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    A METHOD FOR PROVIDING A PRETREATED FILLER COMPOSITION AND ITS USE IN PAPER AND BOARD MANUFACTURING
    164.
    发明申请
    A METHOD FOR PROVIDING A PRETREATED FILLER COMPOSITION AND ITS USE IN PAPER AND BOARD MANUFACTURING 审中-公开
    提供预浸填料组合物的方法及其在纸和纸板制造中的应用

    公开(公告)号：US20160319487A1

    公开(公告)日：2016-11-03

    申请号：US15108670

    申请日：2014-12-17

    Applicant: KEMIRA OYJ ,  UPM-KYMMENE CORPORATION ,  STORA ENSO OYJ

    Inventor： Matti HIETANIEMI ,  Mikko VIRTANEN ,  Katariina TORVINEN ,  Terhi SAARI ,  Hellen ERKKI

    IPC: D21H17/67 ,  D21H21/18 ,  D21H17/34 ,  D21H11/18 ,  D21H17/37

    CPC classification number: D21H17/675 ,  D21H11/18 ,  D21H17/34 ,  D21H17/375 ,  D21H17/69 ,  D21H21/18

    Abstract: The present invention relates to a method for providing a pretreated filler composition for use in paper and board manufacturing including the steps of: a) providing a filler comprising precipitated calcium carbonate, said filler being in the form of a slurry comprising no additives; b) providing at least one polymer selected from polyvinylamine or polyacrylic amide, said polymer having a charge density of an absolute value of at most 4 meq/g determined at pH 7; c) combining said at least one polymer of step b) with the filler of step a); d) providing a slurry of nanofibrillar cellulose; e) combining said nanofibrillar cellulose slurry with the formed combination of step c) and forming a pretreated filler composition comprising aggregates. Further it also relates to a pretreated filler composition prepared therefrom, and its use in stocks, paper and paper board.

    Abstract translation: 本发明涉及一种用于提供用于纸和纸板制造的预处理填料组合物的方法，包括以下步骤：a）提供包含沉淀碳酸钙的填料，所述填料为不含添加剂的浆料形式; b）提供至少一种选自聚乙烯胺或聚丙烯酰胺的聚合物，所述聚合物的电荷密度在pH7下测定为绝对值至多4meq / g; c）将步骤b）的所述至少一种聚合物与步骤a）的填料结合; d）提供纳米纤维素纤维素浆料; e）将所述纳米纤维素纤维素浆料与所形成的步骤c）的组合结合并形成包含聚集体的预处理填料组合物。 此外，它还涉及由其制备的预处理填料组合物，以及其在原料，纸和纸板中的用途。

    METHODS OF DEOXYGENATING BIO-BASED MATERIAL AND PRODUCTION OF BIO-BASED TEREPHTALIC ACID AND OLEFINIC MONOMERS
    166.
    发明申请
    METHODS OF DEOXYGENATING BIO-BASED MATERIAL AND PRODUCTION OF BIO-BASED TEREPHTALIC ACID AND OLEFINIC MONOMERS 审中-公开
    脱氧生物材料的方法和生产基于生物的过硫酸和烯烃单体的方法

    公开(公告)号：US20160046873A1

    公开(公告)日：2016-02-18

    申请号：US14782879

    申请日：2014-04-08

    Applicant: STORA ENSO OYJ

    Inventor： Jari RÄSÄNEN ,  Ali HARLIN ,  Olli AALTONEN ,  Juha LINNEKOSKI ,  Jinto ANTHONYKUTTY

    IPC: C10G3/00 ,  C07C4/06 ,  C07C51/16

    CPC classification number: C10G3/50 ,  C07C4/06 ,  C07C51/16 ,  C07C51/265 ,  C10G3/46 ,  C10G3/49 ,  C10G9/36 ,  C10G2300/1014 ,  Y02P30/20 ,  C07C63/06

    Abstract: The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a Ni—Mo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.

    Abstract translation: 本发明涉及一种使妥尔油沥青脱氧，产生脂族和芳族烃的方法。 本发明甚至包括通过蒸汽裂化将脂族物转化为可聚合烯烃，并且通过氧合将需要的芳烃转化为可聚合的对苯二甲酸，并且根据需要进行重排。 单体可用于生产部分或完全生物来源的聚合物。 根据本发明，首先将妥尔油沥青加热以将其转化成液体，然后将其进料到催化剂床中并用氢催化脱氧。 脱氧催化剂优选为Ni-Mo催化剂，此外，可以使用裂化催化剂，例如酸性沸石催化剂。 将脱氧产物流冷却，以获得液体，蒸馏用于分离用于生产各单体和最终聚合物的脂族和芳族烃。

