年9月30日PCT 1993年1月28日PCT公布。 公开号WO93 / 15157 日本8月5日，1993年。一种水性涂料用树脂组合物，其为主要成分，含有羟基和阳离子基团的树脂和某些酚醛清漆取代的酚型环氧树脂。 该组合物具有优异的浴稳定性和低温固化性，特别适用于阳离子电涂层。

公开(公告)号：US5521011A

公开(公告)日：1996-05-28

申请号：US444160

申请日：1995-05-18

Applicant: Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

Inventor： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

IPC: B32B27/30 ,  B32B27/36 ,  B32B27/38 ,  C08L29/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/06 ,  C08L37/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00

CPC classification number: C08L67/00 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00 ,  C08L33/06 ,  C08L63/00 ,  Y10T428/31511 ,  Y10T428/31518 ,  Y10T428/31529 ,  Y10T428/31551 ,  Y10T428/31699 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

Abstract: An article coated by a method of coating which comprises coating a substrate with a top coating material comprising at least one pigment and a thermosetting composition, the at least one pigment being in an amount of 0 to 100 weight parts based on 100 weight parts of the thermosetting composition, the thermosetting composition comprising (A) a compound having in the molecule two or more functional groups of the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each selected from the group consisting of a hydrogen atom and an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the hetero atom; (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the functional groups of the compound (A) by heating, the reactive functional groups of the compound (B) are epoxy groups; and (F) a complex compound formed by coordination of a conjugated base of a Bronsted acid or a Bronsted salt to a vacant orbital of a Lewis acid in a mol ratio of the Bronsted acid or Bronsted salt to the vacant orbital of the Lewis acid of 0.1 to 4.

Abstract translation: 一种通过涂覆方法涂覆的制品，其包括用包含至少一种颜料和热固性组合物的顶部涂料涂覆基材，所述至少一种颜料的量为0至100重量份，基于100重量份的 所述热固性组合物包含（A）分子中具有式（I）的两个或多个官能团的化合物：其中R 1，R 2和R 3各自选自氢 原子和1至18个碳原子的有机基团，R 4是1至18个碳原子的有机基团，Y 1是氧或硫，或者R 3和R 4彼此键合，形成杂环结构，其包含Y1作为杂原子 原子; （B）化合物在分子中具有两个或更多个可通过加热与化合物（A）的官能团形成化学键的反应性官能团，化合物（B）的反应性官能团是环氧基; 和（F）通过将布朗斯台德酸或布朗斯台德盐的共轭碱与布朗斯台德酸或布朗斯特盐的摩尔比与路易斯酸的空位轨道配位的络合物与路易斯酸的空位轨道 0.1至4。

公开(公告)号：US4885355A

公开(公告)日：1989-12-05

申请号：US236819

申请日：1988-08-26

Applicant: Ritchie A. Wessling ,  Donald L. Schmidt ,  Kiyoshi I. Aikawa

Inventor： Ritchie A. Wessling ,  Donald L. Schmidt ,  Kiyoshi I. Aikawa

IPC: C07D333/32 ,  C07D333/46 ,  C08F20/38 ,  C08F22/24 ,  C08G59/14 ,  C09D201/02

CPC classification number: C09D201/02 ,  C07D333/32 ,  C07D333/46 ,  C08F20/38 ,  C08F22/24 ,  C08G59/1483

Abstract: Water-soluble sulfonium salts are converted, without the elimination of odorous volatile by-products, to water-insoluble products useful as binders in coating formulations by heating a water-soluble cyclic sulfonium salt in which the sulfonium sulfur is bonded only to aliphatic carbons.

Abstract translation: 通过加热其中锍硫仅与脂肪族碳键合的水溶性环状锍盐，将水溶性锍盐转化成不含恶臭挥发性副产物的水不溶性产物，作为涂料配方中的粘合剂。