Abstract:
The invention relates to a continuous method for producing alkyl nitrites and alkyl dinitrites. According to said method, (i) an alkanol or dialkanol is mixed with an aqueous solution of a mineral acid, whereby on average no more than 1.01 mol acid equivalents per mol hydroxyl group of alkanol or dialkanol is used, (ii) in a reaction zone, an aqueous solution of an inorganic nitrite is continuously added to the aqueous mixture obtained in step (i), (iii) the organic phase is optionally isolated.
Abstract:
A process for preparing 4-thioalkylbromobenzene derivatives of the formula I, (I), where: R1 is C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C3-C8-cycloalkyl, halogen; R2 is C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl, C2-C6-alkenyl, cyano or a heterocyclic radical; R3 is C1-C6-alkyl, which comprises reacting a compound of the formula II, (II), in which R?1 and R2¿ are as defined above, with a dialkyl disulfide of the formula III, (III), in the presence of a nitrite and a catalyst in a suitable solvent is described.
Abstract:
The invention relates to a method for producing 4-bromine-aniline derivatives of formula (I), wherein the substituents have the following meanings: R1: C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C1-C6-halogen-alkoxy, C3-C8-cycloalkyl, halogen; R2: C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl, C2-C6-alkenyl, cyano or a heterocyclic radical.
Abstract:
The invention relates to hydroximic acid halogenides of the formula (I) wherein the substituents have the following significance; X - NOCH3, CHOCH3 or CHCH3; Y - O or NH; R - halogen; R - optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl or aryl; R - optionally substituted alkyl, alkoxyalkyl, cycloalkyl-alkyl, alkenyl and alkynyl and their salts. The invention also relates to a method for the production and use of said hydroximic acid halogenides.
Abstract:
The invention relates to a method for producing 2,2,4,4 tetra-substituted 1,3,5 - cyclohexanetriones of formula (I), by reacting a cyclobutane-1,3-diones of formula (II) with an O or N nucleophile and a silylation reagent and then subsequently by acetylisation and cyclisation.
Abstract:
The invention relates to substituted 6-aryl-3-thioxo-5-(thi)oxo-2,3,4,5-tetrahydro-1,2,4-triazines of formula (I) and to their salts. In said formula, R1 is C1-C6-alkyl, C1-C6-halogen alkyl, and possibly substituted phenyl; R2 is NH¿2?, C1-C6-alkyl, C1-C6-halogen alkyl, C2-C6-alkenyl, C3-C6-alkinyl, (C1-C6-alkoxy) carbonyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C3-C6-cycloalkyl; Ar is a group corresponding to formula (Ar?1), (Ar2), (Ar3¿) or (Ar4); Y is O, S; Z is O, S, NH, N(C¿1?-C6-alkyl) and R?3, R4, R5, R6, R7 and R8¿ have the meaning given in the description. Said compounds are used as herbicides and for the desiccation/defoliation of plants.