Abstract:
Crystalline aluminates of the formula: I. (LiAx)y.2Al(OH)3.nH2O II. Li(R)v_r.2Al(OH)3.nH2O, or III. Mm(R)v_r.(D)w_z2Al(OH)3.nH2O wherein A is one or more anions and/or negative-valence radicals or mixtures thereof; wherein, in formula I, x is a quantity of A ions or radicals sufficient to substantially satisfy the valence requirements of Li; wherein n is zero or the number of waters of hydration; wherein y is a numerical value at least sufficient to maintain the crystalline structure; wherein R is a monocarboxylic acid or dicarboxylic acid of C6 C22, including those which are OH substituted; wherein r is greater than zero and represents the number of R ions in the molecule; wherein v is the valence of R, being monovalent or divalent; wherein M is divalent Zn or Ca cations; wherein D represents inorganic anions of valence 1-3, represented by w; wherein z is equal to or greater than zero and represents the number of D anions; wherein, in formula II, vr represents an amount of R anions to substantially satisfy the valence requirements of Li; wherein, in formula III, r>z and (vr + wz) represents an amount of combined anions, R and A, to substantially satisfy the valence requirements of M; with m representing the number of divalent M cations and having a numerical value in the range of 1 to 4, are found to improve the coefficient of friction and antiwear properties of lubrication fluids subjected to shearing, rubbing, or grinding forces at elevated pressure. Also, useful compositions are prepared by incorporating into organic materials, crystalline lithium aluminates of formula I.
Abstract:
Crystalline aluminates of the formula: I. (LiA x ) y ·2Al(OH)₃·nH₂O wherein A is one or more anions and/or negative-valence radicals or mixtures thereof; wherein, in formula I, x is a quantity of A ions or radicals sufficient to substantially satisfy the valence requirements of Li; wherein n is zero or the number of waters of hydration; wherein y is a numerical value at least sufficient to maintain the crystalline structure; are found to improve the properties of organic materials when incorporated therein.
Abstract:
Novel compositions useful as fluid gelling agents, especially for use in subterranean applications such as drilling fluids, are prepared by reacting an aqueous dispersion of a clay, such as bentonite, with an aqueous gel of a monodispersed mixed metal layered hydroxide.
Abstract:
A lubricating grease having a high dropping point, good stability against oxidation and long life contains a thickener comprising essentially the three components: lithium soap of C 12-24 hydroxy fatty acid; lithium phosphate salt produced from phosphoric or phosphorous acid ester and dilithium borate. The amounts of hydroxy fatty acid and phosphoric or phosphorous acid ester are 3-100 parts by weight and 0.05-15 parts by weight per part by weight of boric acid respectively.
Abstract:
Crystalline aluminates of the formula: I. (LiA x ) y ·2Al(OH) 3 ·nH 2 O II. Li(R) v r 2Al(OH) 3 ·nH 2 O, or III. M m (R) v r (D) w z 2Al(OH) 3 ·nH 2 O wherein A is one or more anions and/or negative-valence radicals or mixtures thereof; wherein, in formula I, x is a quantity of A ions or radicals sufficient to substantially satisfy the valence requirements of Li; wherein n is zero or the number of waters of hydration; wherein y is a numerical value at least sufficient to maintain the crystalline structure; wherein R is a monocarboxylic acid or dicarboxylic acid of C 6 -C 22 , including those which are OH - substituted; wherein r is greater than zero and represents the number of R ions in the molecule; wherein v is the valence of R, being monovalent or divalent; wherein M is divalent Zn or Ca cations; wherein D represents inorganic anions of valence 1-3, represented by w; wherein z is equal to or greater than zero and represents the number of D anions; wherein, in formula II, vr represents an amount of R anions to substantially satisfy the valence requirements of Li; wherein, in formula III, r>z and (vr + wz) represents an amount of combined anions, R and A, to substantially satisfy the valence requirements of M; with m representing the number of divalent M cations and having a numerical value in the range of 1 to 4. are found to improve the coefficient of friction and antiwear properties of lubrication fluids subjected to shearing, rubbing, or grinding forces at elevated pressure. Also, useful compositions are prepared by incorporating into organic materials, crystalline lithium aluminates of formula 1.
