A METHOD FOR ANION-EXCHANGE ADSORPTION AND ANION-EXCHANGERS
    143.
    发明申请
    A METHOD FOR ANION-EXCHANGE ADSORPTION AND ANION-EXCHANGERS 审中-公开
    阴离子交换吸附和阴离子交换剂的方法

    公开(公告)号:WO0138227A3

    公开(公告)日:2001-11-15

    申请号:PCT/EP0011605

    申请日:2000-11-22

    CPC classification number: B01J41/20 B01D15/327 B01J41/09 C02F1/42

    Abstract: A method for the removal of a substance carrying a negative charge and being present in an aqueous liquid (I). The method comprises the steps of: (i) contacting the liquid with a matrix carrying a plurality of ligands comprising a positively charged structure and a hydrophobic structure, and (ii) desorbing the substance. The characterizing feature is that (I) each of said ligands together with a spacer has the formula: -- SP---[Ar-R1-N (R2R3R4)] where (A) [Ar-R1-N (R2R3R4)] represents a ligand a) Ar is an aromatic ring, b) R1 is [(L)nR'1]m where n and m are integers selected amongst zero or 1; L is amino nitrogen, ether oxygen or thioether sulphur; R'1 is a linker selected among 1) hydrocarbon groups; 2) -C(=NH)-; c) R2-4 are selected among hydrogen and alkyls; (B) SP is a spacer providing a carbon or a heteroatom directly attached to Ar-R1-N (R2R3R4); (C) --- represents that SP replaces a hydrogen in (Ar-R1-N (R2R3R4); (D) -- represents binding to the matrix; and (II) desorption. There is also described (a) anion-exchangers having high breakthrough capacities, (b) a screening method and (c) a desalting protocol.

    Abstract translation: 一种用于去除携带负电荷并存在于水性液体(I)中的物质的方法。 该方法包括以下步骤:(i)使液体与承载包含带正电结构和疏水结构的多个配体的基质接触,和(ii)解吸该物质。 其特征在于,(I)每个所述配位体与间隔基一起具有下式:-SP --- [Ar-R 1 -N +(R 2 R 3 R 4)]其中(A)[Ar-R 1 -N +(R2R3R4)]表示配体a)Ar是芳香环,b)R1是[(L)nR'1] m,其中n和m是选自零或1的整数; L为氨基氮,醚氧或硫醚硫; R'1是选自1)烃基的连接体; 2)-C(= NH) - ; c)R2-4选自氢和烷基; (B)SP是提供直接与Ar-R 1 -N +(R 2 R 3 R 4)连接的碳或杂原子的间隔基; (C)---表示SP替代(Ar-R1-N +(R2R3R4)中的氢;(D) - 表示与基质的结合;和(II)解吸,还描述了(a) 具有高突破能力的阴离子交换剂,(b)筛选方法和(c)脱盐方案。

    Ion-exchange composition employing resin attachment to dispersant and
method for forming the same
    149.
    发明授权
    Ion-exchange composition employing resin attachment to dispersant and method for forming the same 失效
    使用树脂附着于分散剂的离子交换组合物及其形成方法

    公开(公告)号:US5324752A

    公开(公告)日:1994-06-28

    申请号:US518293

    申请日:1990-05-03

    CPC classification number: B01J20/3221 B01J39/26 B01J41/20 B01J47/006

    Abstract: In accordance with the present invention, an ion-exchange composition has been formed which comprises synthetic resin support particles, dispersant capable of suspending the support particles in an aqueous medium to inhibit or prevent agglomeration, and fine synthetic resin layering particles. In a preferred embodiment, the complex can be formed by contacting a suitable dispersant with monomer in an aqueous solution in which the monomer is insoluble. Under suitable conditions for suspension polymerization, the monomer will polymerize to form resin support particles having dispersant irreversibly attached to those particles. The dispersant is irreversibly attached to the synthetic resin support particles, either by covalent bonding or permanent physical entanglement. The dispersant is also attached to the fine layering particles, either by covalent bonding or electrostatic forces. The result is formation of a support particle-dispersant-layering particle complex.

    Abstract translation: 根据本发明,已经形成了一种离子交换组合物,其包括合成树脂载体颗粒,能够将载体颗粒悬浮在水性介质中以抑制或防止附聚的分散剂和细小的合成树脂层压颗粒。 在优选的实施方案中,络合物可以通过使合适的分散剂与单体在单体不溶的水溶液中接触来形成。 在合适的悬浮聚合条件下,单体将聚合形成具有分散剂不可逆地连接到这些颗粒上的树脂载体颗粒。 分散剂通过共价键或永久性物理缠结不可逆地附着在合成树脂载体颗粒上。 分散剂也通过共价键或静电力连接到细分层颗粒上。 结果是形成载体颗粒 - 分散剂分层颗粒复合物。

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