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    Crystalline aluminates as lubricant additives
    142.
    发明公开
    Crystalline aluminates as lubricant additives 失效
    Kristalline Aluminate als Schmiermittelzusatz。

    公开(公告)号：EP0169357A2

    公开(公告)日：1986-01-29

    申请号：EP85107141.5

    申请日：1985-06-10

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： Kar, Kishore K. ,  Burba III, John L. ,  Bauman, William C.

    IPC: C10M125/00 ,  C10M129/38 ,  C10M159/18

    CPC classification number: C07C53/16 ,  B82Y30/00 ,  C01F7/002 ,  C01P2002/22 ,  C01P2002/78 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/60 ,  C07C53/126 ,  C07C57/04 ,  C07C59/01 ,  C10M113/08 ,  C10M117/02 ,  C10M121/02 ,  C10M125/00 ,  C10M129/40 ,  C10M159/18 ,  C10M2201/0606 ,  C10M2201/0616 ,  C10M2201/0626 ,  C10M2201/063 ,  C10M2201/0656 ,  C10M2201/0666 ,  C10M2201/0806 ,  C10M2201/0856 ,  C10M2201/0866 ,  C10M2201/0876 ,  C10M2201/1013 ,  C10M2201/1026 ,  C10M2207/1225 ,  C10M2207/125 ,  C10M2207/1265 ,  C10M2207/129 ,  C10M2207/166 ,  C10M2207/186 ,  C10M2207/206 ,  C10M2207/246 ,  C10M2227/09 ,  C10N2210/01 ,  C10N2210/03

    Abstract: Crystalline aluminates of the formula:

    I. (LiA x ) y ·2Al(OH) 3 ·nH 2 O
    II. Li(R) v r 2Al(OH) 3 ·nH 2 O, or
    III. M m (R) v r (D) w z 2Al(OH) 3 ·nH 2 O

    wherein A is one or more anions and/or negative-valence radicals or mixtures thereof;
    wherein, in formula I, x is a quantity of A ions or radicals sufficient to substantially satisfy the valence requirements of Li;
    wherein n is zero or the number of waters of hydration;
    wherein y is a numerical value at least sufficient to maintain the crystalline structure;
    wherein R is a monocarboxylic acid or dicarboxylic acid of C 6 -C 22 , including those which are OH - substituted;
    wherein r is greater than zero and represents the number of R ions in the molecule;
    wherein v is the valence of R, being monovalent or divalent;
    wherein M is divalent Zn or Ca cations;
    wherein D represents inorganic anions of valence 1-3, represented by w;
    wherein z is equal to or greater than zero and represents the number of D anions;
    wherein, in formula II, vr represents an amount of R anions to substantially satisfy the valence requirements of Li;
    wherein, in formula III, r>z and (vr + wz) represents an amount of combined anions, R and A, to substantially satisfy the valence requirements of M;
    with m representing the number of divalent M cations and having a numerical value in the range of 1 to 4.
    are found to improve the coefficient of friction and antiwear properties of lubrication fluids subjected to shearing, rubbing, or grinding forces at elevated pressure. Also, useful compositions are prepared by incorporating into organic materials, crystalline lithium aluminates of formula 1.

    Abstract translation: 结晶铝酸盐，其结构式如下：I.（LiAx）y.2Al（OH）3·nH2O II。 Li（R）v_r.2Al（OH）3·nH 2 O或III。 （D）w_z2Al（OH）3·nH 2 O其中A是一个或多个阴离子和/或负价键或其混合物; 其中，在式I中，x是足以基本上满足Li的化合价要求的A离子或自由基的量; 其中n为0或水合水的数量; 其中y是至少足以保持晶体结构的数值; 其中R是C 6 -C 22的单羧酸或二羧酸，包括被OH取代的那些; 其中r大于零并且表示分子中的R离子的数目; 其中v是R的价数，是一价或二价; 其中M是二价Zn或Ca阳离子; 其中D表示以w表示的价数1-3的无机阴离子; 其中z等于或大于零并且表示D阴离子的数目; 其中，在式II中，vr表示基本上满足Li的化合价要求的R阴离子的量; 其中，在式III中，r> z和（vr + wz）表示组合的阴离子R和A的量，以基本上满足M的化合价要求; 其中m表示二价M阳离子的数目并且具有在1至4范围内的数值，可以改善在升高的压力下经受剪切，摩擦或研磨力的润滑流体的摩擦系数和抗磨损性能。 而且，有用的组合物通过将有机材料掺入到式I的结晶的铝酸锂中来制备。

    DEFOAMING AGENT COMPOSITION FOR LUBRICATING OIL AND METHOD OF DEFOAMING USING THIS
    149.
    发明公开
    DEFOAMING AGENT COMPOSITION FOR LUBRICATING OIL AND METHOD OF DEFOAMING USING THIS 审中-公开
    用于润滑油的消泡剂组合物和使用该方法进行消泡的方法

    公开(公告)号：EP2681297A1

    公开(公告)日：2014-01-08

    申请号：EP12710462.8

    申请日：2012-03-02

    Applicant: Shell Internationale Research Maatschappij B.V.

    Inventor： KAMATA, Kumiko ,  TAZAKI, Hiroyuki

    IPC: C10M169/02 ,  C10N30/18 ,  C10N50/10

    CPC classification number: C10M169/02 ,  C10M2201/0856 ,  C10M2213/0606 ,  C10M2229/025 ,  C10N2230/18 ,  C10N2240/04 ,  C10N2250/10

    Abstract: The present invention provides a defoaming agent composition in gel form, of number 1 NLGI grade or harder, for application to the inside wall of a container, being a composition for defoaming bubbles generated from lubricating oil present within a container. The present invention further provides a method of defoaming lubricating oil characterised in that it includes a step of applying a defoaming agent composition in gel form, of number 1 NLGI grade or harder, to the inside wall of a container for lubricating oil and characterised in that this step is a step in which said defoaming agent composition is applied to the inside wall face at or above the oil surface of the lubricating oil, or higher than this.

    Abstract translation: 本发明提供了一种消泡剂组合物，其为1号NLGI级或更硬的凝胶形式，用于施加到容器的内壁，该组合物是用于消除容器内存在的润滑油产生的气泡的组合物。 本发明进一步提供一种消泡润滑油的方法，其特征在于它包括将1号NLGI级或更硬的凝胶形式的消泡剂组合物施加到用于润滑油的容器的内壁上的步骤，其特征在于： 本步骤是将上述消泡剂组合物涂布在润滑油的油面以上的内壁面上，或者比其更高的步骤。

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