Abstract:
A perfluoropolyether, a composition comprising the perfluoropolyether, a process for producing the perfluoropolyether, and a process for improving the thermostability of grease or lubricant are provided. The perfluoropolyether comprises perfluoroalkyl radical end groups in which the radical has at least 3 carbon atoms per radical and is substantially free of perfluoromethyl and perfluoroethyl end groups. The process for producing the perfluoropolyether can comprise (1) contacting a perfluoro acid halide, a C2- to C4-substituted ethyl epoxide, or a C3+ fluoroketone with a metal halide to produce an alkoxide; (2) contacting the alkoxide with either hexafluoropropylene oxide or tetrafluorooxetane to produce a second acid halide; (3) esterifying the second acid halide to an ester; (4) reducing the ester to its corresponding alcohol; (5) converting the alcohol with a base to a salt form; (6) contacting the salt form with a C3 or higher olefin to produce a fluoropolyether; and (7) fluorinating the fluoropolyether. The process for improving the thermostability of a grease or lubricant comprises combining the grease or lubricant with the composition.
Abstract:
PROBLEM TO BE SOLVED: To provide a perfluoropolyether, a composition comprising the perfluoropolyether, a process for producing the perfluoropolyether, and a process for improving the thermostability of grease or lubricant.SOLUTION: A composition comprises a perfluoropolyether, which has the formula selected from the group consisting of F(CFO)CF(CF)CFX, XCFCF(CF)O(CFO)pRO(CFO)CF(CF)CFX, XCFCFO(CFO)CF(CF)CFX, (R)(R)CFO(CFO)CF(CF)CFX, and combinations of two or more thereof (wherein X is I or Br; x is a number from 2 to about 100; z is a number from about 5 to about 100; p is a number from 2 to about 50; n is a number from 2 to about 50; a is 1 or 2; each Ris independently a monovalent Cto Cbranched or linear fluoroalkane; and Ris a divalent Cto Cbranched or linear fluoroalkane).
Abstract translation:要解决的问题:提供全氟聚醚,包含全氟聚醚的组合物,制备全氟聚醚的方法,以及改善润滑脂或润滑剂的热稳定性的方法。 解决方案:组合物包含全氟聚醚,其具有选自F(C 3 SB> F 6 SB > O POS> CF(CF 3 SB>)CF 2 X,XCF CF(CF 3 SB>)O(C 3 SB> F 6 SB> O)pR f SB> 2 SP> O(C 3 SB> F 6 SB> O) n SB> CF(CF 3 SB> )CF 2 SB> X,XCF 2 SB> O(C 3 SB> O) X SB> CF(CF 3 SB>)CF 2 SB> X,(R f SB> 1 SP >)(R f SB> 1 SP>)CFO(C 3 SB> F 3 SB>)CF 2 X,以及其两种或更多种的组合(其中X为I或Br; x为2至约100的数; z为数 约5至约100; p是从2到约50的数字; n是从2到约50的数; a是1或2; 每个R f SB> 1 SP>独立地是C 1 SB> 支链或直链氟代烷烃; 并且R f SB> 2 SP>是C 1 SB> =支链或直链的氟烷烃)。 版权所有(C)2012,JPO&INPIT
Abstract:
A grease-like silicone composition comprising at least (A) a liquid organopolysiloxane comprising 80 to 96.5 mol% of siloxane units represented by the formula R2SiO2/2, 1.0 to 10.0 mol% of siloxane units represented by the formula RSiO3/2, and 0.25 to 10.0 mol% of siloxane units represented by the formula R3SiO1/2 (in the formulas, R stands for identical or different monovalent hydrocarbon groups) and (B) a thickening agent is disclosed. A grease-like silicone composition can be provided that is capable of containing a large amount of thickening agents and possesses superior heat resistance.