    PLY FOR A BOARD FROM AN IN-LINE PRODUCTION PROCESS
    167.
    发明申请
    PLY FOR A BOARD FROM AN IN-LINE PRODUCTION PROCESS 有权
    从一个在线生产过程的板子

    公开(公告)号：US20150315748A1

    公开(公告)日：2015-11-05

    申请号：US14441257

    申请日：2013-11-06

    Applicant: Stora Enso Oyj ,  Wetend Technologies Ltd

    Inventor： Olavi Imppola ,  Jouni Matula ,  Jussi Matula ,  Karri Tahkola ,  Matti Väkeväinen ,  Isto Heiskanen ,  Jari Räsänen

    IPC: D21H17/67

    CPC classification number: D21H17/675 ,  D21H11/18 ,  D21H17/25 ,  D21H17/67 ,  D21H17/70

    Abstract: A ply for a paper and paperboard made from a ply substrate material, wherein the ply comprises a hybrid material, in an amount of 1-25 wt-% of the ply, wherein the hybrid material is introduced into a target suspension of the short circulation of a fibrous web forming process of a fibrous web machine, in an in-line process, wherein said target suspension forms the ply substrate material, and the hybrid material comprises an alkaline earth carbonate precipitated onto or into fibers or fibrils of a nanofibrillated polysaccharide.

    Abstract translation: 一种用于由层状基材材料制成的纸和纸板的层，其中所述帘布层包含以所述帘布层的1-25重量％的量的混合材料，其中所述混合材料被引入所述短循环的目标悬浮液 在线方法中，所述目标悬浮液形成层状基底材料，并且所述混合材料包含沉淀在纳米纤维化多糖的纤维或原纤维上的碱土金属碳酸盐。

    METHODS OF DEOXYGENATION OF TALL OIL AND PRODUCTION OF POLYMERIZABLE MONOMERS THEREFROM
    168.
    发明申请
    METHODS OF DEOXYGENATION OF TALL OIL AND PRODUCTION OF POLYMERIZABLE MONOMERS THEREFROM 审中-公开
    去氧化方法和生产可聚合单体的方法

    公开(公告)号：US20150175500A1

    公开(公告)日：2015-06-25

    申请号：US14394232

    申请日：2013-04-12

    Applicant: Stora Enso Oyj

    Inventor： Ali Harlin ,  Olli Aaltonen ,  Antero Laitinen ,  Jari Räsänen ,  Outi Kylliäinen

    IPC: C07C1/24 ,  C07C4/04

    CPC classification number: C07C1/24 ,  C07C4/04 ,  C07C2527/043 ,  C10G3/42 ,  C10G3/46 ,  C10G3/50 ,  C10G9/36 ,  C10G2300/1011 ,  C10G2400/20 ,  Y02P30/20

    Abstract: A method of deoxygenation of tall oil as well as methods for the production of aliphatic hydrocarbons and polymerizable monomers from tall oil. Sulphurous crude tall oil together with hydrogen gas is fed into a reactor comprising a catalyst bed. The oil is catalytically deoxygenated by hydrogen in the bed by use of a sulfided metal catalyst, e.g. a NiMoS catalyst. The flow exiting the reactor is cooled down and a hydrocarbon-bearing liquid phase is separated from a gas phase, followed by subjecting the liquid phase to distillation for removal of useless aromatic hydrocarbons and then to steam cracking to form a product containing olefins such as ethylene or propylene. By regulation of the deoxygenation temperature to be at least 270° C. but less than 360° C. the yield is rich in linear and cyclic aliphates that usefully turn to olefins in the steam cracking, while formation of napthalenes is reduced.

    Abstract translation: 妥尔油的脱氧方法以及由妥尔油生产脂族烃和可聚合单体的方法。 将硫化氢原油妥尔油与氢气一起加入到包含催化剂床的反应器中。 油通过使用硫化金属催化剂例如在床中由氢催化脱氧。 一种NiMoS催化剂。 将离开反应器的流冷却，将含烃液相与气相分离，然后使液相经蒸馏除去无用的芳烃，然后进行蒸汽裂解，形成含烯烃的产物，如乙烯 或丙烯。 通过将脱氧温度调节为至少270℃但小于360℃，产率丰富，线性和环状脂肪族有利地转化为蒸汽裂解中的烯烃，同时降低了萘的形成。

    HYDROPHOBICALLY SIZED FIBROUS WEB AND A METHOD FOR THE PREPARATION OF A SIZED WEB LAYER
    169.
    发明申请
    HYDROPHOBICALLY SIZED FIBROUS WEB AND A METHOD FOR THE PREPARATION OF A SIZED WEB LAYER 有权
    疏水尺寸纤维网和一种尺寸网层的制备方法

