Abstract:
Multi-layered golf balls having a dual-layered core and cover of at least one layer are provided. The dual-core construction includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An outer core layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. In one version, the foamed outer core layer is made of a relatively soft foam composition having low flex modulus and density. The foamed outer core layer may specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. A cover may be disposed about the core structure. For example, an inner cover made of ethylene acid copolymer ionomer and outer cover made of polyurethane may be used.
Abstract:
Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.
Abstract:
Multi-layered golf balls having a core made of a foamed composition, preferably polyurethane foam, are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The outer core layer may be made from a non-foamed thermoset material such as polybutadiene rubber. The ball further includes an inner cover, preferably made from an ionomer composition comprising an O/X-type acid copolymer, wherein O is α-olefin, and X is a C3-C8 α,β-ethylenically unsaturated carboxylic acid. The outer cover may be made from a non-foamed thermoset or thermoplastic material such as polyurethane. Preferably, the specific gravity of the inner cover is greater than the specific gravity of the outer core, which is greater than the specific gravity of the inner core. The finished ball has good distance and low-spin properties.
Abstract:
Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.
Abstract:
Multi-layered, golf balls having a core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition comprising secondary blowing agents that are activated by heat is used to form the foam center. Non-foamed thermoset materials such as polybutadiene rubber may be used to form the outer core layer. The core layers have different hardness gradients and specific gravity values. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.
Abstract:
Multi-layered, golf balls having a core made of a particle-based polyurethane foam composition are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The surrounding outer core layer is preferably made from a foamed composition. In one embodiment, pre-expanded thermoplastic polyurethane foam beads containing a blowing agent are used to form the foam center and outer core. In another embodiment, pre-formed polyurethane foam particles are used in both core layers. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.
Abstract:
Golf ball comprising at least one layer having a Shore D material hardness of from about 10 to about 55 and consisting of a millable polyurethane rubber composition comprising rubber consisting of: at least one polyether-based millable polyurethane rubber; at least one polyester-based millable polyurethane rubber; at least one polycaprolactone-based millable polyurethane rubber; or combinations thereof; wherein the millable polyurethane rubber composition is vulcanized. The rubber may be mixed/compounded with additional non-rubber ingredients such as at least one cross linking agent, peroxide initiator, filler, antioxidant, processing agent, light stabilizer, colorant, adhesion promotor, isocyanate and/or polyol, or combinations thereof. The at least one layer may be a cover layer, with a second layer, formed from at least one of a thermoset urethane or a thermoplastic material, being adjacent to an inner surface of the cover layer and meanwhile disposed about a polybutadiene-containing core. The rubber may be peroxide and/or sulfur cured.
Abstract:
A golf ball comprising a layer formed from at least one of a thermoset material or a thermoplastic material throughout; the layer having a treated region and an untreated region; the treated region extending inward from an outer surface of the layer and comprising a UV resistance composition; and the untreated region not comprising the UV resistance composition. For example, the treated region may be infused with the UV resistance composition. The layer may be a cover or even an inner golf ball layer, which can sometimes become exposed during play. The UV resistance composition may be formed from a mixture of an ultraviolet light absorber (UVA) and a solvent, the UVA being selected from benzotriazole type stabilizers, hindered amine type stabilizers, phenolic type stabilizers, triazines, or combinations thereof, and the solvent comprising at least one of acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, or butyl acetate.
Abstract:
A golf ball comprising: a core; a casing layer surrounding the core; and a cover layer surrounding the casing layer and being formed from a cover composition that is produced by a reaction of a prepolymer and a chain extender, wherein the prepolymer is formed from the reaction product of: (i) an isocyanate comprising an allophanate (“ICA”) and having an average NCO functionality in the range of 1.9 to 2.8 and (ii) a polyol-containing component or an amine-containing component or a blend thereof; and wherein the chain-extender is selected from the group consisting of amine-terminated chain-extenders, hydroxyl-terminated chain-extenders, and mixtures thereof. The ICA may comprise a reaction product of hexamethylene diisocyanate (HDI), at least one monoalcohol, and a bismuth-containing catalyst. The ICA may have an average equivalent weight of from about 200 to about 350; and the prepolymer may have an average equivalent weight of from about 420 to about 840. The cover has a thickness of at least about 0.010 in. and a flexural modulus of about 10,000 psi or greater.
Abstract:
Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer ionomer resin; and the outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. In one preferred embodiment, the inner core has a positive hardness gradient, the intermediate core has a positive hardness gradient, and the outer core has a zero or negative hardness gradient. The core structure and resulting ball have relatively good resiliency.