Method and device of removing and recycling metals from mixing acid solution

    公开(公告)号:US11976374B2

    公开(公告)日:2024-05-07

    申请号:US17017337

    申请日:2020-09-10

    CPC classification number: C25C1/08 B01J39/05 B01J39/18 B01J47/02 C01G51/003

    Abstract: A method and device of removing and recycling metals from a mixing acid solution, includes adsorbing a mixing acid solution with a pH value of −1 to 4 and a cobalt ion concentration of 100 to 1,000 mg/L by at least two cation resins in series setting to the cobalt ion concentration in the mixing acid solution is less than 10 mg/L, and then adjusting the pH value of the mixing acid solution after adsorption to meet a discharge standard, wherein the particle size of the at least two cation resins in series setting is 150˜1,200 μm. After the cation resins are saturated by adsorption, regenerating the cation resins by sulfuric acid to form a cobalt sulfate solution, and then electrolytically treating the cobalt sulfate solution to obtain electrolytic cobalt and sulfuric acid electrolyte. The operation process is simple without complicated equipment, and it can effectively recycle metals from mixing acid solutions. The cationic resin and sulfuric acid solution can also be reused, so the method of the present invention has environmental and economic benefits.

    ION EXCHANGE MEMBRANE AND ELECTROLYZER
    166.
    发明公开

    公开(公告)号:US20230349058A1

    公开(公告)日:2023-11-02

    申请号:US18139518

    申请日:2023-04-26

    Abstract: An ion exchange membrane containing: a layer S containing a fluorine-containing polymer having a sulfonic acid group; a layer C containing a fluorine-containing polymer having a carboxylic acid group; and—a plurality of reinforcing materials functioning as at least one of reinforcement yarn and sacrifice yarn; wherein, when the ion exchange membrane is viewed from a top surface, an average cross-sectional thickness A of the ion exchange membrane measured in pure water for a region, is μm or more and 75 μm or less, and wherein a strength change ratio calculated from strength S2 of the ion exchange membrane measured after the ion exchange membrane is subjected to a predetermined electrolysis test and strength S1 of the ion exchange membrane measured before the ion exchange membrane is subjected to the electrolysis test, in terms of 100×S2/S1, is 85% or more and 120% or less.

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