Abstract:
Disclosed is an ungelled resin composition comprising a compound having at least one group containing a silicon atom selected from: ##STR1## wherein Q represents the residue from an organic polyol selected from the group consisting of (1) simple diols, triols and higher hydric alcohols, (2) polyester polyols, (3) polyether polyols, (4) amide-containing polyols, (5) epoxy polyols and (6) polyhydric polyvinyl alcohols, and eachR independently is selected from the group of moieties consisting of hydrogen, and a C.sub.1 -C.sub.10 group joined to Si through an Si-C linkage, andY represents an easily hydrolyzable group.The ungelled resin composition contains an amount of easily hydrolyzable Y moieties directly bonded to silicon atoms such that the ratio of the number of grams of the ungelled resin composition to equivalents of easily hydrolyzable Y moieties in the ungelled resin composition is in a range of from 40 to 667. Preferred resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing an ungelled resin composition of the invention. Preferred coating compositions containing an ungelled resin composition of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C within 3 hours.
Abstract:
An anticorrosive coating composition comprising (i) an aqueous medium, and dispersed therein, (ii) a water-soluble, film-forming and crosslinkable resin having a hydroxyl group and a proton-free onium salt radical and (iii) a chelate compound of titanium or zirconium.
Abstract:
Thermosetting powder coatings comprising reactive polymers containing reactive carboxyl, hydroxyl, and/or amide groups and adapted to be cross-linked with aminoplast resins are substantially improved by the inclusion of at least about 0.25% by weight of a heat curing catalyst. The catalyst is an amine salt of cyclohexyl sulfamic acid.
Abstract:
1,084,071. Artificial teeth. DOW CORNING CORPORATION. Feb. 11, 1965 [April 27, 1964], No. 6029/65. Heading A5R. [Also in Divisions B2, B5 and C3] Thermoplastic resins (including thermoplastic cellulose derivatives) are bonded to siliceous materials, such as glass sheets or fabrics, asbestos, ceramics, or silicone elastomers, or to metals such as aluminium or steel, or metal oxides, by bringing the components together after having rendered the surface of one of them plastic, as by heating or applying a solvent, and after applying to one component a polymeric organo-silicon material having per molecule at least one silyl group at least one silicon atom being attached to oxygen, a hydrolysable group, a hydroxyl group or a hydrocarbon or halohydrocarbon radical of less than 10C atoms, the polymer having a molecular weight of at least 2000, preferably 10-20000, and containing at least three siliconbonded non-halogen hydrolysable or hydroxyl groups per molecule, the polymeric material being a graft polymer of the organo-silicon group with the, or a, thermoplastic resin or polyurethane, and being applied as such, or in a volatile solvent, or in aqueous solution or emulsion. The themoplastic component may be applied as a preformed layer, as an impregnant for a fabric layer or in solution as a coating. In a modification the polymeric organo-silicon material, in solution together with the thermoplastic resin, may be admixed with the siliceous component, e.g. chopped glass fibre, to form a moulding composition Examples of thermoplastic resins usable are polythene, polypropylene, polybutylene, polyisobutylene, polystyrene, p.v.c., polyvinylidene, chloride, P.T.F.E., polytrifluoropropene, polyvinyl acetate or acrylonitrile, polyacrylates and methacrylates, polyethyleneterephthalate, poly- 1,4-butane diol isophthalate, polyamides, polycarbonates, and polyformaldehyde; cellulose acetate and ethyl cellulose are included. The silicon-bonded hydrolysable groups in the polymeric organo-silicon material may be any groups replaceable by water to form Si-OH groups, e.g. alkoxy, acyloxy, or cyano or isocyano groups. Reference is made to the bonding by the method of the invention, of porcelain teeth to thermoplastic dentures and of a liner of room temperature-vulcanizing silicon elastomer to the surface of such dentures.
Abstract:
Provided is an aqueous dispersion of colored particles suitable for colorants for writing instrument inks, inkjet inks, painting materials, aqueous coatings, and the like. The aqueous dispersion of colored particles includes a polymer having at least a unit of a monomer derived from a dye having a polymerizable unsaturated group. The monomer derived from the dye is preferably derived from the compound represented by General Formula (1) below:
where Dye represents a dye residue, R1 represents a hydrogen atom or a methyl group,
Y2 represents —O— or —NR10—, where R10 represents a hydrogen atom or an alkyl group,
A1 represents an alkylene group which is unsubstituted or substituted by at least one group selected from —OCO—, —COO—, —NHCONH—, and the like in the chain thereof and/or at the terminal thereof, and/or a hydroxy group.
Abstract:
Described herein is a coated building panel having a body and a surface coating atop the body, the surface coating comprising inorganic pigment and a polymeric dispersant comprising a polymer backbone and pendant side chains extending from the polymer backbone; wherein the surface coating comprises a liquid carrier in an amount less than about 1 wt. % based on the total weight of the surface coating.
Abstract:
A composition for film formation includes a polymer and a solvent. The polymer includes a first repeating unit, a second repeating unit, a third repeating unit, and a structural unit on at least one end of a main chain of the polymer. The first repeating unit includes a crosslinkable group. The second repeating unit differs from the first repeating unit. The third repeating unit differs from the first repeating unit and has higher polarity than polarity of the second repeating unit. The structural unit includes an interacting group capable of interacting with Si—OH, Si—H or Si—N.
Abstract:
The present invention provides a coating composition which cures at low temperatures to form a cured film having high solvent resistance. The present invention provides a low-temperature-curable coating composition which comprises (A) a film-forming polymer having a hydrogen-donating functional group that has a heteroatom which bonds covalently to a hydrogen atom, (B) a film-forming polymer having a specific hydrogen-accepting functional group that has a heteroatom to which no hydrogen atom bonds covalently, and (C) a non-basic volatile solvent selected from the group consisting of a non-basic volatile solvent (C-1) having, in the molecule, both a heteroatom that bonds covalently to a hydrogen atom and a heteroatom that does not bond covalently to a hydrogen atom; a mixture of a non-basic volatile solvent (C-2) having, in the molecule, a heteroatom which bonds covalently to a hydrogen atom and a non-basic volatile solvent (C-3) having, in the molecule, a heteroatom to which no hydrogen atom bonds covalently; and combinations thereof.
Abstract:
A photocurable composition contains at least one ultraviolet absorber represented by Formula (1), and a hard coating agent including the photocurable composition. wherein R1, R2 and R3 may be the same as or different from each other and represent a branched or linear alkyl group with 1-20 carbon atoms and is substituted with a (meth)acryloyloxy group; the alkyl group may be substituted with a hydroxyl group, an alkoxy group having 1-8 carbon atoms, or an acyloxy group having 1-8 carbon atoms; the alkyl group may be interrupted by an oxygen atom, a sulfur atom, a carbonyl group, an ester group, an amide group, or an imide group; and R4, R5 and R6 may be the same as or different from each other and represent a hydrogen atom, a halogen atom, a hydroxyl group, an alkyl group having 1-12 carbon atoms, or an alkoxy group having 1-12 carbon atoms.
Abstract:
The present invention provides a composition which is able to form a layer having excellent surface slip property and friction durability in addition to water-repellency, oil-repellency and antifouling property. The present invention provides a surface-treatment composition comprising (A) at least one fluorine-containing polymer having a curable moiety, and (B) at least one silicon-containing polymer having a curable moiety.