Low-to-Mid Range Water-Reducing Polymer With Mixed Polyoxyalkylene Side Chains

    公开(公告)号:US20170320777A1

    公开(公告)日:2017-11-09

    申请号:US15144958

    申请日:2016-05-03

    Inventor: Lawrence L. Kuo

    Abstract: Methods for plasticizing cementitious mixtures having relatively high water/cement ratio (at least 0.40 or higher) are surprisingly improved in terms of dosage efficiency, compared to conventional “superplasticizer” polycarboxylate polymers, when the comb-type carboxylate copolymer is formed from two different polyether side chains, specifically selected monomer constituents: (A) first polyoxyalkylene monomer represented by structural formula (R1)(R3)C═C(R2)((CH2)m(CO)nO(CH2)o(AO)pR4) wherein (AO)p represents linear alkylene oxide and p is an integer of 5-23; (B) second polyoxyalkylene monomer represented by structural formula (R1)(R3)C═C(R2)((CH2)m(CO)nO(CH2)o(AO)qR4) wherein (AO)q represents linear alkylene oxide groups and q is an integer of 20 to 200; (C) unsaturated carboxylic acid monomer represented by (R5)(R7)C═C(R6)(C(O)OM) wherein M represents an alkali metal, and the ratio of component A to component B is 20:80 to 50:50; and, optionally, (D) a water-soluble monomer represented by (R8)(R9)C═C(R10)(X) wherein R8, R9, and R10 each represent hydrogen or methyl group, and X represents C(O)NH2, C(O)NHR11, C(O)NR12R13, OR14, SO3H, C6H4SO3H, or C(O)NHC(CH3)2CH2SO3H, or mixture thereof, wherein R11, R12, R13, and R14 each represent a C1 to C5 alkyl group.

    Sag Resistant Vapor Permeable Barrier Coating Applicable at Low Temperature

    公开(公告)号:US20170240763A1

    公开(公告)日:2017-08-24

    申请号:US15504104

    申请日:2015-08-12

    Abstract: Methods and systems of the invention, for achieving a liquid-applicable, aqueous-based coating composition that forms a water-impermeable, vapor permeable barrier coating when applied onto a construction surface and allowed to dry, involve mixing together separate first and second components, wherein the first component comprises an acrylic emulsion, flame retardant, clay, and optionally at least one additive selected from thickeners (e.g., cellulosic), fillers, and other conventional additives; and wherein the second component comprises a freezing point depressing agent with a specific type of thickener selected from the group of associative thickeners, alkali soluble emulsion thickeners, or mixture thereof, to obtain the liquid-applicable coating. The present invention achieves low temperature film formation without reliance upon calcium nitrite, calcium nitrate, or sodium chloride type of freezing point depressing salts. The coating can be applied at low (e.g., sub-freezing) temperatures onto a construction surface such as wood, fiberboard, gypsum, cement, concrete, and other building substrates to achieve an effective barrier membrane.

    EARLY STRENGTH SLAG-BASED CEMENTITIOUS BINDER
    149.
    发明申请

    公开(公告)号:WO2022072779A1

    公开(公告)日:2022-04-07

    申请号:PCT/US2021/053092

    申请日:2021-10-01

    Abstract: The present invention provides exemplary method and additive for making cementitious binders that comprise primarily ground granulated blast furnace slag (GGBFS) having excellent strength at 24 hours, with preferably little or minimal amounts of Ordinary Portland Cement (OPC). As OPC manufacture involves carbon dioxide release into the atmosphere, the use of a GGBFS-based binder composition will help to enhance sustainability practices in the construction industry and minimizing strength losses implied by deletion of OPC. Strength in the GGBFS binder composition is enhanced by an alkaline-earth activator in combination with a strength enhancing component comprising dispersant and secondary activator.

    TWO-COMPONENT ACRYLATE-BASED INJECTION RESINS FOR SOIL STABILIZATION

    公开(公告)号:WO2021162999A1

    公开(公告)日:2021-08-19

    申请号:PCT/US2021/017146

    申请日:2021-02-08

    Abstract: A composition and method for stabilizing or consolidating low permeability soil, rock, coal, mineral, or other loose aggregates, especially in a subterranean environment. Disclosed is a two-component, acrylate-based injection resin that includes a first component and a second component. The first component comprises an acrylate and an accelerator, and the second component comprises a radical initiator. At the application site, the components are mixed together to form a liquid resin mixture with sufficiently low viscosity, such that the mixture can permeate the low permeability soil. The mixture is injected into the soil in need of stabilization and undergoes polymerization and curing, in turn forming a subterranean geocomposite having high compressive strength.

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