公开(公告)号：EP2758440A1

公开(公告)日：2014-07-30

申请号：EP12759441.4

申请日：2012-09-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  PANTALEONI, Roberto ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  NEUMANN, Andreas ,  MAZZUCCO, Antonio ,  COLLINA, Gianni ,  SARTORI, Gabriella

IPC: C08F4/651 ,  C08F4/654 ,  C08F10/06 ,  C08J5/18 ,  C08F4/649

CPC classification number: C08F10/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F4/651 ,  C08F4/6543 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15

Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

Abstract translation: 一种制备高纯度丙烯聚合物的方法，所述丙烯聚合物在催化剂存在下进行，所述催化剂包括通过使（a）包含Mg，Ti和至少第一内部电子给体化合物（HD）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内给电子体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物，并且任选地与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分的摩尔比 （b）:( a）低于5。

公开(公告)号：EP2480606B1

公开(公告)日：2014-05-28

申请号：EP10745274.0

申请日：2010-08-26

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  CIARAFONI, Marco ,  COLLINA, Gianni ,  FUSCO, Ofelia ,  PANTALEONI, Roberto ,  MAZZUCCO, Antonio

IPC: C08L23/12 ,  C08F2/00

CPC classification number: C08F297/083 ,  C08F110/06 ,  C08F210/06 ,  C08L23/12 ,  C08L23/16 ,  C08L2205/02 ,  C08L2207/02 ,  C08L2308/00 ,  C08L2314/02 ,  C08L2666/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F2500/17

公开(公告)号：EP2501727B1

公开(公告)日：2014-05-14

申请号：EP10782232.2

申请日：2010-11-15

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COLLINA, Gianni ,  CIARAFONI, Marco ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  GALVAN, Monica ,  MORINI, Giampiero ,  PANTALEONI, Roberto ,  PATER, Joachim T.M. ,  PIEMONTESI, Fabrizio ,  VERROCCHIO, Francesca

IPC: C08F10/06

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F2/001 ,  C08F4/6494 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/05

公开(公告)号：EP2445962B1

公开(公告)日：2013-06-05

申请号：EP10727722.0

申请日：2010-06-23

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  CIARAFONI, Marco ,  PANTALEONI, Roberto ,  FERRARO, Angelo

IPC: C08L23/10 ,  B29C45/00 ,  C08J5/18

CPC classification number: C08J5/18 ,  C08J2323/10 ,  C08L23/0807 ,  C08L23/0815 ,  C08L23/10 ,  C08L2666/06

公开(公告)号：EP2501727A1

公开(公告)日：2012-09-26

申请号：EP10782232.2

申请日：2010-11-15

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COLLINA, Gianni ,  CIARAFONI, Marco ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  GALVAN, Monica ,  MORINI, Giampiero ,  PANTALEONI, Roberto ,  PATER, Joachim T.M. ,  PIEMONTESI, Fabrizio ,  VERROCCHIO, Francesca

IPC: C08F10/06

CPC classification number: C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F2/001 ,  C08F4/6494 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/05

Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90°C; (ii) polymerizing propylene in the optional presence of ethylene and/or C
4 -C
10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25°C and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with α-olefins CH
2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer. An increased reactivity in the last step is observed.

公开(公告)号：EP2367670A1

公开(公告)日：2011-09-28

申请号：EP09801458.2

申请日：2009-12-24

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： CAVALIERI, Claudio ,  GALVAN, Monica ,  BECCARINI, Enrico

IPC: B29C47/00 ,  C08L23/14

CPC classification number: C08L23/14 ,  B29C47/0004 ,  B29C47/0023 ,  B29K2023/06 ,  B29K2023/12 ,  C08L23/0815 ,  C08L23/142 ,  C08L23/16 ,  C08L2203/18 ,  C08L2207/02 ,  C08L2666/06

Abstract: Articles, particularly pressure pipes, having high strength as well as high stiffness and very good impact resistance even at low temperatures can be obtained by using a heterophasic polyolefϊn composition comprising (percent by weight) 70-90% of a random copolymer of propylene with 0.5-6% of 1-hexene, and 10-30% of a polymer of ethylene with a C
3 -C
10 α- olefϊn and optionally a diene, wherein the polymer of ethylene has an ethylene content higher than 45% and an intrinsic viscosity [η] value from 3 to 5 dl/g. A particular advantage of the present invention is that articles comprising the above heterophasic polyolefϊn composition show a low ductile to brittle transition temperature (DBTT).

公开(公告)号：EP4453087A1

公开(公告)日：2024-10-30

申请号：EP22830821.9

申请日：2022-12-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： CAVALIERI, Claudio ,  GALVAN, Monica

IPC: C08L23/10

公开(公告)号：EP4139400A1

公开(公告)日：2023-03-01

申请号：EP21718599.0

申请日：2021-04-19

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  CAVALIERI, Claudio ,  BIONDINI, Gisella ,  BAUDIER, Vincent

IPC: C08L95/00 ,  C08L23/06 ,  C08L23/12 ,  C08L23/16 ,  C08L23/18 ,  C08L23/20 ,  E01C7/18 ,  E01C7/30

公开(公告)号：EP4139399A1

公开(公告)日：2023-03-01

申请号：EP21718598.2

申请日：2021-04-19

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  CAVALIERI, Claudio ,  BIONDINI, Gisella ,  BAUDIER, Vincent

IPC: C08L95/00 ,  C08L23/06 ,  C08L23/12 ,  C08L23/18 ,  C08L23/20 ,  E01C7/18 ,  E01C7/30

公开(公告)号：EP4139398A1

公开(公告)日：2023-03-01

申请号：EP21717484.6

申请日：2021-04-15

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GALVAN, Monica ,  CAVALIERI, Claudio ,  BIONDINI, Gisella ,  BAUDIER, Vincent

IPC: C08L95/00 ,  C08L23/06 ,  C08L23/12 ,  C08L23/18 ,  C08L23/20 ,  E01C7/18 ,  E01C7/30