    公开(公告)号：US20150096700A1

    公开(公告)日：2015-04-09

    申请号：US14396634

    申请日：2013-04-25

    Applicant: STORA ENSO OYJ

    Inventor： Isto Heiskanen ,  Karita Kinnunen ,  Tuomo Hjelt

    IPC: D21H27/30 ,  D21H21/16 ,  D21H11/02 ,  D21H17/22

    CPC classification number: D21H27/30 ,  D21F11/002 ,  D21H11/02 ,  D21H11/18 ,  D21H17/17 ,  D21H17/22 ,  D21H21/16 ,  D21H21/24 ,  D21H21/56

    Abstract: A hydrophobically sized fibrous web layer, preparation of a fibrous web or a fibre-based coating, a multiplayer board product having at least a middle layer formed of said fibrous web, as well as use of a heat-sensitive surfactant for said methods and products, whereby microfibrillated cellulose (MFC) and hydrophobic size are brought to a foam with water and the heat-sensitive surfactant, the foam is supplied to a forming fabric of a paper or board machine, dewatered by suction of air through the forming fabric, and dried to a web product. Alternatively the foam may be supplied onto a premade fibrous web and dried to form a coating layer. The hydrophilic functionality of the surfactant contained in the web may be destroyed by heating. Pulp of a greater fibre length, such as CTMP, may be included, to provide improved wet and dry tensile strength for the paper and board products.

    Abstract translation: 疏水尺寸的纤维网层，纤维网或纤维基涂层的制备，至少由所述纤维网形成的中间层的多层板产品以及用于所述方法和产品的热敏表面活性剂 ，由此将微纤化纤维素（MFC）和疏水性尺寸用水和热敏表面活性剂引入泡沫中，将泡沫供应到纸或纸机的成形织物，通过成形织物的空气抽吸脱水，以及 干燥成网状产品。 或者，泡沫可以供应到预制纤维网上并干燥以形成涂层。 包含在纤维网中的表面活性剂的亲水官能度可能被加热破坏。 可以包括更大纤维长度的纸浆，例如CTMP，以为纸和纸制品提供改善的湿和干拉伸强度。

    METHOD FOR THE PREPARATION OF CELLULOSE ETHERS WITH A HIGH SOLIDS PROCESS, PRODUCT OBTAINED AND USES OF THE PRODUCT
    170.
    发明申请
    METHOD FOR THE PREPARATION OF CELLULOSE ETHERS WITH A HIGH SOLIDS PROCESS, PRODUCT OBTAINED AND USES OF THE PRODUCT 审中-公开
    用高固体工艺制备纤维素的方法，产品获得和使用产品

    公开(公告)号：US20150094464A1

    公开(公告)日：2015-04-02

    申请号：US14390519

    申请日：2013-04-04

    Applicant: Stora Enso OYJ

    Inventor： Heidi Saxell ,  Isto Heiskanen ,  Lars Axrup ,  Cecilia Land Hensdal ,  Veikko Jokela

    IPC: C08B11/12

    CPC classification number: C08B11/12 ,  C08B1/08

    Abstract: The present invention provides a method for production of cellulose ethers in a high solids process substantially without use of organic solvents as reaction and/or washing medium. In the method of the invention the first alkalization step is carried out by using high solids content cellulose pulp and solid sodium hydroxide. This is followed by an etherification step where the solids content is preferably further increased and the use of solid etherification reactant is preferred. As no organic solvents are used as reaction media the invented method enables production of cellulose ethers directly from never dried pulp with significant savings in energy and investment costs. The method is especially suitable for the production of carboxymethyl cellulose sodium salt (CMC) with low degree of substitution (DS

    Abstract translation: 本发明提供了一种基本上不使用有机溶剂作为反应和/或洗涤介质的高固含量方法生产纤维素醚的方法。 在本发明的方法中，通过使用高固含量的纤维素纸浆和固体氢氧化钠来进行第一碱化步骤。 之后是醚化步骤，其中固体含量优选进一步增加，并且优选使用固体醚化反应物。 由于不使用有机溶剂作为反应介质，本发明的方法可以直接从未干燥的纸浆生产纤维素醚，从而显着节省能源和投资成本。 该方法特别适用于低取代度（DS <0.3）的羧甲基纤维素钠盐（CMC）的生产。 所得到的无水或低水溶性羧甲基化纤维素纤维的使用适用于例如用于生产微纤化纤维素。

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